浅析SOFC性能衰减的材料因素

doi:10.61558/2993-074X.2942

电化学（中英文） ›› 2013, Vol. 19 ›› Issue (2): 110-114. doi: 10.61558/2993-074X.2942

浅析SOFC性能衰减的材料因素

高克卿, 刘晓天, 赵二庆, 樊丽权, 熊岳平*

哈尔滨工业大学化工学院, 黑龙江哈尔滨 150001

收稿日期:2011-12-09 修回日期:2012-01-30 出版日期:2013-04-28 发布日期:2012-02-10
通讯作者: 熊岳平 E-mail:ypxiong@hit.edu.cn
基金资助:
国家自然科学基金（No. 51072040）和国家973计划项目（No. 2012CB215400）资助

Analysis of the Material Factors in the Degradation of SOFC Performance

GAO Ke-Qing, LIU Xiao-Tian, ZHAO 二Qing, FAN Li-Quan, XIONG Yue-Ping*

Analysis of the Material Factors in the Degradation of SOFC Performance

Received:2011-12-09 Revised:2012-01-30 Published:2013-04-28 Online:2012-02-10
Contact: XIONG Yue-Ping E-mail:ypxiong@hit.edu.cn

摘要/Abstract

摘要： 从SOFC工作状态出发，分析了材料在氧化还原气氛中的固-气界面化学稳定性、材料间固-固界面的扩散与相互反应的特性以及外部化学物质的介入对三相界面反应等方面因素对电池性能可能产生的影响.故我国应注重探究实用的SOFC电池性能衰减材料因素.

关键词: 衰减, 固-气界面, 固-固界面, 三相界面

Abstract: Based on the cell operating conditions, the material factors which influence the cell performance of SOFC including the chemical stability of materials at solid-gas interface in redox atmosphere, the diffusion and reaction between the interface of solid-solid materials, and degradation caused by the external chemical substances brought into the cells at triple phase boundary are mainly analyzed. Given that under the current state of the research it is urgent to explore the material factors on degradation of cell performance to meet demands in SOFC applications.

Key words: degradation, solid-gas interface, solid-solid interface, triple phase boundary

中图分类号:

TM911.4

高克卿, 刘晓天, 赵二庆, 樊丽权, 熊岳平. 浅析SOFC性能衰减的材料因素[J]. 电化学（中英文）, 2013, 19(2): 110-114.

GAO Ke-Qing, LIU Xiao-Tian, ZHAO 二Qing, FAN Li-Quan, XIONG Yue-Ping. Analysis of the Material Factors in the Degradation of SOFC Performance[J]. Journal of Electrochemistry, 2013, 19(2): 110-114.

参考文献

[1] Takahashi T. Fuel Cells [M]. Dou F L (窦方亮), Xiong Y P (熊岳平), Tr. Fuel Cells [M]. Changchun: Jilin University Press (吉林大学出版社), 1994: 113.
[2] Singhal S C. Recent progress in tubular solid oxide fuel cells technology [M]// Electrochemical Society Series. Pennington, Electrochemical Society Inc, 1997, 97(40): 37-50.
[3] Sakai N, Yamaji K, Horit T, et al. Control factors of material degradation in SOFC operation [J]. Materia Japan, 2005, 44: 207-210.
[4] Yokokawa H, Sakai N, Horit T, et al. Electrolytes for solid oxide fuel cells [J]. MRS Bulletin, 2005, 30(8): 591-595.
[5] Yamaji K, Xiong Y P, Kishimoto H, et al. Electronic conductivity and efficiency of SOFC electrolytes [M]// Fuel Cell Seminar. Pennington, Electrochemical Society Inc, 2007, 12(1): 317-322.
[6] Xiong Y P, Yamaji K, Sakai N, et al. Electronic Conductivity of ZrO2-CeO2-YO1.5 solid solutions [J]. Journal of the Electrochemical Society, 2001, 12(148): 489-492.
[7] Xiong Y P, Yamaji K, Horita T, et al. Electronic conductivity of 20mol% Y2O1.5 doped CeO2 [J]. Journal of the Electrochemical Society, 2002, 11(149): 450-454.
[8] Xiong Y P, Yamaji K, Horita T, et al. Hole and electron conductivities of 20 mol%-ReO1.5 doped CeO2 (Re = Yb, Y, Gd, Sm, Nd, La). Journal of the Electrochemical Society, 2004, 3(151): A407-A412.
[9] Xiong Y P, Yamaji K, Kishimoto H, et al. Electronic conductivity of ZrO2 - CeO2 - YO1.5 solid solutions in a wide range of temperature and oxygen partial pressure [J]. Journal of the Electrochemical Society, 2006, 12(153): A2189-A2204.
[10] Sakai N, Xiong Y P, Yamaji K, et al. Transport properties of ceria-zirconia-yttria solid solutions {(CeO2)x(ZrO2)1-x}1-y(YO1.5)y (x = 0 ~ 1, y = 0.2, 0.35) [J]. Journal of Alloys and Compounds, 2006, 408-412: 503-506.
[11] Sakai N, Xiong Y P, Yamaji K, et al. Anomalous conductivity and microstructure in gadolinium doped ceria prepared from nano-sized powder [J]. Solid State Ionics, 2006, 177:2503-2507.
[12] Xie M, Zhan Z L, Liu X J, et al. Low-temperature ceria-electrolyte solid oxide fuel cells for efficient methanol oxidation [J]. Journal of Power Sources, 2011, 196(23): 9961-9964.
[13] Ishihara T, Mtsuda H, Takita Y. Doped LaGaO3 perovskite-type oxide as a new oxide ionic conductor [J]. Journal of the American chemical society, 1994, 116(9):3801-3803.
[14] Ishihara T, Mtsuda H, Takita Y. Effects of rare-earth cations doped for La site on the oxide ionic conductor of LaGaO3-based perovskite-type oxide [J]. Solid State Ionics, 1995, 79: 147-151.
[15] Murakami N, Nakamura S, Sato M, et al. R&D intermediate-temperature SOFC using LaGaO3-based oxide as electrolyte (6) [C]// Extended Abstracts of the 15th symposium on SOFC in Japan, Tokyo, The SOFC Society of Japan, 2006: 103A.
[16] Yamaji K, Xiong Y P, Kishimoto H, et al. Electronic conductivity of doped lanthanum gallate electrolytes [C]// Solid state ionics: The science and technology of ions in motion, Singapore, World Scientific Publishing Co. Pte. Ltd., 2004: 253-260.
[17] Yamaji K, Xiong Y P, Kishimoto H, et al. Electronic conductivity of La0.8Sr0.2Ga0.8Mg0.2-xCoxO3-δ electrolytes (II) [C]// Solid state ionics: Advanced materials for emerging technologies, Singapore, World Scientific Publishing Co. Pte. Ltd., 2006: 252-259.
[18] Han M F, Peng S P, Wang Z L, et al. Properties of Fe-Cr based alloys as interconnects in a solid oxide fuel cell [J]. Journal of Power Sources, 2007, 164(1): 278-283.
[19] Horita T, Xiong Y P, Kishimoto H, et al. Oxidation behavior of Fe-Cr and Ni-Cr based alloy interconnects in CH4-H2O for solid oxide fuel cells [J]. Journal of the Electrochemical Society, 2005, 152(11): A2193-A2198.
[20] Horita T, Xiong Y P, Yamaji K, et al. Stability of Fe-Cr alloy interconnects under CH4-H2O atmosphere for SOFCs [J]. Physical Chemistry Chemical Physics, 2003, 5(11): 2253-2256.
[21] Uehara T, Yasuda N, Ohno T, et al. Improvement of oxidation resistance of Fe-Cr ferritic alloy sheets for SOFC interconnects [J]. Electrochemistry, 2009, 77(2): 131-133.
[22] Yokokawa H, Sakai N, Kawada T, et al. Thermodynamic analysis on relation between nonstoichiometry of LaMnO3 perovskites and their reactivity with ZrO2 [J]. Denki Kagaku, 1989, 57(8): 829-836.
[23]. H. Yokokawa. Generalized chemical potential diagram-its fundamentals and applications part four-extension to multicomponents systems [J]. Materia Japan, 1996, 35: 1345-1351.
[24] Huang K Q, Feng M, Goodenough J B, et al. Characterization of Sr-Doped LaMnO3 and LaCoO3 as cathode materials for a doped LaGaO3 ceramic fuel cell [J]. Journal of the Electrochemical Society, 1996,143(12): 3630-3636.
[25] Huang K Q, Goodenough J B. A solid oxide fuel cell based on Sr- and Mg-doped LaGaO3 electrolyte: the role of a rare-earth oxide buffer [J]. Journal of Alloys and Compounds, 2000, 303-304: 454-464.
[26] Liu R Z (刘仁柱), Huang B (黄波), Ye X F (叶晓峰), et al. Fabrication and performance of Ni-ScSZ Cermet anode modified by coating with Gd0.2Ce0.8O2 for a SOFC [J]. Journal of Electrochemistry (电化学), 2007, 13(1): 50-56.
[27] Yokokawa H, Tu H Y, Iwanschitz B, Mai A. Fundamental mechanisms limiting solid oxide fuel cell durability [J]. Journal of Power Sources, 2008, 182(2): 400-412.
[28] Sasaki K. Chemical Durability of SOFCs [C]// Extended abstracts of the 17th Symposium on SOFC in Japan. Tokyo, 2008: 34-37.
[29] Sasaki K, Susuki K, Iyoshi A, et al. H2S poisoning of solid oxide fuel cells [J]. Journal of the Electrochemical Society, 2006, 153(11):A2023-A2029.
[30] Liu R R, Kim S H, Taniguchi S, et al. Influence of water vapor on long-term performance and accelerated degradation. Journal of Power Sources, 2001, 1967, 17(S1): 7090-7096.
[31] Kishimoto H, Xiong Y P, Yamaji K, et al. Stability of Ni base anode for direct hydrocarbon SOFCs [J]. Journal of Chemical Engineering of Japan, 2007, 13(40): 1178-1182.
[32] Yamaji K, Xiong Y P, Kishimoto H, et al. Study of accelerating tests methods on durability of SOFCs: effect of variation in driving force of reactions and/or in mass transfer of impurities [C]// Extended Abstracts of the 17th Symposium on SOFC in Japan, Tokyo, 2008: 30-33.
[33] Xiong Y P, Yamaji K, Kishimoto H, et al. Deposition of platinum particles at LSM/ScSZ/air three-phase boundaries using a platinum current collector [J]. Electrochemical and Solid-State Letters, 2009, 12(3): B31-B33.
[34] Xiong Y P, Yamaji K, Horita T, et al. Sulfur poisoning of SOFC cathodes [J]. Journal of the Electrochemical Society, 2009, 5(156): B588-B592.
[35] Cheng M J. Investigation on new cathodes for lowering operation temperature [C]// Asia-European Workshop on SOFC, 2008, Dalian, China.
[36] Wang S R, Introduction of planar SOFC research activities in SICCAS [C]//, Asia-European Workshop on SOFC, 2008, Dalian, China.
[37] Eguchi K. Report on 2008 Korea-Japan-China SOFC Symposium [J], The Jo urnal of Fuel Cell Technology (Japan) 2008, 3(8): 133-134.

浅析SOFC性能衰减的材料因素

Analysis of the Material Factors in the Degradation of SOFC Performance

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 10

Metrics

[1]	罗宇, 马如琴, 龚正良, 杨勇. 固态锂硫电池研究进展[J]. 电化学（中英文）, 2023, 29(3): 2217007-.
[2]	吉维肖, 王功伟, 王强, 白力军, 屈德扬. 多孔电极在电化学体系中的应用[J]. 电化学（中英文）, 2020, 26(5): 576-595.
[3]	刘勇，丁涵，司德春，彭杰，张剑波. 静电纺丝制备质子交换膜燃料电池催化剂层综述[J]. 电化学（中英文）, 2018, 24(6): 639-654.
[4]	胡燚，何湘柱, 邓忠德，孔令涌，尚伟丽. 锂离子电池正极材料LiNi _0.5Co_0.2Mn _0.3O₂和LiNi_0.5Co _0.2Mn _0.3O₂/LiFePO₄容量衰减原因分析[J]. 电化学（中英文）, 2017, 23(6): 675-683.
[5]	孙现众, 张熊, 王凯, 马衍伟. 高能量密度的锂离子混合型电容器[J]. 电化学（中英文）, 2017, 23(5): 586-603.
[6]	刘文, 王苗, 陈继涛, 张新祥, 周恒辉. 锂离子电池正极材料LiNi0.5Co0.2Mn0.3O2的合成及其高温容量衰减研究[J]. 电化学（中英文）, 2012, 18(2): 118-124.
[7]	王大为, 李东江, 李军, 杨勇. 锂离子电池电化学反应模型研究进展浅析[J]. 电化学（中英文）, 2011, 17(4): 355-362.
[8]	程璇,彭程,游梦迪,刘晶,张颖. DMFC寿命测试过程中膜电极的表面和结构研究(英文)[J]. 电化学（中英文）, 2005, 11(3): 254-261.
[9]	胡晓宏,杨汉西,艾新平,李升宪,洪昕林. LiMn_2O_4正极在高温下性能衰退现象的研究[J]. 电化学（中英文）, 1999, 5(2): 224-230.
[10]	储炜，史苑芗，魏宝明, 杨勇，陈旭光，林祖赓. 模拟混凝土孔溶液中钢筋钝化膜生长动力学及孔蚀过程的研究[J]. 电化学（中英文）, 1995, 1(4): 415-421.