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电化学(中英文) ›› 2017, Vol. 23 ›› Issue (3): 262-275.  doi: 10.13208/j.electrochem.161052

• 有机电化学及电化学工业近期研究专辑(华东理工大学张新胜教授、北京化工大学曾程初教授主编) • 上一篇    下一篇

电化学条件下α-C—H键的官能团化的研究进展

钱 朋,毕美香,王玉康,查正根*,汪志勇*   

  1. 合肥微尺度国家实验室,中国科学技术大学化学与材料科学学院,合肥 230026
  • 收稿日期:2016-11-16 修回日期:2017-02-13 出版日期:2017-06-29 发布日期:2017-02-15
  • 通讯作者: 查正根,汪志勇 E-mail:zwang3@ustc.edu.cn; zgzha@ustc.edu.cn
  • 基金资助:

    国家自然科学基金项目(21272222, 21172205, 21432009, 21472177, 21672200)资助

Research Progresses of α-C—H Bond Functionalizations under Electrochemical Conditions

QIAN Peng, BI Mei-xiang, WANG Yu-kang, ZHA Zheng-gen*, WANG Zhi-yong*   

  1. Hefei National Laboratory for Physical Sciences at Microscale and Department of Chemistry, University of Science and Technology of China Hefei, 230026, P. R. China
  • Received:2016-11-16 Revised:2017-02-13 Published:2017-06-29 Online:2017-02-15
  • Contact: ZHA Zheng-gen, WANG Zhi-yong E-mail:zwang3@ustc.edu.cn; zgzha@ustc.edu.cn

摘要:

近年来,有机电化学合成已经成为有机合成化学中构造碳碳及碳杂键的重要方法. 该文主要综述了目前电化学合成的主要研究方向,着重介绍了我们课题组在电化学合成中利用碘自由基,促进苯乙酮α-C—H键的官能团化所取得的研究进展. 该方面的研究为绿色有机合成的发展提供了新的思路和方向.

关键词: 有机电合成;碘自由基;C&mdash, H官能团化;绿色合成

Abstract: Recently, organic electrochemical synthesis has emerged as the most important and attractive method to construct carbon-carbon bond and carbon-heteroatom bonds in organic synthetic chemistry. This review mainly summarizes the electrochemical syntheses at present, especially focused on the recent progresses in our research group using an iodine radical as a mediator to promote α-C?H bond functionalization. The organic electrosynthesis provides an alternative approach and a new research direction in the development of green organic synthesis.

Key words: organic electrosynthesis, iodine radical, C—H functionalization, green synthesis

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