C-H键选择性直接电氧化研究

doi:10.13208/j.electrochem.161046

电化学（中英文） ›› 2017, Vol. 23 ›› Issue (3): 276-282. doi: 10.13208/j.electrochem.161046

• 有机电化学及电化学工业近期研究专辑（华东理工大学张新胜教授、北京化工大学曾程初教授主编） • 上一篇下一篇

C-H键选择性直接电氧化研究

廖艳梅，武倩倩，张安伦，朱英红*，马淳安*

浙江工业大学化学工程学院，绿色化学合成技术国家重点实验室培育基地，杭州 310032

收稿日期:2016-10-31 修回日期:2017-03-30 出版日期:2017-06-29 发布日期:2017-03-31
通讯作者: 朱英红，马淳安 E-mail:yhzhuchem@zjut.edu.cn, science@zjut.edu.cn
基金资助:
973前期研究专项（2012CB722604）资助

Selective Direct Electro-Oxidation of C-H Bond

Liao Yan-mei， Wu Qian-qian， Zhang An-lun， Zhu Ying-hong*，Ma Chun-an*

State Key Laboratory of Green Chemistry Synthesis Technology，College of chemical Engineering， Zhejiang University of Technology，Hangzhou，310032 Zhejiang China

Received:2016-10-31 Revised:2017-03-30 Published:2017-06-29 Online:2017-03-31
Contact: Zhu Ying-hong，Ma Chun-an E-mail:yhzhuchem@zjut.edu.cn, science@zjut.edu.cn

摘要/Abstract

摘要：

C-H键是有机化合物中最基本的化学键，C-H键的活化和直接转化避免了反应物的预先官能化，是最终实现烷烃类化合物转化为不同种类有机化合物最直接、高效的转换方式，通过C-H键构建C-X键（X=O、C、N）是非常重要和具有挑战性的研究. C-H键直接电氧化活化过程中以“电子”参与反应，不需要加入额外的催化剂，并可通过选择合适的电极材料、支持电解质、溶剂和反应温度，通过恒电流或者恒电位电解，进行具有特定的反应选择性和区域选择性的C-H键电氧化活化，从而获得含其他活性基团的目标产物.

关键词: C-H键, 直接电氧化, 选择性

Abstract: Carbon-hydrogen (C-H) bond is the most basic chemical bond in organic compounds. The activation and direct conversion of C-H bond are the effective methodology for synthesis of different kinds of organic compounds from alkane compounds. The oxidative activation and functionalization of C-H bonds constitute an important and challenging area of investigation. The electro-oxidative activation of C-H bonds to form new C-O, C-C and C-N bonds has proven to be interesting and important in organic chemistry using the clean electron as the oxidant. The target C-O, C-C and C-N compounds could be selectively achieved by choosing the appropriate electrode, supporting electrolyte and solvent, as well as reaction temperature via the constant current or constant potential electrolysis technology.

Key words: C-H bond, direct electro-oxidation, selectivity

中图分类号:

O646

廖艳梅，武倩倩，张安伦，朱英红，马淳安. C-H键选择性直接电氧化研究[J]. 电化学（中英文）, 2017, 23(3): 276-282.

Liao Yan-mei， Wu Qian-qian， Zhang An-lun，Zhu Ying-hong，Ma Chun-an. Selective Direct Electro-Oxidation of C-H Bond[J]. Journal of Electrochemistry, 2017, 23(3): 276-282.

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链接本文: https://electrochem.xmu.edu.cn/CN/10.13208/j.electrochem.161046

https://electrochem.xmu.edu.cn/CN/Y2017/V23/I3/276

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C-H键选择性直接电氧化研究

Selective Direct Electro-Oxidation of C-H Bond

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