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电化学(中英文) ›› 2017, Vol. 23 ›› Issue (3): 250-261.  doi: 10.13208/j.electrochem.161041

• 有机电化学及电化学工业近期研究专辑(华东理工大学张新胜教授、北京化工大学曾程初教授主编) • 上一篇    下一篇

电羧化:一种固定CO2制备有机羧酸的有效途径

王 欢,陆嘉星*   

  1. 上海市绿色化学与化工过程绿色化重点实验室,华东师范大学化学与分子工程学院,上海 200062
  • 收稿日期:2016-10-21 修回日期:2017-02-07 出版日期:2017-06-29 发布日期:2017-02-08
  • 通讯作者: 陆嘉星 E-mail:jxlu@chem.ecnu.edu.cn
  • 基金资助:

    国家自然科学基金项目(20573037,20973065,21373090,21473060,21673078)资助

Electrocarboxylation: an Effective Process for Fixation of CO2 into Organic Carboxylic Acids

WANG Huan, LU Jia-xing*   

  1. Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, China
  • Received:2016-10-21 Revised:2017-02-07 Published:2017-06-29 Online:2017-02-08
  • Contact: LU Jia-xing E-mail:jxlu@chem.ecnu.edu.cn

摘要:

温室气体CO2的绿色高效转化利用是当前的研究热点. 其中,有机物的电化学羧化反应是CO2利用的有效途径. 温和条件(常温常压)下,有机底物电还原生成的碳负离子可以捕获体系中的CO2,进而合成具有高附加值的有机羧酸类化合物. 本文重点介绍了本课题组在电羧化反应方面的研究进展,包括各类电活性基团物质的电羧化反应以及不对称电羧化反应.

关键词: 电羧化, 二氧化碳, 有机电合成

Abstract:

Conversion and utilization of greenhouse gas carbon dioxide (CO2) have become more and more significant to the sustainable development of the global economy. Among them, electrocarboxylation of organic substrates is an effective process. Under mild conditions such as ambient temperature and pressure, carbocations generated by electroreduction of organic substrates can react with CO2 into corresponding carboxylic acids. This paper introduces the recent progress of our group in electrochemical carboxylation, including electrocarboxylation of varies active organic substrates and asymmetric electrocarboxylation.

Key words: electrocarboxylation, carbon dioxide, organic electrosynthesis.

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