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电化学(中英文) ›› 2016, Vol. 22 ›› Issue (2): 113-122.  doi: 10.13208/j.electrochem.151146

• 燃料电池电化学催化与催化剂近期研究专辑(重庆大学 魏子栋教授主编) • 上一篇    下一篇

扫描电化学显微镜在电催化氧反应研究中的应用

陈星星*   

  1. 辽宁科技大学化工学院,辽宁省鞍山市高新区千山中路185号,邮编114051
  • 收稿日期:2015-12-29 修回日期:2016-01-28 出版日期:2016-04-28 发布日期:2016-04-28
  • 通讯作者: 陈星星 E-mail:xingchenstar79@163. com
  • 基金资助:

    辽宁省教育厅优秀人才(第二层次)基金项目资助, 辽宁科技大学人才引进基金项目资助

Mini-Review: Possible Applications of Scanning Electrochemical Microscopy (SECM) in Characterizations of Oxygen Reduction Reaction and Oxygen Evolution Reaction

CHEN Xing-xing*   

  1. School of Chemical Engineering, University of Science and Technology Liaoning, Anshan 114051, Liaoning, China
  • Received:2015-12-29 Revised:2016-01-28 Published:2016-04-28 Online:2016-04-28
  • Contact: CHEN Xing-xing E-mail:xingchenstar79@163. com

摘要:

本综述首先简单介绍了扫描电化学显微镜的基本概况,尤其是不同的工作模式. 其次,有针对性地介绍了SECM的不同工作模式在氧还原和水解析氧反应相关研究中的应用. 最后,对扫描电化学显微镜未来在新能源转换存储系统研究领域的应用进行了展望.

关键词: 扫描电化学显微镜, 氧还原, 水解析氧, 燃料电池, 金属空气电池, 水解

Abstract:

Scanning electrochemical microscopy (SECM) has been proved to be a unique technique for combinatorial screening of localized phenomena for different electrocatalysts potentially used in new energy conversion and storage systems. This mini-review provides a brief summary of different SECM working modes, such as direct mode, feedback mode, generation-collection mode, redox competition mode and noise mode, which are especially applied for characterizing the oxygen reactions. Particularly, a series of important development in SECM screening of electrocatalysts for oxygen reduction reaction and oxygen evolution reaction from the author and W. Schuhmann’s group in Germany has been highlighted and overviewed. Finally, some prospects for the SECM development in new energy system-related research in the future are also discussed.

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