自增湿阴极开放式PEMFC的温度调控

doi:10.13208/j.electrochem.130621

电化学（中英文） ›› 2014, Vol. 20 ›› Issue (2): 184-188. doi: 10.13208/j.electrochem.130621

自增湿阴极开放式PEMFC的温度调控

赵思臣^1,2*，王奔¹，贾秋红^2,3，韩明⁴，谢玉洪¹,

1. 西南交通大学电气工程学院，四川成都 610031；2. 西南交通大学机械工程学院，四川成都 610031；3. 重庆理工大学机械工程学院，重庆 400054；4. 淡马锡理工学院清洁能源研究中心，新加坡 529757

收稿日期:2013-06-21 修回日期:2013-08-09 出版日期:2014-04-28 发布日期:2014-04-17
通讯作者: 赵思臣 E-mail:253032409@qq.com

Effect of Temperature on the Self-Humidifying Open-Cathode Proton Exchange Membrane Fuel Cell

ZHAO Si-chen^{1, 2*}, WANG Ben¹, JIA Qiu-hong^{2, 3}, HAN Ming⁴, XIE Yu-hong^{1, 4}

1. School of Electrical Engineering, Southwest Jiaotong University, Chengdu 610031, China; 2. School of Mechanical Engineering, Southwest Jiaotong University, Chengdu 610031, China; 3. College of Mechanical Engineering, Chongqing University of Technology, Chongqing 400054, China; 4. Clean Energy Research Center, Temasek Polytechnic, 529757, Singapore

Received:2013-06-21 Revised:2013-08-09 Published:2014-04-28 Online:2014-04-17
Contact: ZHAO Si-chen E-mail:253032409@qq.com

摘要/Abstract

摘要： 温度对自增湿阴极开放式质子交换膜燃料电池（PEMFC）的性能有着重要的影响. 依据自制的常压自增湿型PEMFC及温度控制设备搭建测试平台，测试了燃料电池在不同工作温度下的输出特性曲线—伏安曲线和功率输出曲线. 通过拟合得到了电极过程动力学参数，分析了工作温度影响电池性能的主要原因.

关键词: 质子交换膜燃料电池, 自增湿, 输出特性曲线, 最佳工作温度, 温度控制

Abstract: Based on the experiments about the output characteristics of a home-made temperature-controlled PEMFC system with atmospheric pressure and no external humidifying condition in different loading voltages and operating temperatures, the optimum operating temperature at different loading voltages can be obtained by tracking the output characteristics of PEMFC operating over a range of temperatures. By analyzing the fitted data the kinetic parameters are evaluated and the effect of different operating temperatures on the PEMFC performance is discussed from a view of electrode kinetics.

Key words: proton exchange membrane fuel cell, self-humidifying, optimum operating temperature, output characteristic curve, temperature control

中图分类号:

TM911.4

赵思臣*，王奔，贾秋红，韩明，谢玉洪. 自增湿阴极开放式PEMFC的温度调控[J]. 电化学（中英文）, 2014, 20(2): 184-188.

ZHAO Si-chen*, WANG Ben, JIA Qiu-hong, HAN Ming, XIE Yu-hong. Effect of Temperature on the Self-Humidifying Open-Cathode Proton Exchange Membrane Fuel Cell[J]. Journal of Electrochemistry, 2014, 20(2): 184-188.

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链接本文: https://electrochem.xmu.edu.cn/CN/10.13208/j.electrochem.130621

https://electrochem.xmu.edu.cn/CN/Y2014/V20/I2/184

参考文献

[1] Zawodzinski T A (Jr.), Derouin C, Radzinski S, et al. Water uptake by and transport through nafion? 117 membranes[J]. Journal of The Electrochemical Society, 1993, 140(4): 1041-1047.
[2] Zawodzinski T A (Jr.), Springier T E, Davey J, et al. A comparative study of water uptake by and transport through ionomeric fuel cell membranes[J]. Journal of Electrochemical Society, 1993, 140(7): 1981-1985.
[3] Zawodzinki T A. Effects of water on the properties of polymer exchange membrane in fuel cell[J]. Solid State Ionics, 1993, 60: 199-201P.
[4] Ciureanu M, Roberge R. Electrochemical impedance study of PEM fuel cells. Experimental diagnosis and modeling of air cathodes[J]. Journal of Physical Chemistry B, 2001, 105(17): 3531-3539.
[5] Ge S H(葛善海), Yi B L(衣宝廉), Xu H F(徐洪峰). Model of water transport for proton-exchange membrane fuel cell (PEMFC)[J]. Journal of Chemical Industry and Engineering (化工学报), 1999, 50(1): 39-47.
[6] Buchi F N, Srinivasan S. Operating proton exchange membrane fuel cells without external humidification of the reactant gases - Fundamental aspects [J]. Journal of The Electrochemical Society, 1997, 144(8): 2767-2772.
[7] Bemad D M, Verbrugge M W. A mathematical model of the solid-polymer-electrolyte fuel cell[J]. Journal of The Electrochemical Society, 1992, 139(9): 2477-2491.
[8] Yu J R(于景荣), Yi B L(衣宝廉), Han M(韩明), et al. Operating proton exchange membrane fuel cells without external humidification[J]. Chinese Journal of Power Sources(电源技术), 2001, 25(5): 327-329.
[9] Chan S H, Han M, Jiang S P. Guidelines for stable operation of a polymer electrolyte fuel cell with self-humidifying membrane electrolyte assembly[J]. Journal of the Electrochemical Society, 2007, 154(5): B486-B493.
[10] Riascos L A M, Pereira D D. Limit operating temperature in polymer electrolyte membrane fuel cells[J]. Journal of the Electrochemical Society, 2009, 156(9): B1051-B1058.
[11] Srinivasan S, Ticianelli EA, Derouin C R, et al. Advances in solid polymer electrolyte fuel cell technology with low platinum loading electrodes[J]. Journal of Power Sources, 1988, 22(3/4): 359-375.
[12] Srinivasan S, Velew OA, Parthasarathy A, et al. High energy efficiency and high power density proton exchange membrane fuel cells — electrode kinetics and mass transport[J]. Journal of Power Sources, 1991, 36(3): 299-320.
[13] James L, Andrew D. Fuel cell system explained (Second edition)[M]. Chichester: John Wiley & Sons, 2003: 22-24.
[14] Han M, Chan S H, Jiang S P. Investigation of self-humidifying anode in polymer electrolyte fuel cells[J]. International Journal of Hydrogen Energy, 2007, 32: 385-391.
[15] Hogarth W H J, Benziger B. Operation of polymer electrolyte membrane fuel cells with dry feeds: Design and operating strategies[J]. Journal of Power Sources, 2006, 159(2): 968-978.
[16] Li H, Tang Y H, Wang Z W, et al. A review of water flooding issues in the proton exchange membrane fuel cell[J]. Journal of Power Sources, 2008, 178(1): 103-117.
[17] Atiyeh H K, Karan K, Peppley B. Experimental investigation of the role of a micro porous layer on the water transport and performance of a PEM fuel cell[J]. Journal of Power Sources, 2007, 170(1):111-121.

自增湿阴极开放式PEMFC的温度调控

Effect of Temperature on the Self-Humidifying Open-Cathode Proton Exchange Membrane Fuel Cell

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