片状LiV3O8软模板辅助溶胶凝胶法制备及其在水系锂离子电池中的性能研究

doi:10.13208/j.electrochem.130353

电化学（中英文） ›› 2013, Vol. 19 ›› Issue (6): 579-584. doi: 10.13208/j.electrochem.130353

• 锂离子电池近期研究专辑 (厦门大学杨勇教授主编) • 上一篇下一篇

片状LiV₃O₈软模板辅助溶胶凝胶法制备及其在水系锂离子电池中的性能研究

谭帅，孙旦，王海燕^*，侯天丽，肖仲星，唐有根

中南大学有色金属资源化学教育部重点实验室，化学化工学院湖南长沙 410083

收稿日期:2013-03-27 修回日期:2013-05-29 出版日期:2013-12-28 发布日期:2013-12-23
通讯作者: 王海燕 E-mail:wanghy419@126.com
基金资助:
中国博士后基金（No. 2013M530356）、有色金属资源化学教育部重点实验室开放基金（No. 2012KF01）、中南大学科研启动基金及中南大学贵重仪器设备开放基金（No. CSUZC201303）资助

Preparation and Electrochemical Properties of Flake-like LiV₃O₈ by Soft Template Assisted Sol-gel Method as Anode Material for Aqueous Li-ion Battery

TAN Shuai, SUN Dan, WANG Hai-yan^*, HOU Tian-li, XIAO Zhong-Xing, TANG You-gen

Key Laboratory of Resources Chemistry of Nonferrous Metals, Ministry of Education, School of Chemistry and Chemical Engineering, Central South University, Changsha, 410083, P.R China

Received:2013-03-27 Revised:2013-05-29 Published:2013-12-28 Online:2013-12-23
Contact: WANG Hai-yan E-mail:wanghy419@126.com

摘要/Abstract

摘要： 负极材料是目前制约水溶液锂离子电池的关键. 采用十二烷基苯磺酸钠软模板辅助的溶胶凝胶法制备了片状LiV₃O₈材料. XRD和SEM测试表明目标材料为纯相的片状结构LiV₃O₈，属单斜晶系，P21/m点群. 组装LiMn₂O₄//Li₂SO₄//LiV₃O₈水溶液锂离子电池，测试发现片状LiV₃O₈具有较高的倍率性能和较好的循环寿命. 在0.1C下，LiV₃O₈的放电比容量为154 mAh.g^-1. 在1C、5C和10C时，放电容量分别为134 mAh.g^-1、78 mAh.g^-1和54 mAh.g^-1. 1C下前170周循环的容量保持率约60%.

关键词: 水系锂离子电池, LiV₃O₈, 溶胶-凝胶法, 电化学性能

Abstract: Anode material has become the key issue for restricting the development of aqueous lithium ion battery (ALIB). Flake-like LiV3O8 materials were synthesized by sol-gel method using sodium dodecyl benzene sulfonate (SDBS) as a template. The XRD and SEM results showed that as-prepared flake-like LiV₃O₈was of high purity with monoclinic system and P21/m space group. LiMn₂O₄//Li₂SO₄//LiV₃O₈ ALIB was assembled and tested. As observed, the flake-like LiV3O8 here exhibited good high-rate performance and cycling stability. A high discharge capacity of 154 mAh.g^-1 (based on the mass of negative electrode) was delivered at 0.1C (1C=300 mA.g^-1). At 1C, 5C and 10C rates, the reversible discharge capacities of 134 mAh.g^-1, 78 mAh.g^-1 and 54 mAh.g^-1 were retained, respectively. More importantly, the capacity retention after 170 cycles at 1C was about 60%.

Key words: aqueous Li-ion battery, LiV3O8, sol-gel method, electrochemical properties

中图分类号:

谭帅，孙旦，王海燕*，侯天丽，肖仲星，唐有根. 片状LiV₃O₈软模板辅助溶胶凝胶法制备及其在水系锂离子电池中的性能研究[J]. 电化学（中英文）, 2013, 19(6): 579-584.

TAN Shuai, SUN Dan, WANG Hai-yan*, HOU Tian-li, XIAO Zhong-Xing, TANG You-gen. Preparation and Electrochemical Properties of Flake-like LiV₃O₈ by Soft Template Assisted Sol-gel Method as Anode Material for Aqueous Li-ion Battery[J]. Journal of Electrochemistry, 2013, 19(6): 579-584.

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https://electrochem.xmu.edu.cn/CN/Y2013/V19/I6/579

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片状LiV₃O₈软模板辅助溶胶凝胶法制备及其在水系锂离子电池中的性能研究

Preparation and Electrochemical Properties of Flake-like LiV₃O₈ by Soft Template Assisted Sol-gel Method as Anode Material for Aqueous Li-ion Battery

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