ZnO-聚苯胺复合膜的制备和性能研究

电化学（中英文） ›› 2003, Vol. 9 ›› Issue (1): 30-35.

ZnO-聚苯胺复合膜的制备和性能研究

席燕燕,黄怀国,郑志新,董平,周剑章,吴玲玲,林仲华

厦门大学固体表面物理化学国家重点实验室化学系物理化学研究所,厦门紫金科技股份有限公司,厦门大学固体表面物理化学国家重点实验室化学系物理化学研究所,厦门大学固体表面物理化学国家重点实验室化学系物理化学研究所,厦门大学固体表面物理化学国家重点实验室化学系物理化学研究所,厦门大学固体表面物理化学国家重点实验室化学系物理化学研究所,厦门大学固体表面物理化学国家重点实验室化学系物理化学研究所福建　厦门361005 ,福建　厦门361000,福建紫金矿冶研究院福建紫金矿业股份有限公司,福建龙岩364200 ,福建　厦门361005 ,福建　厦门361005 ,福建　厦门361005 ,福建　厦门361005 ,福建　厦门361005

收稿日期:2003-02-28 修回日期:2003-02-28 出版日期:2003-02-28 发布日期:2003-02-28

The Preparation and Characterization of ZnO-PANI Composite Film

XI Yan_yan1, HUANG Huai_guo2,3, ZHENG Zhi_xin, DONG Ping1,ZHOU Jian_zhang1, WU Ling_ling1, LIN Zhong_hua1 Department of Chemistry,Institute of Physical Chemistry, Xiamen University, Xiamen 361005,China, 2. Xiamen Zijin Science and Technology Co., LTD., Xiamen 361005,China, 3. Fujian Zijin Research Institute of Mining and Metallurgy, Fujian Zijin Mining Industry Co., LTD., Longyan 364200, China)

Received:2003-02-28 Revised:2003-02-28 Published:2003-02-28 Online:2003-02-28

摘要/Abstract

摘要： 　利用溶胶-凝胶法在Au膜、聚苯胺膜(PANI)和ITO(导电玻璃)基体上制备ZnO纳米微粒膜,初步研究了该微粒膜的形貌,结构和紫外-可见吸收等性质.结果表明,PANI的孔洞结构抑制了ZnO颗粒的团聚,因此,ZnO-PANI复合膜的紫外-可见吸收光谱和荧光光谱相对于ZnO-Au微粒膜有一定程度的蓝移.光电流谱研究同时表明,ZnO-聚苯胺复合膜有望在光电化学方面得到应用.

关键词: ZnO, 聚苯胺, 复合膜, 纳米微粒

Abstract: ZnO nanoparticle films were prepared on the Au film, PANI film and ITO by sol_gel method, and their morphological optical and photoelectrochemical properties were also studied. The results showed that the porous structure of PANI can suppress the aggregation of ZnO particles, resulting in the blue shift of on_set in the UV_Vis spectra and fluorescence spectra of ZnO_PANI composite film compared with that of ZnO_Au film. It was suggested that the ZnO_PANI composite film can be used in photoelectric coversion.

中图分类号:

TB43

席燕燕, 黄怀国, 郑志新, 董平, 周剑章, 吴玲玲, 林仲华. ZnO-聚苯胺复合膜的制备和性能研究[J]. 电化学（中英文）, 2003, 9(1): 30-35.

XI Yan_yan, HUANG Huai_guo, ZHENG Zhi_xin, DONG Ping, ZHOU Jian_zhang, WU Ling_ling, LIN Zhong_hua Department of Chemistry, Institute of Physical Chemistry, Xiamen University, Xiamen , China, . Xiamen Zijin Science and Technology Co., LTD., Xiamen , China, . Fujian Zijin Research Institute of Mining and Metallurgy, Fujian Zijin Mining Industry Co., LTD., Longyan , China) . The Preparation and Characterization of ZnO-PANI Composite Film[J]. Journal of Electrochemistry, 2003, 9(1): 30-35.

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https://electrochem.xmu.edu.cn/CN/Y2003/V9/I1/30

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