多级树状纳米结构聚苯胺的电化学制备

doi:10.61558/2993-074X.2945

电化学（中英文） ›› 2013, Vol. 19 ›› Issue (2): 130-134. doi: 10.61558/2993-074X.2945

多级树状纳米结构聚苯胺的电化学制备

翁少煌², 周剑章^1*, 林仲华¹, 林新华²

1. 厦门大学固体表面物理化学国家重点实验室，化学化工学院化学系，福建厦门361005； 2. 福建医科大学药学院药物分析学系，福建福州 350004

收稿日期:2011-11-17 修回日期:2012-01-05 出版日期:2013-04-28 发布日期:2012-01-15
通讯作者: 周剑章 E-mail:jzzhou@xmu. edu. cn
基金资助:
国家自然科学基金项目（No. 21021002）、福建省自然科学基金(No. 2011J05023)和厦门大学固体表面物理化学国家重点实验室开放课题资助

Electrochemical synthesis of hierarchical dendritic polyaniline nanostructures

WENG Shao-Huang², ZHOU Jian-Zhang¹*, LIN Zhong-Hua¹, LIN Xin-Hua²

1. State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China; 2. Department of Pharmaceutical Analysis, Faculty of Pharmacy, Fujian Medical University, Fuzhou 350004, China

Received:2011-11-17 Revised:2012-01-05 Published:2013-04-28 Online:2012-01-15
Contact: ZHOU Jian-Zhang E-mail:jzzhou@xmu. edu. cn

摘要/Abstract

摘要： 建立一种无模板的恒电位电聚合方法，可在室温下制备对甲基苯磺酸（p-TSA）掺杂的多级树状纳米结构聚苯胺（PANI）.根据电聚合曲线分析了PANI的聚合机理.扫描电镜（SEM）、透射电镜（TEM）观察表明制备的PANI具有均匀的多级树状纳米结构.紫外可见吸收光谱（UV-Vis）和红外光谱（FTIR）则显示所制备的PANI为掺杂态.该电沉积方法具有简便、易操作的特点，还可应用于其他纳米结构导电聚合物的可控制备.

关键词: 电化学制备, 多级树状纳米结构, 聚苯胺

Abstract: In this work, the p-TSA doped and hierarchical dendritic nanostructured polyanilines (PANI) have been prepared by potentiostatic electropolymerization without using any templates at room temperature. The mechanism of the polymerization has been discussed according to the electrodeposition curves. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were employed to confirm the formation of uniform hierarchical dendritic structure on PANI. UV-Vis spectroscopy (UV-Vis) and infrared spectroscopy (FTIR) proved that the prepared PANI is in the form of emeraldine salt. The templateless electrodeposition method is simple, easy to operate, can be applied to fabricate other nanostructures of conducting polymers.

中图分类号:

O646

翁少煌, 周剑章, 林仲华, 林新华. 多级树状纳米结构聚苯胺的电化学制备[J]. 电化学（中英文）, 2013, 19(2): 130-134.

WENG Shao-Huang, ZHOU Jian-Zhang, LIN Zhong-Hua, LIN Xin-Hua. Electrochemical synthesis of hierarchical dendritic polyaniline nanostructures[J]. Journal of Electrochemistry, 2013, 19(2): 130-134.

参考文献

[1] Zhou J Z (周剑章), Weng S H (翁少煌), Lin Z H(林仲华). Redox state of polyaniline nanodot and its coulomb staircase effect [J]. Journal of Electrochemistry (电化学), 2009, 15(3): 241-244.
[2] Qi Li (齐丽), Zhou J Z (周剑章), Weng S H (翁少煌), et al. Size effect of conductivities of polyaniline nanowires[J]. Chemical Journal of Chinese Universities(高等学校化学学报), 2007, 28(3): 562-564.
[3] Wan M X. Some issues related to polyaniline micro-/nanostructures [J]. Macromolecular Rapid Communications, 2009, 30(12): 963-975.
[4] Li D, Kaner R B. Shape and aggregation control of nanoparticles: not shaken, not stirred [J]. Journal of the American Chemical Society, 2006, 128(3): 968-975.
[5] Zhou C Q, Han J, Guo R. Controllable synthesis of polyaniline multidimensional architectures: from plate-like structures to flower-like superstructures [J]. Macromolecules, 2008, 41(17): 6473-6479.
[6] Zhu Y, Li J M, Wan M X, et al. 3D-boxlike polyaniline microstructures with super-hydrophobic and high-crystalline properties [J]. Polymer, 2008, 49(16): 3419-3423.
[7] Zhu Y, Hu D, Wan M X, et al. Conducting and superhydrophobic rambutan-like hollow spheres of polyaniline [J]. Advanced Materials, 2007, 19(16): 2092-2096.
[8] Zhou C Q, Han J, Guo R. Dilute anionic surfactant solution route to polyaniline rectangular sub-microtubes as a novel nanostructure [J]. Journal of Physical Chemistry B, 2008, 112(16): 5014-5019.
[9] Zhou C Q, Han J, Guo R. Synthesis of polyaniline hierarchical structures in a dilute SDS/HCl solution: nanostructure-covered rectangular tubes [J]. Macromolecules, 2009, 42(4): 1252-1257.
[10] Zhang X T, Song W H. Potential controlled electrochemical assembly of chiral polyaniline with enhanced stereochemical selectivity [J]. Polymer, 2007, 48(19): 5473-5479.
[11]: Zhang X T, Song W H, Harris P J F, et al. Electrodeposition of chiral polymer-carbon nanotube composite films [J]. ChemPhysChem, 2007, 8(12): 1766-1769.
12：Li W G, Wang H L, Electrochemical synthesis of optically active polyaniline films [J]. Advanced Functional Materials, 2005, 15 (11): 1793-1798.
13: Shim Y B, Park S M. Electrochemistry of conductive polymers VII. autocatalytic rate constant for polyaniline growth [J]. Synthetic Metals, 1989, 29(1): 169-174.
[14]: Wei Y, Jang G W, Chan C C, et al. Polymerization of aniline and alkyl ring-substituted anilines in the presence of aromatic additives [J]. Journal of Physical Chemistry, 1990, 94(19): 7716-7721.
15: Xing S X, Zheng H W, Zhao G K. Preparation of polyaniline nanofibers via a novel interfacial polymerization method [J]. Synthetic Metals, 2008, 158(1/2): 59-63.
16: MacDiarmid A G, Epstein A J. Secondary doping in polyaniline [J]. Synthetic Metals, 1995, 65(1/3): 85-92.
17: Zhang L J, Peng H, Kilmartin P A, et al. Poly(3,4-ethylenedioxythiophene) and polyaniline bilayer nanostructures with high conductivity and electrocatalytic activity [J]. Macromolecules, 2008, 41(20): 7671-7678.
18: Neoh K G, Pun M Y, Kang E T, et al. Polyaniline treated with organic acids: doping characteristics and stability [J]. Synthetic Metals, 1995, 73(3): 209-215.

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多级树状纳米结构聚苯胺的电化学制备

Electrochemical synthesis of hierarchical dendritic polyaniline nanostructures

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