焦耳热快速合成双功能电催化剂用于高效水分解

doi:10.13208/j.electrochem.2214007

摘要/Abstract

摘要：

电解水是有效的产氢方式之一, 开发具有高催化活性的电极材料是当前电解水的研究热点,但仍面临诸多挑战。本研究报告了一种通过焦耳热技术快速制备多金属异质结构, 并将其用作电解水的双功能电催化剂, 展现出优异的电解水催化活性。通过焦耳热处理三种金属前驱涂覆的碳布, Mo₂C和CoO/Fe₃O₄异质结构形成。当其用作析氢（HER）和析氧（OER）的双功能催化剂时, 仅需121 mV和268 mV的过电位,可以实现10 mA·cm^-2的电流密度。当用于两电极电解水时, MoC/FeO/CoO/CC作为阳极和阴极催化剂表现出优异的电催化性能和长期稳定性, 仅需1.69 V即可实现10 mA·cm^-2的电流密度, 并且展现出25小时的稳定性。本研究通过简单、快速的焦耳热技术实现了双金属/多金属异质结构的构筑,并应用于高效水电解,为合理设计多金属异质结构提供指导。

关键词: 氢析出反应, 氧析出反应, 双功能电催化剂, 水分解, 焦耳热

Abstract:

Water electrolysis is an available way to obtain green hydrogen. The development of highly efficient electrocatalysts is a current research hotspot for water splitting, but it remains challenging. Herein, we demonstrate the synthesis of a robust bifunctional multi-metal electrocatalysts toward water splitting via the rapid Joule-heating conversion of metal precursors. The composition and morphology were well regulated via altering the ratio of metal precursors. In particular, the trimetal MoC/FeO/CoO/carbon cloth (CC) electrode revealed the outstanding bifunctional electrocatalytic performance due to the unique composition and large electrochemical active surface area. Typically, the MoC/FeO/CoO/CC catalyst needed low overpotentials of 121 and 268 mV to reach 10 mA·cm^-2 toward HER and OER in 1 mol·L^-1 KOH solution, respectively. When used as both cathode and anode, a small potential of 1.69 V was required to achieve 10 mA·cm^-2 for overall water splitting and an impressive stability for 25 h was observed. This facile and rapid Joule heating strategy offers guideline for rational manufacture of bimetal or multi-metal electrocatalysts toward diverse application.

Key words: hydrogen evolution reaction, oxygen evolution reaction, bifunctional electrocatalyst, water splitting, Joule heating

周澳, 郭伟健, 王月青, 张进涛. 焦耳热快速合成双功能电催化剂用于高效水分解[J]. 电化学（中英文）, 2022, 28(9): 2214007.

Ao Zhou, Wei-Jian Guo, Yue-Qing Wang, Jin-Tao Zhang. The Rapid Preparation of Efficient MoFeCo-Based Bifunctional Electrocatalysts via Joule Heating for Overall Water Splitting[J]. Journal of Electrochemistry, 2022, 28(9): 2214007.

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链接本文: https://electrochem.xmu.edu.cn/CN/10.13208/j.electrochem.2214007

https://electrochem.xmu.edu.cn/CN/Y2022/V28/I9/2214007

图/表 6

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