络合还原法制备碳载钯纳米粒子及其电催化甲酸氧化

doi:10.61558/2993-074X.2012

电化学（中英文） ›› 2009, Vol. 15 ›› Issue (4): 382-386. doi: 10.61558/2993-074X.2012

络合还原法制备碳载钯纳米粒子及其电催化甲酸氧化

何卫;康永印;杜翀;邹志青;张校刚;杨辉;

南京航空航天大学材料科学与技术学院;中国科学院上海微系统与信息技术研究所;

收稿日期:2009-11-28 修回日期:2009-11-28 出版日期:2009-11-28 发布日期:2009-11-28

Complex Reduction Preparation of Carbon Supported Pd Nanoparticle Catalyst and its Electrocatalysis for Formic Acid Oxidation

HE Wei1,KANG Yong-yin2,DU Chong2,ZOU Zhi-qing2,ZHANG Xiao-gang1,YANG Hui2*

(1.College of Materials Science and Engineering,Nanjing University of Aeronautics and Astronautics,Nanjing 210016,China;2.Energy Science and Technology Laboratory,Shanghai Institute of Microsystem and Information Technology,Chinese Academy of Sciences,Shanghai 200050,China

Received:2009-11-28 Revised:2009-11-28 Published:2009-11-28 Online:2009-11-28

摘要/Abstract

摘要： 应用柠檬酸钠络合还原法制备了粒径小、分布均匀的碳载Pd纳米粒子(Pd/C).由于柠檬酸钠的络合作用,有效地降低了Pd粒子在形成过程中的团聚.经过简单的热处理调控Pd粒子大小,发现随热处理温度的升高,Pd粒子直径由初始的2.7 nm增大到5.8 nm左右.电化学测试表明Pd/C的Pd粒子尺寸越小,电催化甲酸氧化的质量比活性越高,但如当Pd粒径较大,则催化剂呈现出更高的面积比活性.Pd粒径为3.6 nm的催化剂,其电催化甲酸氧化的稳定性最好.

关键词: Pd/C催化剂, 柠檬酸钠, 络合还原, 甲酸氧化, 尺寸效应

Abstract: A simple procedure involved the complexing of PdCl2 with sodium citrate followed by ethylene glycol reduction has been employed for the preparation of carbon-supported Pd nanoparticles(Pd/C).The XRD and TEM characterizations indicate that Pd nanoparticles with a small particle size were well-dispersed on carbon support.The mean particle sizes of the Pd/C catalysts were found to be increased from 2.7 to 5.8 nm with heat-treatments at different temperature.The mass activity of the Pd/C catalyst for formic acid electrooxidation increased with the decrease in Pd particle size.However,the specific activity increased with Pd particle size.Furthermore,the Pd/C catalyst with a particle size of ca.3.6 nm exhibited the best stability.

Key words: Pd/C catalyst, sodium citrate, complex-reduction, formic acid oxidation, particle size effect

中图分类号:

O646.54

何卫, 康永印, 杜翀, 邹志青, 张校刚, 杨辉, . 络合还原法制备碳载钯纳米粒子及其电催化甲酸氧化[J]. 电化学（中英文）, 2009, 15(4): 382-386.

HE Wei, KANG Yong-yin, DU Chong, ZOU Zhi-qing, ZHANG Xiao-gang, YANG Hui. Complex Reduction Preparation of Carbon Supported Pd Nanoparticle Catalyst and its Electrocatalysis for Formic Acid Oxidation[J]. Journal of Electrochemistry, 2009, 15(4): 382-386.

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https://electrochem.xmu.edu.cn/CN/Y2009/V15/I4/382

参考文献

[1]Sun S G,Clavilier J,Bewick A.The mechanism ofelectrocatalytic oxidation of formic acid on Pt(100)and Pt(111)in sulphuric acid solution:an EMIRSstudy[J].J Electroanal Chem,1988,240(1/2):147-159. [2]Zhang L L,Tang Y W,Bao J C,et al.A carbon-sup-ported Pd-P catalyst as the anodic catalyst in a directformic acid fuel cell[J].J Power Sources.2006,162(1):177-179. [3]Wang J,Kang Y,Yang H,et al.Boron-doped palla-dium nanoparticles on carbon black as a superior cata-lyst for formic acid electro-oxidation[J].J Phys ChemC,2009,113(19):8366-8372. [4]Hoshi N,Kida K,Nakamura M,et al.Structural effectsof electrochemical oxidation of formic acid on singlecrystal electrodes of palladium[J].J Phys Chem B,2006,110(25):12480-12484. [5]Park S,Xie Y,Weaver M J.Electrocatalytic pathwayson carbon-supported platinum nanoparticles:Compari-son of particle-size-dependent rates of methanol,formicacid,and formaldehyde electrooxidation[J].Lang-muir,2002,18(15):5792-5798. [6]Kim J,Jung C,Rhee C K,et al.Electrocatalytic oxi-dation of formic acid and methanol on Pt deposits on Au(111)[J].Langmuir,2007,23(21):10831-10836. [7]Chen Y(陈滢),Tang Y W(唐亚文),Gao Y(高颖),et al.Electrocatalytic performance of Pd/C catalyst pre-pared with improved liquid phase reduction method foroxidation of formic acid[J].Chinese Journal of Inor-ganic Chemistry(in Chinese).2008,24(4):560-564. [8]Li HQ,Sun G Q,Jiang QA,et al.Synthesis of highlydispersed Pd/C electro-catalyst with high activity forformic acid oxidation[J].Electrochem Commun,2007,9(6):1410-1415. [9]Zhu Y,Kang Y,Zou Z,et al.A facile preparation ofcarbon-supported Pd nanoparticles for electrocatalyticoxidation of formic acid[J].Electrochem Commun,2008,10(5):802-805. [10]Chen Y,Tang Y W,Liu C P,et al.Room tempera-ture preparation of carbon supported Pt-Ru catalysts[J].J Power Sources,2006,161(1):470-473. [11]Meng H,Sun S,Masse J,et al.Electrosynthesis ofPd single-crystal nanothorns and their application inthe oxidation of formic acid[J].Chem Mater,2008,20(22):6998-7002. [12]Zhou W J,Lee J Y.Particle size effects in Pd-cata-lyzed electrooxidation of formic acid[J].J Phys ChemC,2008,112(10):3789-3793.

络合还原法制备碳载钯纳米粒子及其电催化甲酸氧化

Complex Reduction Preparation of Carbon Supported Pd Nanoparticle Catalyst and its Electrocatalysis for Formic Acid Oxidation

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