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电化学(中英文) ›› 2010, Vol. 16 ›› Issue (1): 96-101.  doi: 10.61558/2993-074X.2046

• 研究论文 • 上一篇    下一篇

MnO_2/聚苯胺复合材料的电化学电容

徐小存;刘开宇;殷志刚;孙哲;苏耿;   

  1. 中南大学化学化工学院;
  • 收稿日期:2010-02-28 修回日期:2010-02-28 出版日期:2010-02-28 发布日期:2010-02-28

Electrochemical Capacitance of MnO_2 /PANI Composite

XU Xiao-cun,LIU Kai-yu*,YIN Zhi-gang,SUN Zhe,SU Geng   

  1. (College of Chemistry and Chemical engineering,Central South University,Changsha 410083,Hunan,China
  • Received:2010-02-28 Revised:2010-02-28 Published:2010-02-28 Online:2010-02-28

摘要: 以P123为模板剂,软模板法制备出纳米MnO2.酸性条件下引入苯胺并聚合,得到了MnO2/聚苯胺复合材料.X射线衍射(XRD)、红外光谱(IR),扫描电子显微镜(SEM)表征观察样品的结构、形貌.循环伏安、交流阻抗、恒电流充放电等测试MnO2/聚苯胺电极的电化学性能.结果表明:引入苯胺改变了样品纳米MnO2的形貌.MnO2/聚苯胺电极比容量高达190.8F·g-1,500次循环电极比容量仅衰减4.7%,库仑效率均保持在97%以上.

关键词: MnO2, 聚苯胺, 复合材料, 超级电容器, 电化学性能, 软模板

Abstract: Nano-MnO2 was prepared by using P123 as a soft template.The MnO2 /polyaniline composite was further prepared by polymerization of aniline with the nano-MnO2 in acidic conditions and was investigated by XRD and IR.The morphology of nano-MnO2 observed by SEM was changed with the introduction of aniline.The electrochemical properties of MnO2 /PANI electrode were investigated using cyclic voltammetry,galvanostatic charge-discharge and electrochemical impedance spectroscopy.The specific capacitance of MnO2 /PANI electrode could reach as high as 190.8 F·g-1,which decayed only 4.7% over 500 cycles.And the coulombic efficiency has been maintained at above 97%.

Key words: MnO2, polyaniline, composites, supercapacitor, electrochemical property soft-template

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