电化学(中英文) ›› 2022, Vol. 28 ›› Issue (8): 2110191. doi: 10.13208/j.electrochem.211019
罗大娟, 刘冰倩*(), 覃蒙颜, 高荣, 苏丽霞, 苏永欢
收稿日期:
2021-10-20
修回日期:
2021-12-20
出版日期:
2022-08-28
发布日期:
2022-01-10
通讯作者:
* Tel: (86-851)8830717, E-mail: 基金资助:
Da-Juan Luo, Bing-Qian Liu*(), Meng-Yan Qin, Rong Gao, Li-Xia Su, Yong-Huan Su
Received:
2021-10-20
Revised:
2021-12-20
Published:
2022-08-28
Online:
2022-01-10
摘要:
亚硝酸盐是一种广泛存在的原料,长期食用会对人体健康不利甚至致癌。因此,简单、灵敏的亚硝酸盐检测方法的开发具有非常重要的意义。本文合成了金/还原氧化石墨烯/羟基氧化铁(Au/rGO/FeOOH)复合材料,并通过SEM、 XRD和EDX等测试进行了材料表征。将合成的复合材料滴涂在氧化氟锡(FTO)电极表面,利用它们的协同催化氧化性能,成功构建了一步检测亚硝酸盐(NO2-)的新型电化学传感器。在最佳优化实验条件下, 通过差分脉冲伏安法实现NO2-的定量检测, 其线性范围为0.001 ~ 5 mmol·L-1, 检出限为0.8 μmol·L-1(S/N = 3), 且响应时间小于2 s。同时, 所制备的传感器表现出良好的选择性和重现性, 也能用于实际样品的测定。
罗大娟, 刘冰倩, 覃蒙颜, 高荣, 苏丽霞, 苏永欢. 基于Au/rGO/FeOOH的新型电化学传感器一步检测亚硝酸盐[J]. 电化学(中英文), 2022, 28(8): 2110191.
Da-Juan Luo, Bing-Qian Liu, Meng-Yan Qin, Rong Gao, Li-Xia Su, Yong-Huan Su. A Novel Electrochemical Sensor Based on Au/rGO/FeOOH for One-Step Detection of Nitrite[J]. Journal of Electrochemistry, 2022, 28(8): 2110191.
表1
NO2-检测方法的比较
Method | Linear range (mmol·L-1) | Detected limit (μmol·L-1) | Ref. |
---|---|---|---|
HPLC | 0.001 ~ 0.8 | 0.075 | [16] |
Colorimetric method | 0.05 ~ 1 | 25 | [17] |
Fluorescent assay | 0.01 ~ 0.225 | 3.4 | [18] |
Spectrophotometric method | 0.01 ~ 0.84 | 0.39 | [19] |
Differential pulse voltammetry | 0.005 ~ 0.8 | 1.5 | [20] |
Amperometric method | 0.0049 ~ 1.184 | 3.3 | [21] |
Cyclic voltammetry | 0 ~ 1.38×104 | 1.39 | [22] |
Differential pulse voltammetry | 0.0025 ~ 1.25 | 0.15 | [23] |
Amperometric method | 0.002 ~ 0.425 | 0.7 | [24] |
Amperometric method | 0.001 ~ 1 | 0.018 | [25] |
Differential pulse voltammetry | 12 ~ 1.2×103 | 11.4 | [26] |
Electrochemical sensor | 0.001 ~ 5 | 0.8 | This work |
[1] |
Shpaizer A, Nussinovich A, Kanner J, Tirosh O. S-nitroso-N-acetylcysteine generates less carcinogenic N-nitrosamines in meat products than nitrite[J]. J. Agric. Food Chem., 2018, 66(43): 11459-11467.
doi: 10.1021/acs.jafc.8b04549 URL |
[2] | Du J(杜娟), Wang Q H(王青华), Liu L Q(刘利强). Nitrite application harmful analys is and its subs titute research in meat product[J]. Food Sci. Technol.(食品科技), 2007, (8): 166-169. |
[3] | Li G(李刚), Qin C M(覃春美), Zhang Y(张燕), Yin L(尹雷), Wang D J(汪代杰). Diethyl nitrosamine induced increased IFN-λ expression in early hepatocellular carcinoma of rats[J]. Basic Clin. Med. (基础医学与临床), 2019, 39(3): 402-403. |
[4] | Sheng L(盛丽), Zhu J L(朱金林), Han X Q(韩小茜), Wang H X(王海霞). Fluorospectrophotometric determination of traces of nitrite ion by its fluorescence quenching effect oil thionine[J]. Phys. Test. Chem. Anal. (Part B)(理化检验(化学分册)), 2008, 44(12): 1182-1183+1186. |
[5] |
Higuchi K, Motomizu S. Flow-injection spectrophotometric determination of nitrite and nitrate in biological samples. Original papers[J]. Anal. Sci., 1999, 15(2): 129-134.
doi: 10.2116/analsci.15.129 URL |
[6] |
Ding X L, Yang J, Dong Y M. Advancements in the preparation of high-performance liquid chromatographic organic polymer monoliths for the separation of small-molecule drugs[J]. J. Pharm. Anal., 2018, 8(2): 75-85.
doi: 10.1016/j.jpha.2018.02.001 URL |
[7] |
Kozub B R, Rees N V, Compton R G. Electrochemical determination of nitrite at a bare glassy carbon electrode; why chemically modify electrodes?[J]. Sens. Actuator B-Chem., 2010, 143(2): 539-546.
doi: 10.1016/j.snb.2009.09.065 URL |
[8] |
Tajiki A, Abdouss M, Sadjadi S, Mazinani S. Voltammetric detection of nitrite anions employing imidazole functionalized reduced graphene oxide as an electrocatalyst[J]. Electroanalysis, 2020, 32(10): 2290-2298.
doi: 10.1002/elan.202060187 URL |
[9] | Lei P, Zhou Y, Zhu R Q, Wu S, Jiang C B, Dong C, Liu Y, Shuang S M. Gold nanoparticles decorated bimetallic CuNi-based hollow nanoarchitecture for the enhancement of electrochemical sensing performance of nitrite[J]. Micro-chim. Acta, 2020, 187(10): 572. |
[10] |
Iqbal W, Batool M, Hameed A, Abbas S, Nadeem M A. Boosting the activity of FeOOH via integration of ZIF-12 and graphene to efficiently catalyze the oxygen evolution reaction[J]. Int. J. Hydrog. Energy, 2021, 46(49): 25050-25059.
doi: 10.1016/j.ijhydene.2021.05.037 URL |
[11] |
Li C C, Chen D L, Wang Y Y, Lai X Y, Peng J, Wang X H, Zhang K X, Cao Y. Simultaneous electrochemical detection of nitrite and hydrogen peroxide based on 3D Au-rGO/FTO obtained through a one-step synthesis[J]. Sensors, 2019, 19(6): 1304.
doi: 10.3390/s19061304 URL |
[12] | Shi W P(石维平), Cai J(蔡杰), Yang Y N(杨雅妮), Luo H H(罗欢欢), Liu B Q(刘冰倩), Fu Q P(付秋平). Portable glucose meter for detection of mercury (II) ion[J]. Chin. J. Anal. Chem.(分析化学), 2019, 47(9): 1337-1343. |
[13] |
Zhou Q, Lin Y X, Shu J, Zhang K Y, Yu Z Z, Tang D P. Reduced graphene oxide-functionalized FeOOH for signal-on photoelectrochemical sensing of prostate-specific antigen with bioresponsive controlled release system[J]. Biosens. Bioelectron., 2017, 98: 15-21.
doi: 10.1016/j.bios.2017.06.033 URL |
[14] |
Zou L N, Yang L X, Zhan Y, Huang D, Ye B X. Photoelec-trochemical aptasensor for thrombin based on Au-rGO-CuS as signal amplification elements[J]. Microchim. Acta, 2020, 187(8): 433.
doi: 10.1007/s00604-020-04380-x URL |
[15] |
Duan C Q, Bai W S, Zheng J B. Non-enzymatic sensors based on a glassy carbon electrode modified with Au nanoparticles/polyaniline/SnO2 fibrous nanocomposites for nitrite sensing[J]. New J. Chem., 2018, 42(14): 11516-11524.
doi: 10.1039/C8NJ01461B URL |
[16] |
Wu A G, Duan T T, Tang D, Xu Y H, Feng L, Zheng Z G, Zhu J X, Wang R S, Zhu Q. Determination of nitric oxide-derived nitrite and nitrate in biological samples by HPLC coupled to nitrite oxidation[J]. Chromatographia, 2013, 76(23-24): 1649-1655.
doi: 10.1007/s10337-013-2529-0 URL |
[17] |
Singhaphan P, Unob F. Thread-based platform for nitrite detection based on a modified Griess assay[J]. Sens. Actuator B-Chem., 2021, 327: 128938.
doi: 10.1016/j.snb.2020.128938 URL |
[18] |
Zhou D L, Huang H, Wang Y. Sensitive and selective detection of nitrite ions with highly fluorescent glutathione-stabilized copper nanoclusters[J]. Anal. Methods, 2017, 9(38): 5668-5673.
doi: 10.1039/C7AY02035J URL |
[19] |
Lo H S, Lo K W, Yeung C F, Wong C Y. Rapid visual and spectrophotometric nitrite detection by cyclometalated ruthenium complex[J]. Anal. Chim. Acta, 2017, 990: 135-140.
doi: 10.1016/j.aca.2017.07.018 URL |
[20] |
Yang Y J, Li W K. CTAB functionalized graphene oxide/multiwalled carbon nanotube composite modified electrode for the simultaneous determination of ascorbic acid, dopamine, uric acid and nitrite[J]. Biosens. Bioelectron., 2014, 56: 300-306.
doi: 10.1016/j.bios.2014.01.037 pmid: 24530832 |
[21] |
Sudha V, Kumar S M S, Thangamuthu R. Hierarchical porous carbon derived from waste amla for the simultaneous electrochemical sensing of multiple biomolecules[J]. Colloid Surf. B-Biointerfaces, 2019, 177: 529-540.
doi: 10.1016/j.colsurfb.2019.01.029 URL |
[22] |
Terbouche A, Lameche S, Ait-Ramdane-Terbouche C, Guerniche D, Lerari D, Bachari K, Hauchard D. A new electrochemical sensor based on carbon paste electrode/Ru (III) complex for determination of nitrite: Electroche-mical impedance and cyclic voltammetry measurements[J]. Measurement, 2016, 92: 524-533.
doi: 10.1016/j.measurement.2016.06.034 URL |
[23] |
Bao Z L, Zhong H, Li X R, Zhang A R, Liu Y X, Chen P, Cheng Z P, Qian H Y. Core-shell Au@Ag nanoparticles on carboxylated graphene for simultaneous electrochemical sensing of iodide and nitrite[J]. Sens. Actuator B-Chem., 2021, 345: 130319.
doi: 10.1016/j.snb.2021.130319 URL |
[24] |
Ghanei-Motlagh M, Taher M A. A novel electrochemical sensor based on silver/halloysite nanotube/molybdenum disulfide nanocomposite for efficient nitrite sensing[J]. Biosens. Bioelectron., 2018, 109: 279-285.
doi: S0956-5663(18)30158-1 pmid: 29573727 |
[25] | Zhou F L(周福玲), Xiong X L(熊小莉), Sun X P(孙旭平). High-efficiency nitrite sensor based on CoP nano-wire array[J]. J. Electrochem. (电化学), 2019, 25(2): 252-259. |
[26] | Luo T R(罗婷容), Shi W P(石维平), Liu B Q(刘冰倩), Nie F Q(聂方钦), Deng X J(邓雪锦), Liu Y Z(刘跃芝). A label-free homogenous electrochemical sensor for rapid detection of NO2- in water[J]. Chin. J. Anal. Lab.(分析试验室), 2019, 38(9): 1035-1038. |
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