基于碳复合Fe3O4纳米粒子的过氧化氢电化学传感器研究

doi:10.13208/j.electrochem.170506

电化学（中英文） ›› 2018, Vol. 24 ›› Issue (3): 279-284. doi: 10.13208/j.electrochem.170506

基于碳复合Fe₃O₄纳米粒子的过氧化氢电化学传感器研究

张思宇，王会娟，李书芳，屈建莹^*

河南大学化学化工学院环境与分析科学研究所，河南开封 475004

收稿日期:2017-05-06 修回日期:2017-09-09 出版日期:2018-06-28 发布日期:2017-09-17
通讯作者: 屈建莹 E-mail:qujy@henu.edu.cn
基金资助:
河南省高校科技创新团队支持计划（No. 15IRTSTHN019）资助

Carbon Composite Fe₃O₄ Nanoparticles Based Electrochemical Sensor for Hydrogen Peroxide Detection

ZHANG Si-yu, WANG Hui-juan, LI Shu-fang, QU Jian-ying^*

Institute of Environmental and Analytical Sciences, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475004, Henan, China

Received:2017-05-06 Revised:2017-09-09 Published:2018-06-28 Online:2017-09-17
Contact: QU Jian-ying E-mail:qujy@henu.edu.cn

摘要/Abstract

摘要： 本文以碳纳米粒子复合Fe₃O₄磁性纳米粒子构建新型过氧化氢电化学传感器，该传感器对过氧化氢有良好的电催化性能，过氧化氢浓度在1.00×10^-6 ~ 1.00×10^-3 mol·L^-1范围内与其氧化峰电流之间呈良好线性关系(R = 0.9980)，检出限为6.60×10^-7 mol·L^-1. 该传感器具有良好的抗干扰能力、较高的重现性和稳定性.

关键词: 过氧化氢, Fe₃O₄纳米粒子, 碳纳米粒子

Abstract: In this work, a novel hydrogen peroxide electrochemical sensor was constructed with ferroferric oxide (Fe₃O₄) magnetic nanoparticles, which demonstrated good electrocatalytic activity for hydrogen peroxide. There existed a good linear relationship between the concentration of hydrogen peroxide and the oxidation peak current in the range of 1.00 × 10^-6 ~ 1.00 × 10^-3 mol·L^-1 (R = 0.9980) with the detection limit of 6.60 × 10-7 mol·L^-1. The sensor exhibited good anti-interference ability, high reproducibility and stability.

Key words: hydrogen peroxide, Fe₃O₄ nanoparticles, carbon nanoparticles

中图分类号:

O646
O657.1

张思宇，王会娟，李书芳，屈建莹. 基于碳复合Fe₃O₄纳米粒子的过氧化氢电化学传感器研究[J]. 电化学（中英文）, 2018, 24(3): 279-284.

ZHANG Si-yu, WANG Hui-juan, LI Shu-fang, QU Jian-ying. Carbon Composite Fe₃O₄ Nanoparticles Based Electrochemical Sensor for Hydrogen Peroxide Detection[J]. Journal of Electrochemistry, 2018, 24(3): 279-284.

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链接本文: https://electrochem.xmu.edu.cn/CN/10.13208/j.electrochem.170506

https://electrochem.xmu.edu.cn/CN/Y2018/V24/I3/279

参考文献

[1] Giorgio M, Trinei M, Migliaccio E, et al. Hydrogen peroxide: a metabolic by-product or a common mediator of ageing signals?[J]. Nature Reviews Molecular Cell Biology, 2007, 8(9): 722-728.
[2] Zhang R Z, Chen W. Recent advances in graphene-based nanomaterials for fabricating electrochemical hydrogen peroxide sensors[J]. Biosensors and Bioelectronics, 2017, 89(S1): 249-268.
[3] Ge S G, Liu W Y, Liu H Y, et al. Colorimetric detection of the flux of hydrogen peroxide released from living cells based on the high peroxidase-like catalytic performance of porous PtPd nanorods[J]. Biosensors and Bioelectronics, 2015, 71: 456-462.
[4] Zheng L Z(郑龙珍), Li Y D(李引弟), Xiong L Y(熊乐艳), et al. Graphene-polydopamine nanocomposite preparation of hydrogen peroxide biosensor[J]. Chinese Journal of Analytical Chemistry (分析化学研究报告), 2012, 1(40): 72-76.
[5] Shi Y, Su P, Wang Y Y, et al. Fe₃O₄ peroxidase mimetics as a general strategy for the fluorescent detection of H₂O₂-involved systems[J]. Talanta, 2014, 130: 259-264.
[6] Yuan K F, Ni Y H, Zhang L. Facile hydrothermal synthesis of polyhedral Fe₃O₄ nanocrystals, influencing factors and application in the electrochemical detection of H₂O₂[J]. Journal of Alloys and Compounds, 2012, 532: 10-15.
[7] Liu Y, Zhou J, Gong J, et al. The investigation of electrochemical properties for Fe₃O₄@Pt nanocomposites and an enhancement sensing for nitrite[J]. Electrochimica Acta, 2013, 111: 876-887.
[8] Peng H P, Liang R P, Zhang L, et al. Facile preparation of novel core-shell enzyme-Au-polydopamine-Fe₃O₄ magnetic bionanoparticles for glucose sensor[J]. Biosensors and Bioelectronics, 2013, 42: 293-299.
[9] Zhang S, Liu X Y, Huang N, et al. Sensitive detection of hydrogen peroxide and nitrite based on silver/carbon nanocomposite synthesized by carbon dots as reductant via one step method[J]. Electrochimica Acta, 2016, 211: 36-43.
[10] Liu W(刘文), Wei Z P(魏志鹏), Zheng L Z(郑龙珍). Research progress of the catalytic property of Fe₃O₄ magnetic nanoparticles[J]. Chinese Journal of Spectroscopy Laboratory(光谱实验室), 2012, 29(4): 1956-1959.
[11] Liu H, Ye T, Mao C. Fluorescent carbon nanoparticles derived from candle soot[J]. Angewandte Chemie International Edition, 2007, 46(34): 6473-6475.
[12] Wang S S(王珊珊), Mi W Q(米渭清), Zhu H(朱红), et al. Synthesis of carbon by one step microwave method and its fluorescence properties[J]. Spectroscopy and Spectral Analysis(光谱学与光谱分析), 2012, 32(10): 2710-2713.
[13] Fang Y, Guo S, Li D, et al. Easy synthesis and imaging applications of cross-linked green fluorescent hollow carbon nanoparticles[J]. ACS Nano, 2011, 6(1): 400-409.
[14] Li H, Li F, Wang G, et al. One-step synthesis of fluorescent carbon nanoparticles for degradation of naphthol green under visible light[J]. Journal of Luminescence, 2014, 156: 36-40.
[15] Qu S N, Wang X Y, Lu Q P, et al. A biocompatible fluorescent ink based on water-soluble luminescent carbon nanodots[J]. Angewandte Chemie-International Edition, 2012, 51(49): 12215-12218.
[16] Cao L, Sahu S, Anilkumar P, et al. Carbon nanoparticles as visible-light photocatalysts for efficient CO₂ conversion and beyond[J]. Journal of the American Chemical Society, 2011, 133(13): 4754-4757.
[17] Liu J(刘杰), Wang S L(王树林), Cui T Y(崔体运), et al. Preparation and characterization of Fe₃O₄ magnetic nanoparticles[C]//颗粒学前沿问题研讨会暨第九届全国颗粒制备与处理研讨会，中国颗粒学会颗粒制备与处理专业委员会，中国，威海，2009: 179-181.
[18] He Z, Gudavarthy R V, Koza J A, et al. Room-temperature electrochemical reduction of epitaxial magnetitefilms to epitaxial iron films[J]. Journal of the American Chemical Society, 2011, 133(32): 12358-12361.
[19] Zhang Z X, Zhu H, Wang X L, et al. Sensitive electrochemical sensor for hydrogen peroxide using Fe₃O₄ magnetic nanoparticles as a mimic for peroxidase[J]. Micro-
chimica Acta, 2011, 174(1/2): 183-189.
[20] Zhang L, Zhou N J, Wang B, et al. Fabrication of Fe₃O₄/PAH/PSS@Pd core-shell microspheres by layer-by-layer assembly and application in catalysis[J]. Journal of Colloid and Interface Science, 2014, 421: 1-5.
[21] Yu C M, Wang Y D, Wang L, et al. Nanostructured bio-ensors built with layer-by-layer electrostatic assembly of hemoglobin and Fe₃O₄@Pt nanoparticles[J]. Colloids and Surfaces B: Biointerfaces, 2013, 103: 231-237.
[22] Wei H, Wang E. Fe3O4 magnetic nanoparticles as peroxidase mimetics and their applications in H₂O₂ and glucose detection[J]. Analytical Chemistry, 2008, 80(6): 2250-2254.
[23] Gao L Z, Zhuang J, Nie L, et al. Intrinsic peroxidase-like activity of ferromagnetic nanoparticles[J]. Nature Nanotechnology, 2007, 2(9): 577-583.
[24] Ma M, Xie J, Zhang Y, et al. Fe₃O₄@Pt nanoparticles with enhanced peroxidase-like catalytic activity[J]. Matericals Letters, 2013, 105: 36-39.
[25] Dong Y(董莹), Wang Y(王勇), Xing H H(邢欢欢), et al. Au/Fe₃O₄/chitosan nanometer compound detecting NO₂- electricity sensor[J]. Journal of Electrochemistry(电化学), 2015, 2(21): 85-90.
[26] Yuan K F, Ni Y H, Zhang L. Facile hydrothermal synthesis of polyhedral Fe₃O₄ nanocrystals, influencing factors and application in the electrochemical detection of H₂O₂[J]. Journal of Alloys and Compounds, 2012, 532: 10-15.
[27] Zhang L H, Zhai Y M, Gao N, et al. Sensing H2O2 with layer-by-layer assembled Fe₃O₄-PDDA nanocomposite film[J]. Electrochemistry Communications, 2008, 10(10): 1524-1526.
[28] Liu D, Guo Q H, Zhang X P, et al. PdCo alloy nanoparticle-embedded carbon nanofiber for ultrasensitive nonenzymatic detection of hydrogen peroxide and nitrite[J]. Journal of Colloid and Interface Science, 2015, 450: 168-173.
[29] Qu J Y, Lou T F, Kang S P, et al. Preparation of poly-(p-aminobenzoic acid)/multiwall carbon nanotubes composite film modified glassy carbon electrode and application to detect catechol and hydroquinone simultaneously[J]. Electrochemistry, 2013, 81(2): 82-85.

基于碳复合Fe₃O₄纳米粒子的过氧化氢电化学传感器研究

Carbon Composite Fe₃O₄ Nanoparticles Based Electrochemical Sensor for Hydrogen Peroxide Detection

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