静电纺丝技术在锂-空气电池上的应用

doi:10.13208/j.electrochem.161121

电化学（中英文） ›› 2018, Vol. 24 ›› Issue (1): 46-55. doi: 10.13208/j.electrochem.161121

• 电镀与表面精饰近期研究专辑( 哈尔滨工业大学安茂忠教授主编) • 上一篇下一篇

静电纺丝技术在锂-空气电池上的应用

付月^1,2，王金^1,2，于海洋^1,2，田景华^1,2*，杨瑞枝^1,2*

1. 苏州大学能源与材料创新研究院，苏州大学物理与光电?能源学部&苏州纳米科技协同创新中心，苏州，261005，江苏；2. 轻工业化学电源研究所，苏州大学，苏州，215600，江苏

收稿日期:2016-11-21 修回日期:2017-01-18 出版日期:2018-02-28 发布日期:2017-01-30
通讯作者: 田景华，杨瑞枝 E-mail:jhtian@suda. edu. cn; yangrz@suda.edu.cn
基金资助:
国家自然科学基金项目(No. 21303114, No. 21673153)，江苏省自然科学基金 (No. BK20161207), 江苏省高校自然科学研究面上项目(No. 15KJB480001)和厦门大学固体表面物理化学国家重点实验室开放课题 (No. 201515) 资助

Applications of Electrospinning in Lithium-Air Batteries

FU Yue^1,2, Wang Jin^1,2, YU Hai-yang ^1,2, TIAN Jing-hua^1,2*, YANG Rui-zhi^1,2*

1. Soochow Institute for Energy and Materials Innovations, College of Physics, Optoelectronics and Energy & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, 215006, Jiangsu；2. Institute of Chemical Power Sources, Soochow University, Suzhou, 215600, Jiangsu

Received:2016-11-21 Revised:2017-01-18 Published:2018-02-28 Online:2017-01-30
Contact: TIAN Jing-hua, YANG Rui-zhi E-mail:jhtian@suda. edu. cn; yangrz@suda.edu.cn

摘要/Abstract

摘要：

近年来，锂-空气电池由于具有极高的理论容量和对环境友好等优势，作为“终极电池”引起了广大科研工作者和电动汽车公司的极大兴趣和广泛关注. 但目前锂-空气电池还存在着充放电过电位大、循环性能差等局限性，寻找高效的锂-空气电池催化剂成为该领域发展的研究热点之一. 锂-空气电池阴极催化剂主要有贵金属、非贵金属、碳材料以及金属氧化物等，可通过多种方法合成制备，如水热(溶剂热)法、溶胶-凝胶法、共沉淀法、静电纺丝法等等. 其中，静电纺丝技术由于具有制备方法简易、高效且产量高等优点，近年来得到了长足的发展，可以用来大量制备锂-空气电池阴极催化剂，甚至制备自支撑结构的锂-空气电池阴极催化剂材料. 本文综述了静电纺丝技术在锂-空气电池上的应用，主要包括利用静电纺丝技术制备非贵金属催化剂、碳材料催化剂、金属氧化物催化剂和复合催化剂等，以及将制备的催化剂组装成锂-空气电池后表现出的优异的电池性能.

关键词: 锂-空气电池, 静电纺丝, 催化剂, 纳米纤维

Abstract:

Lithium-air batteries have received increasing attention as the “ultimate batteries” due to their extremely high theoretical capacity and environment friendly. However, there are still many obstacles hindering the wide applications of the lithium-air batteries owing to the limitations of large charge-discharge over-potentials, poor Columbic efficiency and cycling performance. Exploring of high-efficiency, low-cost and eco-friendly catalysts is one of the vital issues for lithium-air batteries. Meanwhile, electrospinning techniques have been under substantial developments due to its simple fabrication process, high efficiency and production. This paper reviews the recent progresses in fabrications of various novel catalysts for lithium-air batteries with electrospinning techniques, which mainly focuses on the non-precious metals catalysts, carbon-based catalysts, metal oxides catalysts and their hybrid composites.

Key words: lithium-air batteries, electrospinning, catalysts, nanofibers

中图分类号:

付月，王金，于海洋，田景华，杨瑞枝. 静电纺丝技术在锂-空气电池上的应用[J]. 电化学（中英文）, 2018, 24(1): 46-55.

FU Yue, Wang Jin, YU Hai-yang, TIAN Jing-hua, YANG Rui-zhi. Applications of Electrospinning in Lithium-Air Batteries[J]. Journal of Electrochemistry, 2018, 24(1): 46-55.

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静电纺丝技术在锂-空气电池上的应用

Applications of Electrospinning in Lithium-Air Batteries

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