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电化学(中英文) ›› 2017, Vol. 23 ›› Issue (1): 1-6.  doi: 10.13208/j.electrochem.160315

• 研究论文 • 上一篇    下一篇

负载型离子液体在C-H键电氧化活化中的应用研究

陈姿颖,武倩倩,张健青,朱英红*,马淳安*   

  1. 浙江工业大学化学工程学院,绿色化学合成技术国家重点实验室培育基地,浙江 杭州 310032
  • 收稿日期:2016-03-12 修回日期:2016-04-12 出版日期:2017-02-28 发布日期:2016-05-18
  • 通讯作者: 朱英红,马淳安 E-mail:science@zjut. edu. cn
  • 基金资助:

    973前期研究专项(No. 2012CB722604)资助

Application of Composite Ionic Liquid in Electro-oxidation Activation of a C-H Bond

CHEN Zi-ying, WU Qian-qian, ZHANG Jian-qing, ZHU Ying-hong*, MA Chun-an*   

  1. College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China
  • Received:2016-03-12 Revised:2016-04-12 Published:2017-02-28 Online:2016-05-18
  • Contact: ZHU Ying-hong, MA Chun-an E-mail:science@zjut. edu. cn

摘要:

本文将1-乙基-3-甲基咪唑醋酸盐离子液体修饰在多壁碳纳米管上,制备出离子液体/碳纳米管复合材料,并研究了对甲氧基甲苯(p-MT)在该复合离子液体水溶液体系中的电氧化性能. 同时,通过循环伏安法和计时电流法考查了扫描速率、温度、反应底物浓度等因素对电氧化性能的影响,研究了p-MT在该体系中的动力学过程. 实验结果表明,p-MT在复合离子液体水溶液体系中发生不可逆的电氧化反应,且该过程受扩散控制,扩散系数为7.69×10-10 cm2·s-1. 适当地升高温度和增大反应底物浓度都有利于促进p-MT中C-H键选择性电氧化为相应醛基,选择性可达到95%. 通过在不同结构电解槽中进行恒电位电解研究,发现离子液体/MWCNTs复合电解质在一室型电解槽中进行p-MT电氧化的电解效率更高、对目标产物对甲氧基苯甲醛(p-MBA)的选择性也更好.

关键词: C-H键氧化, 离子液体/碳纳米管复合材料, 电氧化活化, 对甲氧基苯甲醛

Abstract:

In this paper, the ionic liquid/carbon nanotube composite material was prepared through modifying the ionic liquid 1-ethyl-3-methylimidazolium acetate to multi-walled carbon nanotubes. The electro-oxidation properties of p-methoxy toluene (p-MT) were studied using the composite as an electrolyte. The effects of scanning speed, temperature and substrate concentration were studied by cyclic voltammetry and chronoamperometry. The electrochemical kinetics of p-MT in this system was also studied. The results showed that the electrochemical oxidation of p-MT in the composite electrolyte solution was irreversible. The process was mainly controlled by diffusion, and the diffusion coefficient (D) was 7.69×10-10 cm2.s-1. Increasing the reaction temperature and the concentration of substrate could promote the electro-oxidation of the C-H bond to the corresponding aldehyde, and the selectivity of p-methoxybenzaldehyde (p-MBA) could improve to 95%. The electrolysis in one-pot was more efficiency and achieved better selectivity than that in the H-type.

Key words: the C-H bond oxidation, ionic liquid / nano composite material, Electro-oxidation activation, p-methoxybenzaldehyde

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