二氟草酸硼酸钠作为电解液添加剂对石墨负极性能的影响

doi:10.13208/j.electrochem.150430

电化学（中英文） ›› 2015, Vol. 21 ›› Issue (4): 387-392. doi: 10.13208/j.electrochem.150430

二氟草酸硼酸钠作为电解液添加剂对石墨负极性能的影响

姚洋洋^1,3，刘冬冬¹，王莉²，何向明^2,3，李建军^2,3，张鼎^1*

1. 太原理工大学化学化工学院，山西太原 030024；2. 清华大学核能与新能源技术研究院，北京 100084；3. 江苏华东锂电技术研究院，江苏张家港 215600

收稿日期:2015-04-30 修回日期:2015-05-29 出版日期:2015-08-28 发布日期:2015-08-28
通讯作者: 张鼎 E-mail:zhangding@tyut.edu.cn
基金资助:
太原理工大学校青年基金（No. 2013Z045）资助

Sodium Difluoro(oxalato)borate as An Electrolyte Additive to Improve the Electrochemical Performance of Graphite Anode

YAO Yang-yang^1,3, LIU Dong-dong¹, WANG Li², HE Xiang-ming^2,3, LI Jian-jun^2,3, ZHANG Ding^1*

1. College of chemistry and chemical engineering of Taiyuan University of Technology, Taiyuan 030024, Shanxi, China; 2. Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China; 3. Jiangsu Huadong Institute of Li-ion Battery, Zhangjiagang 215600, Jiangsu, China

Received:2015-04-30 Revised:2015-05-29 Published:2015-08-28 Online:2015-08-28
Contact: ZHANG Ding E-mail:zhangding@tyut.edu.cn

摘要/Abstract

摘要： 锂离子电池日益广泛的应用对其性能提出越来越高的要求，而在电解液中加入适当的添加剂能够显著提升电极材料的电化学性能. 本文首次在1 mol·L^-1 LiPF₆/EC + DMC + EMC（体积比1:1:1）的电解液中添加一定量的二氟草酸硼酸钠(NaDFOB)，并通过循环伏安（CV）、电化学阻抗图谱（EIS）和扫描电子显微镜（SEM）等分析考察了其对石墨负极材料性能的具体影响. 结果显示，添加NaDFOB的电解液显著提高了石墨材料在常温下的可逆充放电容量和循环性能，同时明显改善了石墨材料的高温循环性能. 其机理在于NaDFOB的阴阳离子同时参与了石墨表面固体电解质界面膜（SEI）的形成，形成高稳定性的电解液/电极界面.

关键词: 锂离子电池, 电解液添加剂, 石墨, 固体电解质界面膜, 二氟草酸硼酸钠

Abstract: The fast development in applications of Li-ion batteries (LiBs) in daily life urges for better electrochemical performance of LiBs, which can be promoted by adding appropriate electrolyte additives. This work studied the effect of NaDFOB as the additive on a common electrolyte formula (1 mol·L^-1 LiPF₆ in EC+DMC+EMC, 1:1:1 by volume). Analysis methods such as CV, EIS and SEM were adopted to study electrochemical performance of experimental battery and interface profiles. It was revealed that the reversible charge-discharge capacity and cycling performance of graphite anode had been dramatically improved. In addition, the cycling performance of graphite anode at moderate temperature was obviously improved by the adoption of NaDFOB. Both anion and cation in NaDFOB participated the formation of SEI film on the graphite anode surface and thus generated a highly stable electrolyte/electrode interface.

Key words: Li-ion battery, electrolyte additive, graphite, SEI film, sodium difluoro (oxalato)borate

中图分类号:

TM912
O646

姚洋洋, 刘冬冬, 王莉, 何向明, 李建军, 张鼎. 二氟草酸硼酸钠作为电解液添加剂对石墨负极性能的影响[J]. 电化学（中英文）, 2015, 21(4): 387-392.

YAO Yang-yang, LIU Dong-dong, WANG Li, HE Xiang-ming, LI Jian-jun, ZHANG Ding. Sodium Difluoro(oxalato)borate as An Electrolyte Additive to Improve the Electrochemical Performance of Graphite Anode[J]. Journal of Electrochemistry, 2015, 21(4): 387-392.

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https://electrochem.xmu.edu.cn/CN/Y2015/V21/I4/387

参考文献

[1] Johnson B A, White R E. Characterization of commercially available lithium-ion batteries[J]. Journal of Power Sources, 1998, 70(1): 48-54.
[2] Tarascon J M, Armand M. Issues and challenges facing rechargeable lithium batteries[J]. Nature, 2001, 414(6861): 359-367.
[3] Peled E, Golodnitsky D, Menachem C, et al. An advanced tool for the selection of electrolyte components for rechargeable lithium batteries[J]. Journal of the electrochemical Society, 1998, 145(10): 3482-3486.
[4] Aurbach D. Review of selected electrode-solution interactions which determine the performance of Li and Li ion batteries[J]. Journal of Power Sources, 2000, 89(2): 206-218.
[5] Goodenough J B, Kim Y. Challenges for rechargeable Li batteries[J]. Chemistry of Materials, 2010, 22(3): 587-603.
[6] Zhang S S. A review on electrolyte additives for lithium-ion batteries[J]. Journal of Power Sources, 2006, 162(2): 1379-1394.
[7] Zhuang Q C(庄全超), Wei G Z(魏国祯), Dong Q F(董全峰), et al. The influence of temperature on the performance of graphite electrode[J]. Acta Physico-Chimica Sinica(物理化学学报), 2009, 25(3): 406-410.
[8] Schroeder G, Gierczyk M B, Walkowiak D W. Impact of ethyl tris-2-methoxyethoxy silane on the passivation of graphite electrode in Li-ion cells with PC-based electrolyte[J]. Electrochemistry Communications, 2006, 8(10): 1583-1587.
[9] Xu M Q, Zhou L, Hao L S, et al. Investigation and application of lithium difluoro(oxalate) borate (LiDFOB) as additive to improve the thermal stability of electrolyte for lithium-ion batteries[J]. Journal of Power Sources, 2011, 196(16): 6794-6801.
[10] Fu M H(付茂华), Huang K L(黄可龙), Liu S Q(刘素琴), et al. The influence of NaDFOB on the high temperature performance of LiFePO4/graphite battery[J]. Acta Physico-Chimica Sinica (物理化学学报), 2009, 25(10): 1985-1990.
[11] Gao H Q(高宏权), Lai Y Q(赖延清), Zhang Z A(张治安), et al. The electrochemical behavior of new lithium LiBC2O4F2 in EC+DMC solution[J]. Acta Physico-Chimica Sinica(物理化学学报), 2009, 25(5): 905-910.
[12] Aurbach D, Gamolsky K, Markovsky B, et al. On the use of vinylene carbonate (VC) as an additive to electrolyte solutions for Li-ion batteries[J]. Electrochimica Acta, 2002, 47(17): 1423-1439.
[13] Komaba S, Itabashi T, Kaplan B, et al. Enhancement of Li-ion battery performance of graphite anode by sodium ion as an electrolyte additive[J]. Electrochemistry Communications, 2003, 5(11): 962-966.
[14] Allen J L, McOwen D W, Delp S A, et al. N-Alkyl-N-methylpyrrolidinium difluoro(oxalato) borate ionic liquids: Physical/electrochemical properties and Al corrosion[J]. Journal of Power Sources, 2013, 237: 104 -111.
[15] Naji A, Ghanbaja J, Humbert B, et al. Electroreduction of graphite in LiClO4-ethylene carbonate electrolyte. Characterization of the passivating layer by transmission electromicroscopy and Fourier-transform infrared spectroscopy[J]. Journal of Power Sources, 1996, 63(1): 33-39.
[16] Zhang S S. Electrochemical study of the formation of a solid electrolyte interface on graphite in a LiBC2O4F2-based electrolyte[J]. Journal of Power Sources, 2007, 163(2): 713-718.
[17] Komaba S, Watanabe M, Groult H, et al. Impact of sodium salt coating on a graphite negative electrode for lithium-ion batteries[J]. Electrochemical and Solid-State Letters, 2006, 9(3): A130-A133.
[18] Komaba S, Itabashi T, Watanabe M, et al. Electrochemistry of graphite in Li and Na salt codissolving electrolyte for rechargeable batteries[J]. Journal of The Electrochemical Society, 2007, 154(4): A322-A330.
[19] Shieh D T, Hsieh P H, Yang M H. Effect of mixed LiBOB and LiPF6 salts on electrochemical and thermal properties in LiMn2O4 batteries[J]. Journal of Power Sources, 2007, 174(2): 663-667.
[20] Funabiki A, Inaba M, Ogumi Z, et al. Impedance study on the electrochemical lithium intercalation into natural graphite powder[J]. Journal of the Electrochemical Society, 1998, 145(1): 172-178.
[21] Zhang Z A, Chen X J, Li F Q, et al. LiPF6 and lithium oxalyldifluoroborate blend salts electrolyte for LiFePO4/artificial graphite lithium-ion cells[J]. Journal of Power Sources, 2010, 195(21): 7397-7402.
[22] Zhang S S, Xu K, Jow T R. EIS study on the formation of solid electrolyte interface in Li-ion battery[J]. Electrochimica Acta, 2006, 51(8): 1636-1640.

二氟草酸硼酸钠作为电解液添加剂对石墨负极性能的影响

Sodium Difluoro(oxalato)borate as An Electrolyte Additive to Improve the Electrochemical Performance of Graphite Anode

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