钙钛矿La1-xSrxCoO3的电化学电容性能

doi:10.61558/2993-074X.2110

电化学（中英文） ›› 2013, Vol. 19 ›› Issue (2): 174-177. doi: 10.61558/2993-074X.2110

钙钛矿La_1-xSr_xCoO₃的电化学电容性能

徐暘，包彦彦，杜龙飞，曹殿学，王贵领^*

1. 哈尔滨工程大学材料科学与化学工程学院，黑龙江哈尔滨 150001； 2. 黑龙江中医药大学药学院，黑龙江哈尔滨 150040

收稿日期:2012-02-27 修回日期:2012-04-10 出版日期:2013-04-28 发布日期:2012-04-20
通讯作者: 王贵领 E-mail:wangguiling@hrbeu.edu.cn
基金资助:
国家自然科学基金项目（No. 20973048）资助

The Electrochemical Capacitance Performance of La_1-xSr_xCoO₃ Perovskites

XU Yang, BAO Yan-yan, DU Long-Fei, CAO Dian-xue, WANG Gui-Ling^*

1. College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001,China；2. College of Pharmacy, Heilongjiang University of Traditional Chinese Medicine, Harbin 150040, China

Received:2012-02-27 Revised:2012-04-10 Published:2013-04-28 Online:2012-04-20
Contact: WANG Gui-Ling E-mail:wangguiling@hrbeu.edu.cn

摘要/Abstract

摘要： 以溶胶-凝胶法制备La_1-xSr_xCoO₃(x = 0.2, 0.4, 0.6, 0.8)电极材料，XRD表征证明所得产物属钙钛矿相. 由循环伏安和充放电曲线测试了La_1-xSr_xCoO₃在碱性介质中的电化学电容性能. 结果表明，La_0.6Sr_0.4CoO₃电极10 mA.cm^-2电流密度的放电比电容为325 F.g^-1，500周期循环后其比电容仍保持于315 F.g^-1，比电容保持率97.0%.

关键词: 钙钛矿, 电化学电容, 碱性介质

Abstract: In this paper, the La_1-xSr_xCoO₃(x = 0.2, 0.4, 0.6, 0.8) perovskites powders were synthesized by a sol-gel method. The perovskite phases were characterized by X-ray diffraction (XRD), while the electrochemical capacitance performance of La_1-xSr_xCoO₃ electrodes in alkaline electrolyte was studied by cyclic voltammetry and galvanostatic charge/discharge test. It was found that the La_0.6Sr_0.4CoO₃ electrode exhibited a specific capacitance of 325 F.g^-1 in 6.0 mol.L^-1 KOH electrolyte at a current density of 10 mA.cm^-2, and the specific capacitance of 315 F.g^-1 could be maintained after 500 charge/discharge cycles which corresponds to the retention rate of 97%.

Key words: perovskite, electrochemical capacitance, alkaline electrolytes

中图分类号:

O646.54

徐暘, 包彦彦, 杜龙飞, 曹殿学, 王贵领. 钙钛矿La_1-xSr_xCoO₃的电化学电容性能[J]. 电化学（中英文）, 2013, 19(2): 174-177.

XU Yang, BAO Yan-yan, DU Long-Fei, CAO Dian-xue, WANG Gui-Ling. The Electrochemical Capacitance Performance of La_1-xSr_xCoO₃ Perovskites[J]. Journal of Electrochemistry, 2013, 19(2): 174-177.

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://electrochem.xmu.edu.cn/CN/10.61558/2993-074X.2110

https://electrochem.xmu.edu.cn/CN/Y2013/V19/I2/174

参考文献

[1] Burke A. Ultracapacitors: Why, how, and where is the technology[J]. Journal of Power Sources, 2000, 91(1): 37-50.
[2] Winter M, Brodd R J. What are batteries, fuel cells, and supercapacitors[J]. Chemical Reviews, 2004, 104(10): 4245-4269.
[3] Yu Z H, Donald Z, Anima B. An innovative optimal power allocation strategy for fuel cell, battery and supercapacitor hybrid electric vehicle[J]. Journal of Power Sources, 2011, 196(4): 2351-2359.
[4] Zhang Y, Feng H, Wu X, et al. Progress of electrochemical capacitor electrode materials: A review[J]. International Journal of Hydrogen Energy, 2009, 34(11): 4889-4899.
[5] Xu H(徐惠), Peng Z J(彭振军), Guo D H(郭东红), et al. Preparation and capacitance characteristics of nickel oxide electrode with mesh-Like structure[J]. Journal of Electrochemistry(电化学), 2011, 17(4): 448-452.
[6] Hu Z A, Mo L P, Feng X J, et al. Synthesis and electrochemical capacitance of sheet-like cobalt hydroxide[J]. Materials Chemistry and Physics, 2009, 114(1): 53-57.
[7] Zhao Z Z(赵真真), Ni W B(倪文彬), Gao N Y(高能越), et al. Effects of graphene on electrochemical behaviors of Ni(OH)2 as supercapacitor material[J]. Journal of Electrochemistry(电化学), 2011, 17(3): 292-299.
[8] Zhang H X, Feng J, Zhang M L. Preparation of flower-like CuO by a simple chemical precipitation method and their application as electrode materials for capacitor[J]. Materials Research Bulletin, 2008, 43(12): 3221-3226.
[9] Chen H Y(陈海燕), Shao Y Q(邵艳群), Tang D(唐电). Capacitance behaviors of Ti/Ru0.1Ti0.1Sn0.8O2 electrodes[J]. Journal of Electrochemistry(电化学), 2011, 17(2): 231-233.
[10] Wu W(吴雯), Hou M Y(侯孟炎), Zhou D D(周丹丹), et al. Effect of pore size on pseudo-capacitive performance of NiO in the mixed electrolyte of KOH and hexacyanoferrate[J]. Journal of Electrochemistry(电化学), 2011, 17(2): 169-174.
[11] Gao Y Y, Chen S L, Cao D X, et al. Electrochemical capacitance of Co3O4 nanowire arrays supported on nickel foam[J]. Journal of Power Sources, 2010, 195(6): 1757-1760.
[12] Wang G L, Huang J C, Chen S L, et al. Preparation and supercapacitance of CuO nanosheet arrays grown on nickel foam[J]. Journal of Power Sources, 2011, 196(13): 5756-5760.
[13] Wang L(王亮), Liu C G(刘贵昌), Shi Z C(施志聪). Synthesis of α-MnO2 microspheres for the application in supercapacitor[J]. Journal of Electrochemistry(电化学), 2009, 15(04): 441-444.
[14] Xu C G, Li B H, Du H D, Kang F Y, et al. Super capacitive studies on amorphous MnO2 in mild solutions[J]. Journal of Power Sources, 2008, 184(2): 691-694.
[15] Ren Y, Gao L. From three-dimensional flower-like α-Ni(OH)2 nanostructures to hierarchical porous NiO nanoflowers: Microwave-assisted fabrication and supercapacitor properties[J]. Journal of the American Ceramic Society, 2010, 93(11): 3560-3564.
[16] Xiao F, Zhang X G, Hu F P, et al. Preparation and electrochemical capacitance of brown-millerite SrCoO2.5 as electrode materials for supercapacitor[J]. Materials Chemistry and Physics, 2005, 94(2/3):221-225.
[17] Wang G L, Bao Y Y, Tian Y M, et al. Electrocatalytic activity of perovskite La1?xSrxMnO3 towards hydrogen peroxide reduction in alkaline medium[J]. Journal of Power Sources, 2010, 195(19): 6463-6467.
[18] John T, Scott W D. Activity of perovskite La1?xSrxMnO3 catalysts towards oxygen reduction in alkaline electrolytes[J]. Journal of Power Sources, 2009, 188(2): 359-366.

钙钛矿La_1-xSr_xCoO₃的电化学电容性能

The Electrochemical Capacitance Performance of La_1-xSr_xCoO₃ Perovskites

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

Metrics

[1]	邹庚, 冯炜程, 宋月锋, 汪国雄. 固体氧化物电解池阳极材料研究进展[J]. 电化学（中英文）, 2023, 29(2): 2215006-.
[2]	梁宵, 张可新, 沈雨澄, 孙轲, 石磊, 陈辉, 郑克岩, 邹晓新. 钙钛矿型水氧化电催化剂[J]. 电化学（中英文）, 2022, 28(9): 2214004-.
[3]	王伟国, 白天, 薛高飞, 叶美丹. CsPbIBr₂钙钛矿太阳能电池中通过氧气诱导Spiro-OMeTAD快速氧化[J]. 电化学（中英文）, 2021, 27(2): 216-226.
[4]	韦童, 李箭, 贾礼超, 池波, 蒲健. 钙钛矿材料在固体氧化物燃料电池燃料重整中的应用[J]. 电化学（中英文）, 2020, 26(2): 198-211.
[5]	李一航, 夏长荣. 固体氧化物电解池直接电解CO₂的研究进展[J]. 电化学（中英文）, 2020, 26(2): 162-174.
[6]	鲁浩天，周静红，叶光华，周兴贵. 电化学电容器连续模型的建立与研究进展[J]. 电化学（中英文）, 2018, 24(5): 517-528.
[7]	王宏宇，樊慧，王小红，齐力. 基于阴离子-石墨嵌层化合物的电化学电容器[J]. 电化学（中英文）, 2017, 23(5): 497-506.
[8]	张囡，叶美丹, 温晓茹, 林昌健. 通过磁控溅射金属钛生长金红石型二氧化钛纳米片阵列应用于钙钛矿太阳能电池[J]. 电化学（中英文）, 2017, 23(2): 226-237.
[9]	刘晓东，李永舫. 阴极界面修饰层改善平面p-i-n型钙钛矿太阳能电池的光伏性能[J]. 电化学（中英文）, 2016, 22(4): 315-331.
[10]	乔文远，郭强，李聪，马爽，王福芝，戴松元，谭占鳌. 基于WO_x/PEDOT:PSS复合空穴传输层的高效稳定平面异质结钙钛矿太阳电池[J]. 电化学（中英文）, 2016, 22(4): 382-389.
[11]	高兆辉, 张浩, 曹高萍, 韩敏芳, 杨裕生. 电化学电容器氮化钒负极材料性能研究[J]. 电化学（中英文）, 2013, 19(2): 178-183.
[12]	丛文博, 贺晓书, . PANI/MWCNT电极在硫酸锂溶液中电容性能[J]. 电化学（中英文）, 2009, 15(3): 288-292.
[13]	马池, 孔令斌, 罗永春, 康龙, . Co(OH)_2/NaY复合材料的制备及其超级电容性能[J]. 电化学（中英文）, 2008, 14(3): 335-339.
[14]	米红宇, 张校刚, 杨苏东, 叶向果, . 肝素钠掺杂球状聚吡咯的合成及其电化学电容[J]. 电化学（中英文）, 2008, 14(2): 166-169.
[15]	王虹, 唐致远, 李中延, 庄新国, . V_2O_5/C电化学电容器有机电解液的性能研究[J]. 电化学（中英文）, 2008, 14(2): 125-129.