表面硅烷化铜箔的电化学腐蚀与防护研究

doi:10.61558/2993-074X.2931

电化学（中英文） ›› 2012, Vol. 18 ›› Issue (4): 359-364. doi: 10.61558/2993-074X.2931

表面硅烷化铜箔的电化学腐蚀与防护研究

伟俊, 张余宝, 古宁宇*, 刘峰

南昌大学化学系，江西南昌 330031

收稿日期:2012-01-13 修回日期:2012-02-09 发布日期:2012-02-24 出版日期:2012-08-28
通讯作者: 古宁宇 E-mail:nygu@ncu.edu.cn
基金资助:
国家自然科学基金（No. 50803026）和江西省科技支撑计划课题（No. 2009BGA00300）资助

Electrochemical Corrosion and Protection of Copper Foil Treated by Surface Siloxane Filming

MIAO Wei-Jun, ZHANG Yu-Bao, GU Ning-Yu*, LIU Feng

Department of Chemistry, Nanchang University, Nanchang 330031

Received:2012-01-13 Revised:2012-02-09 Online:2012-02-24 Published:2012-08-28
Contact: GU Ning-Yu E-mail:nygu@ncu.edu.cn

摘要/Abstract

摘要： 用γ-氨丙基三甲氧基硅烷(γ-APS)溶液对铜箔表面硅烷化处理，采用动电位极化和电化学交流阻抗研究不同pH的γ-氨丙基三甲氧基硅烷溶液自组装铜箔电极在0.1 mol.L^-1NaCl溶液的腐蚀防护效果，采用扫描电子显微镜观察γ-氨丙基三甲氧基硅烷自组装膜的表面形貌.结果表明，γ-氨丙基三甲氧基硅烷自组装铜箔有较好的腐蚀防护效果，其中pH=7的γ-氨丙基三甲氧基硅烷溶液自组装膜的抗腐蚀效果最佳.

关键词: &gamma, -氨丙基三甲氧基硅烷；铜箔；表面硅烷化；电化学防腐

Abstract: Copper foil specimens were immersed in hydro-alcoholic solution of 3-amino-propyl-trimethoxy-silane (γ-APS) to prepare a protective self-assembled siloxane membrane on the surface. Potentiodynamic polarization and electrochemical impedance spectroscopic tests were performed in 0.1 mol.L^-1 NaCl to evaluate the effects of the self-assembled siloxane membranes prepared at different pH of γ-APS on corrosion of copper foil. The surface morphology of siloxane membrane was studied by SEM. Experimental results revealed that the γ-APS self-assembled siloxane membranes effectively inhibited the corrosion of copper foil and the optimum anti-corrosion effect was found when the pH value of the silane solution was 7.

Key words: 3-amino-propyl-trimethoxy-silane, copper foil, surface siloxane filming, electrochemical corrosion protection

中图分类号:

O646.6

苗伟俊, 张余宝, 古宁宇, 刘峰. 表面硅烷化铜箔的电化学腐蚀与防护研究[J]. 电化学（中英文）, 2012, 18(4): 359-364.

MIAO Wei-Jun, ZHANG Yu-Bao, GU Ning-Yu, LIU Feng. Electrochemical Corrosion and Protection of Copper Foil Treated by Surface Siloxane Filming[J]. Journal of Electrochemistry, 2012, 18(4): 359-364.

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https://electrochem.xmu.edu.cn/CN/Y2012/V18/I4/359

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表面硅烷化铜箔的电化学腐蚀与防护研究

Electrochemical Corrosion and Protection of Copper Foil Treated by Surface Siloxane Filming

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