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电化学(中英文) ›› 2009, Vol. 15 ›› Issue (2): 190-193.  doi: 10.61558/2993-074X.1977

• 研究论文 • 上一篇    下一篇

3-氨基-1,2,4-三氮唑和Na_2WO_4复合缓蚀剂对黄铜的缓蚀协同作用

徐群杰;李春香;倪钰宏;周国定;   

  1. 上海大学应用化学系;上海电力学院环境工程系,上海高校电力腐蚀控制与应用电化学重点实验室;上海电力学院环境工程系上海高校电力腐蚀控制与应用电化学重点实验室;
  • 收稿日期:2009-05-28 修回日期:2009-05-28 出版日期:2009-05-28 发布日期:2009-05-28

Complex of 3-Amino-1,2,4-Triazole and Na_2WO_4 as An Inhibitor for Brass Corrosion

XU Qun-jie1,2,LI Chun-xiang1,2,NI Yu-hong2,ZHOU Guo-ding2   

  1. (1.Department of Chemical Engineering,Shanghai University,Shanghai 200444,China;2.Department of Environment Engineering,Shanghai University of Electric Power,Shanghai 200090,China
  • Received:2009-05-28 Revised:2009-05-28 Published:2009-05-28 Online:2009-05-28

摘要: 应用交流阻抗和极化曲线测试3-氨基-1,2,4-三氮唑(ATA)和钨酸钠复合缓蚀剂对黄铜在3%NaCl溶液中的缓蚀作用.结果表明,ATA对黄铜有缓蚀作用,并以7.5 mg.L-1ATA的缓蚀效果最好,缓蚀率为87.46%,以7.5 mg.L-1ATA和0.15 mg.L-1Na2WO4配成复合缓蚀剂则对黄铜具有很好缓蚀协同效应,缓蚀效率达91.82%,属阴极型缓蚀剂.

关键词: 黄铜, ATA, 缓蚀剂, 交流阻抗

Abstract: AC impedance and polarization methods were used to study the inhibition effect of ATA and the complex of ATA and Na2WO4 for brass corrosion in 3% NaCl solution.The results indicated that ATA had inhibition effect for brass corrosion.ATA showed the best inhibition effect for brass corrosion at the ATA concentration of 7.5 mg·L-1,and the inhibition efficiency was 87.46%.At the ATA concentration of 7.5 mg·L-1 and at the Na2WO4 concentration of 0.15 mg·L-1,the complex showed optimum inhibition effect for brass corrosion,and also showed synergistic effect and the inhibition efficiency reached 91.82%.The complex of ATA and Na2WO4 was cathodic corrosion inhibitor.

Key words: brass, ATA, inhibitor, AC impedance

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