欢迎访问《电化学(中英文)》期刊官方网站,今天是

电化学(中英文) ›› 2002, Vol. 8 ›› Issue (2): 172-176. 

• 研究论文 • 上一篇    下一篇

混合金属氧化物阳极在海水中的电化学性能

王廷勇,许立坤,陈光章   

  1. 中国船舶重工集团公司七二五研究所青岛分部,中国船舶重工集团公司七二五研究所青岛分部,中国船舶重工集团公司七二五研究所青岛分部 山东青岛266071 ,山东青岛266071 ,山东青岛266071
  • 收稿日期:2002-05-28 修回日期:2002-05-28 出版日期:2002-05-28 发布日期:2002-05-28

Electrochemical Properties of Mixed Metal Oxide Coated Titanium Anodes in Seawater

WANG Ting_yong *, XU Li_kun, CHEN Guang_zhang   

  1. (Qingdao Branch of Luoyang Ship Material Research Institute, Qingdao 266071,China
  • Received:2002-05-28 Revised:2002-05-28 Published:2002-05-28 Online:2002-05-28

摘要: 采用热分解方法制备钛基混合金属氧化物阳极 ,用扫描电镜对阳极涂层显微形貌进行了分析 ,并通过实海模拟试验考察了混合金属氧化物阳极在海水阴极保护系统中的使用性能 .SEM分析结果表明 ,混合金属氧化物阳极涂层呈多孔多裂纹的显微结构 ,与其它阳极材料相比 ,此种阳极具有更大的活性表面积 .电化学试验结果表明 ,混合金属氧化物阳极在海水中具有良好的电化学稳定性和电化学活性 ;此外 ,混合金属氧化物阳极在海水中的消耗率很低 ,属于不溶性的阳极材料 ,作为外加电流阴极保护的辅助阳极具有广泛的应用前景

关键词: 电化学稳定性, 电化学活性, 消耗率

Abstract: Mixed metal oxide coated titanium anodes prepared by thermal decomposition were characterized by scanning electron microscopy and electrochemical measurement, while the consumption rate of an anode was also measured in seawater. In order to examine the practical performances of mixed metal oxide_coated anodes, a simulating test on floating dock in seawater has also been carried out. The SEM results indicate that oxide layers exhibited a cracked_mud morphology which endows the anode with good electrocatalytic activity. The electrochemical measurements showed that mixed metal oxide_coated anodes exhibit excellent electrochemical activity and electrochemical stability in seawater. Owing to good corrosion resistance and low consumption rate in seawater, the mixed metal oxide coated anodes belong to insoluble material,which are outstanding candidates for use as anode in impressed current cathodic protection systems.

Key words: Electrochemical activity, Electrochemical stability, Consumption rate

中图分类号: