电化学(中英文) ›› 1999, Vol. 5 ›› Issue (1): 1-13.
• 研究论文 • 下一篇
田中群,任斌,佘春兴,陈衍珍
收稿日期:
1999-02-28
修回日期:
1999-02-28
出版日期:
1999-02-28
发布日期:
1999-02-28
Tian Zhongqun, Ren Bin, She Chunxing, Chen Yanzhen
Received:
1999-02-28
Revised:
1999-02-28
Published:
1999-02-28
Online:
1999-02-28
摘要: 常规电化学研究方法是以电信号为激励和检测手段,它提供的是电化学体系的各种微观信息的总和,难以准确地鉴别复杂体系的各反应物、中间物和产物,并解释电化学反应机理.近年来,由谱学方法(以光为激励和检测手段)与常规电化学方法相结合产生的谱学电化学技术得到迅速...
中图分类号:
田中群, 任斌, 佘春兴, 陈衍珍. 电化学原位拉曼光谱的应用及进展[J]. 电化学(中英文), 1999, 5(1): 1-13.
1田中群,孙世刚,罗瑾,杨勇.现场光谱电化学研究新进展.物理化学学报,1994,10:8602SchroterandH.W.Klochner,in:WeberA.Ed.RamanSpectroscopyofGasesandLiquids.Berlin:Springer_Verlag,1979,Vol.11:1233ChangRK,FurtakTEEds.SurfaceenhancedRamanscatering,NewYork:PlenumPres,19824OtoA,MrozekI,GrabhornHandAkemannW.Surface_enhancedRamanscatering.J.Phys.Condens.Mater,1992,4:11435MoskovitsM.Surface_enhancedspectroscopy.Rev.Mod.Phys.,1985,57:7836EfrimaS,Surface_enhancedRamanscatering(SERS).inBockrisJO’M,WhiteREandConwayBE(Eds.),“ModernAspectsofElectrochemistry”,NewYork:PlenumPress,1985,16:2537FleischmannM,HilI.Ramanspectroscopy,in:BockrisJO’M,WhiteREandConwayBE,YeagerE“ComprehensiveTreatiseofElectrochemistry”,NewYork:PlenumPres,1985,8:3738PetingerB,SurfaceenhancedRamanspectroscopy,in:LipkowskiJ,RosPN.Eds.AdsorptionofMoleculesatMetalElectrodes,(VCH,NewYork,1992),p.2859BirkeRLandLombardiJR.SurfaceenhancedRamanspectroscopy.inGaleRJ(Ed.).Spectroelectrochemistry_theoryandpractice,NewYork:PlenumPres,198810HembreeDM,OswaldJC,SmyreNR.SurfaceEnhancedRamanMicrospectroscopyatElectrodeSurfaces.Appl.Spectrosc.,1987,41:26711MacomberSH,FurtakTE.Surface_enhancedRamanscateringmagnifiedphotochemicalactivationofthesilverelectrodeinaqueoushalideelectrolytes.Chem.Phys.Let.,1982,90:43912GaoXP,GosztolaD,LeungLWetal.Surface_enhancedRamanscateringatgoldelectrodes:DependenceonelectrochemicalpretreatmentconditionsandcomparisonswithsilverJ.Electroanal.Chem.,1987,233:21113PetingerB,PhiopotMR,GordonJG.Furtherobservationofthesurface_enhancedRamanspectrumofwateronsilverandcopperelectrodes.Surf.Sci.,1981,105:46914FurtakTE,Curentunderstandingofthemechanismofsurface_enhancedRamanscatering.J.Electroanal.Chem.,1983,150:37515FleischmannM,GravesPR,RobinsonJ.EnhancedandnormalRamanscateringfrompyridineadsorbedonroughandsmoothsilverelectrodes.J.Electroanal.Chem.,1985,182:7316FleischmannM,TianZQ.TheefectsoftheunderpotentialandoverpotentialdepositionofleadandthaliumonsilverontheRamanspectraofadsorbates.J.Electroanal.Chem.,1987,217:38517TianZQ,LiWH,ZouSZ.PotentialaveragedsurfaceenhancedRamanspectroscopy.Appl.Spectrosc.,1996,50:156918ClineMP,BarberPW,ChangRKetal.Surface_enhancedelectricintensitiesontransition_andnoble_metalspheroids.J.Opt.Soc.Am.,1986,B3:1519FleischmannM,TianZQ,LiLJ.Ramanspectroscopyofadsorbatesonthinfilmelectrodesdepositedonsilversubstrates.J.Electroanal.Chem.,1987,217:39720AramakiK,UeharaJ.ASERSstudyonadsorptionofsomeorganiccompoundsoniron.J.Electrochem.Soc.,1989,136:129921LeungLW,WeaverMJ.Extendingthemetalinterfacegeneralityofsurface_enhancedRamanspectroscopy:Underpotentialdepositedlayersofmercury,thalium,andleadongoldelectrodes.J.Electroanal.Chem.,1987,217:36722LeungLW,WeaverMJ.Extendingsurface_enhancedRamanspectroscopytotransition_metalsurfaces:Carbonmonoxideadsorptionandelectroxidationonplatinum_andpaladium_coatedelectrodes.J.Am.Chem.Soc.,1987,109:511323OblonskyLJ,DevineTM,AgerJW.Surface_enhancedRamanscateringfrompyridineadsorbedonthinlayersofstainlesssteel.J.Electrochem.Soc.,1994,141:331224查英华,魏宝明,田中群,林昌健.表面增强拉曼光谱用于不锈钢缓蚀机理的研究.腐蚀科学与防护技术,1994,6:5825VanDuyneRP,HaushalterJP.ResonanceRamanspectroelectrochemistryofsemiconductorelectrode:ThePhotooxidationofTetrathiafulvaleneatn_GaAs(100)inAcetonitrile.J.Phys.Chem.,1984,88:244626FengQ,CotonTM.Asurface_enhancedresonanceRamanstudyofthephotoreductionofmethylviologenonaP_InPsemiconductorelectrode.J.Phys.Chem.,1986,90:98327ZouSZ,WiliansCT,ChenEK_Yetal.Probingmolecularvibrationsatcatalyticalysignificantinterfaces:Anewubiquityofsurface_enhancedRamanscatering.J.Am.Chem.Soc.,1998,120:381128KraserW,RenouprezAJ.EnhancedRamanspectroscopyofCoadsorbedCarbonMonoxideandHydrogenonSmalNickelParticles.J.RamanSpectrosc.,1981,11:42529BilmesA.,RubimJC,OtoAetal.SERSfrompyridineadsorbedonelectrodispersedplatinumelectrodes.Chem.Phys.Let.,1989,159:8930PetingerB,FriedrichA,TiedemannU.Ramanspectroscopyatmetalelectrodes.J.Electroanal.Chem.,1990,280:4931FleischmannM,SockalingumD,MusianiMM.TheuseofinfraredFourierTransformtechniquesinthestudyofsurfaceenhancedspectra.Spectrochim.Acta,1990,46A:28532HuangQJ,YaoJL,MaoBWetal.SurfaceRamanspectroscopicstudiesofpyrazineadsorbedontonickelelectrodes.Chem.Phys.Let.,1997,271:10133TianZQ,GaoJS,LiXQetal.CanRamanspectroscopybecomeageneraltechniqueforsurfacescienceandelectrochemistry.J.RamanSpectrosc.,1998,29:70334RenB,HuangQJ,CaiWBetal.SurfaceRamanspectraofpyridineandhydrogenadsorbedatPtandNielectrodes.J.Electroanal.Chem..1996,415:17535GaoJS,TianZQ.SurfaceRamanspectroscopicstudiesofruthenium,rhodiumandpaladiumelectrodesdepositedonglasycarbonsubstrates.SpectrochimicaActaA,1997,53:159536TianZQ,RenB,MaoBW.ExtendingsurfaceRamanspectroscopytotransitionmetalsurfacesforpracticalapplicationsI.Vibrationalpropertiesofthiocyanateandcarbonmonoxideadsorbedonelectrochemicalyactivatedplatinumsurfaces.J.Phys.Chem.,1997,101:133837CaiWB,RenB,LiuFMetal.Investigationofsurface_enhancedRamanscateringfromplatinumelectrodesusingaconfocalRamanmicroscope:dependenceofsurfacerougheningpretreatment.Surf.Sci.,1998,406:938RenB,LiuFM,XieJetal.In_situmonitoringofRamanscateringandphotoiluminanscencefromsiliconsurfacesinHFsolutions.Appl.Phys.Let.,1998,72:93339TianZQ,RenB,ChenYXetal.Probingelectrode/electrolyteinterfacialstructuresinthepotentialregionofhydrogenevolutionbyRamanspectroscopy.J.Chem.Soc.FaradayTrans.,1996,20:382940RenB,YaoJL,LiXQetal.ApplicationsofconfocalRamanmicroscopyinelectrochemistry.In:HeynsAM,TheXVIthInternationalConferenceonRamanSpectroscopy,NewYork:JohnWiley&SonsLtd.,1998:80841BroloAG,OdziemkowskiMandIrishDE.AninsituRamanspectroscopicstudyofelectrochemicalprocesesinmercury_solutioninterphases.J.RamanSpectrosc.,1998,29:71342CooneyRP,ReidES,FleischmannM.Thiocyanateadsorptionandcorosionatsilverelectrodes:ARamanspectroscopicstudy.J.Chem.Soc.,FaradayTrans.,1977,73:169143WetzelH,GerischerH,PetingerB.Surface_enhancedRamanscateringfromsilver_cyanideandsilver_thiocynatevibrationsandtheimportanceofadatoms.Chem.Phys.Let.,1981,80:15944WeaverMJ,BarzF,GordonJG.Surface_enhancedRamanspectroscopyofelectrochemicalycharacterizedinterfaces:potentialdependenceofRamanspectraforthiocyanateatsilverelectrodes.Surf.Sci.,1983,125:40945GaoXP,WeaverMJ.Metal_adsorbatevibrationalfrequenciesasaprobeofsurfacebonding:halideandpseudohalideatgoldelectrodes.J.Phys.Chem.,1986:90:405746TianZQ,LiWH,QiaoZH.Molecular_levelinvestigationsofdiferenttypesofcoadsorptionatAgelectrodesbyRamanspectroscopy.Rusian.J.Electrochem.,1995,31:1014.47SharonovS,NabievI,FeofanovAetal.Confocal3_dimensionalscanninglaserRaman_SERS_fluorescencemicroprobespectralimagingandhigh_resolutionapplications.J.RamanSpectrosc.,1994,25:69948田中群.表面增强拉曼光谱研究电化学中的共吸附现象.物理化学学报,1988,4:34449ChenTT,ChangRK.Surface_enhancedRamanscateringofinterfacialDOD,HOD,andOD-.Surf.Sci.,1985,158:32550TianZQ,SligalaevSK,ZouSZetal.TheobservationofSERSofwaterinawidepotentialrangefromtheAg/NaClO4system.Electrochim.Acta,1994,39:219551ChenYX,ZouSZ,HuangKQetal.SERSstudiesofelectrode/electrolyteinterfacialwaterI.librationsofwatercorelatedtohydrogenevolutionreaction.J.RamanSpectrosc.,1998,29:74952GosztolaD,WeaverMJ.Electroinducedstructuralchangesinmanganesedioxide+manganesehydroxidefilmsascharacterizedbyreal_timesurface_enhancedRamanspectroscopy.J.Electroanal.Chem.,1989,271:14153CasadoJ,OteroTF,HotaS,etal,Electrochemicaldopinginaseriesofalpha,alpha‘_dimethylend_cappedoligothienyls—AnFT_Ramanconfirmationofaradicalcationgeneration.Opt.Mater.,1998,9:8254MartinF,PrietoAC,DeSajaJAetal.SERSstudyofthepyrrolepolymerization.J.Mol.Struct.,1988,174:36355田中群,雷良才,景遐斌.苯胺在银和金电极上的表面增强拉曼光谱.物理化学学报,1988,4:45856钟传健,田中群,田昭武.吡咯电化学聚合的现场ESR波谱和Raman光谱研究.中国科学B,1989,12:125957陈衍珍,辜志俊,田中群.导电聚合物单体的光电聚合.物理化学学报.1993,9(2):27758BukowskaJ,JackowskaK.InsituRamanstudiesofpolypyroleformationonasilverelectrode.Electrochim.Acta,1990,35(2):31559FujitaW,TeramaeN,HaraguchiH.FormationofthiopheneoligomersandpolythiopheneonaroughenedgoldelectrodestudiedbysurfaceenhancedRamanscatering.Chem.Let.,1994,51160FujitaW,IshiokaT,TeramaeN.PolymerizationofpyroleonaroughenedgoldelectrodestudiedbysurfaceenhancedRamanscatering.Chem.Let.,1994,93361WuLL,LuoJ,LinZH.Spectroelectrochemicalstudiesofpoly_o_phenylenediamine.PartI.InsituresonanceRamanspectroscopy.J.Electroanal.Chem.,1996,417:5362ProbstM,HolzeR.Spectroelectrochemicalinvestigationofpolyxylidines.Ber.BensengesPhys.Chem.,1996,100:128663BazzaouiEA,LeviG,AeiyachSetal.SERSspectraofpolythiophereindopedandundopedstates.J.Phys.Chem.,1995,99:662864MalinauskasA,BronM,HolzeR.ElectrochemicalandRamanspectroscopicstudiesofelectrosynthesizedcopolymersandbilayerstructuresofpolyanilineandpoly(o_phenylenediamine).Sythet.Metal.,1998,92:12765FleischmannM,SundholmG,TianZ.Q.AnSERSStudyofSilverElectrodepositionfromThioureaandCyanideContainingSolutions.Electrochim.Acta,1986,31:90766DaujotisVandKairysV.Themechanismofelectroreductionofsilvercyanidecomplexesinaqueouselectrolytes_II.InterpretationofSERSdata.Electrochim.Acta,1998,42:134567ReentsB,PleithW,MacagnoVAandLaconiGI.Influenceofthioureaonsilverdeposition:Spectroscopicinvestigation.J.Electroanal.Chem.,1998,453:12168牛振江,姚士冰,周绍民.现场表面拉曼光谱研究Fe_Mo合金诱导共沉积.物理化学学报,1998,14:107469FleischmannM,HilIR,MengoliGetal.Acomparativestudyoftheeficiencyofsomeorganicinhibitorsforthecorosionofcopperonaqueouschloridemediausingelectrochemicalandsurface_enhancedRamanscateringtechniques.Electrochim.Acta,1985,30:87970徐海波,余家康,董俊华.硫脲和尿素在银电极上吸附行为的电化学和SERS研究.腐蚀科学与防护技术,1997,9:30271ThieryD,LeygrafC.SimultaneousRamanspectroscopyandelectrochemicalstudiesofcorosioninhibitingmoleculesoncopper.J.Electrochem.Soc.,1985,132:100972MusianiMM,MengoliG.AnElectrochemicalandSERSInvestigationoftheInfluenceofpHontheEfectivenesofsomeCorosionInhibitorsofCopper.J.Electroanal.Chem.,1987,217:18773林仲华,王逢春,田中群.2_氨基嘧啶对铜的缓蚀机理.物理化学学报,1992,8:8774HamiltonJC,FarmerJ,AndersonRJ.InsituRamanspectroscopyofanodicfilmsformedoncopperandsilverinsodiumhydroxidesolution.J.Electrochem.Soc.,1986,133:73975HuangWW,FrechP.InsituRamanstudiesofgraphitesurfacestructuresduringlithiumelectrochemicalintercalation.J.Electrochem.Soc.,1998,145:76576钟发平,杨汉西,徐知三,查全性.微型拉曼电解池现场研究硫酰氯的电化学还原.物理化学学报,1992,8:26677OstrovskiD,TorelLM.AppetecchiGBetal.AnelectrochemicalandRamanspectroscopicalstudyofgelpolymerelectrolytesforlithiumbateries.SolidStateIonics,1998,106:1978LoYL,HwangBJ.InsituRamanstudiesoncathodicalydepositednickelhydroxidefilmsandelectrolesNi_Pelectrodesin1MKOHsolution.Langmuir,1998,14:94479顾仁敖,曹佩根,孙如,曹文东,徐浩元.非水体系表面增强拉曼光谱研究.光散射学报,1998,10:17780顾仁敖,宗亚平,冷永章.非水体系中哌啶在银电极表面的表面增强喇曼散射.光学学报,1989,9:104181HilIR,IrishDEandAtkinsonGF.InvestigationsofSilverElectrodeSurfaceinPropyleneCarbonate/AlkaliHalideElectrolytesbySurfaceEnhancedRamanScatering.Langmuir,1986,2:75282XiaoYJ,WangT,WangXQ,GaoXX.Surface_enhancednear_infraredRamanspectroscopyofnicotinamideadeninedinucleotidesonagoldelectrode.J.Electroanal.Chem.,1997,433:4983BryantMA,PembertonJE.SurfaceRamanscateringofself_asembledmonolayersformedfrom1_alkanethiolsatAg.J.Am.Chem.Soc.,1991,113:362984ZhuT,YuHZ,CaiSMetal.Electrochemicalin_situRamanstudyofazobenzeneself_asembledmonolayersongold.Cryst.Liq.Cryst.Sci.Tec.A,1997,2947985HatchetDW,StevensonKJ,LacyWBetal.ElectrochemicaloxidativeadsorptionofethanethiolateonAg(111).J.Am.Chem.Soc.,1997,119:659686TsenM,SunL.Surface_enhancedRamanscateringfromfunctionalizedself_asembledmonolayers.1.DistancedependenceofenhancedRamanscateringfromaterminalphenylgroup.Anal.Chim.Acta,1995,307:33387PatersonML,WeaverMJ.SurfaceenhancedRamanspectroscopyasaprobeofadsorbate_surfacebonding:Simplealkenesandalkynesadsorbedatgoldelectrodes.J.Phys.Chem.,1985,89:504688SmithBD,IrishDE,KedzierzawskiPetal.ASERSstudyoftheintermediateandpoisoningspeciesformedduringtheelectrochemicalreductionofCO2onCopper.J.Electrochem.Soc.,1997,144:428889BryantMA,JoaSLandPembertonJE.RamanscateringfrommonolayerFilmsofthiophenoland4_mercaptopyridineatPtsurfaces.Langmuir,1992,8:75390BryantSPandFurtakTE.SurfaceplasmonassistedRamanscateringfromelectrochemicalycontroledadsorbatesonflatsinglecrystalsilver.Electrochim.Acta,1991,11/12:187991BroloAG,IrishDE,LipkowskiJ.Surface_enhancedRamanspectraofpyridineandpyrazineadsorbedonaAu(210)single_crystalelectrode.FT_RamanMicroscopy:DiscusionandPreliminaryResults.J.Phys.Chem.,1997,101:390692BruckbauerAandOtoA.Ramanspectroscopyofpyridineadsorbedonsinglecrystalcopperelectrodes.J.Raman.Spectrosc.,1998,29:66593FutamataM,Highly_sensitiveRamanspectroscopyusingsurface_plasmon_polariton.In:HeynsAM,TheXVIthInternationalConferenceonRamanSpectroscopy,NewYork:JohnWiley&SonsLtd.,1998,35694FutamataM.High_sensitiveRamanspectroscopytocharacterizeadsorbatesontheelectrode.Surf.Sci.,1997,386:8995LiWH,TianZQ,GaoJS,etal.In_situtime_resolvedRamanspectroscopicstudiesofsilverelectrodeinNaSCNsolution.Chin.Chem.Let.,1993,4:82996ShiCT,ZhangW,BirkeRLetal.SERSinvestigationoftheadsorptionandelectroreductionof4_cyanopyridineonasilverelectrode.J.Electroanal.Chem.,1997,423:6797MeserschmidtRGandChaseDB.FT_RamanMicroscopy:DiscussionandPreliminaryResults.Appl.Spectrosc.,1989,43:1198YangXM,TrykDA,HashimotoKetal.Examinationofthephotoreactionofp_nitrobenzoicacidonelectrochemicalyroughenedsilverusingsurface_enhancedRamanimaging(SERI).J.Phys.Chem.B.,1998,102:4933.99YangXM,TrykDA,HashimotoKetal.Surface_enhancedRamanimaging(SERI)asatechniqueforimagingmolecularmonolayerswithchemicalselectivityunderambientconditions.J.Raman.Spectrosc.,1998,29:725.100OzekiTandIrishDE.Theapplicationofconcentration_distanceprofilingRamanmicrospectroscopytothestudyofthephotoinducedcrystalizationoftriethylenediaminetriodideuponasilverelectrode.J.Phys.Chem.,1992,96:1306101张树霖.突破分辨率极限的拉曼光谱学—简介近场光学与近场拉曼光谱.光散射学报,1997,9:47102李五湖,田中群.光导纤维拉曼光谱技术及其在化学中的应用.光散射学报,1993,5:50103HuyNQ,JouanMandDaoNQ.Useofamono_FiberoptrodeinremoteandinsitumeasurementsbytheRaman/laser/fiberoptics(RLFO)method.Appl.Spectrosc.,1993,47:2013104TianZQ,LiWH,RenB.SimultaneousSTMandRamanmeasurementsonelectrochemicalinterfaces.J.Electroanal.Chem.,1996,401:24 |
[1] | 沈茎, 王子明, 郑大江, 宋光铃. 钝化与过钝化状态下304不锈钢的点蚀行为研究[J]. 电化学(中英文), 2020, 26(6): 808-814. |
[2] | 邢逸飞, 李娜, 温晓芳, 韩宏彦, 崔敏, 张聪, 任聚杰, 籍雪平. 基于取代型多酸复合材料的多巴胺电化学检测[J]. 电化学(中英文), 2020, 26(6): 890-899. |
[3] | 杨纳川, 王玉, 帅毅, 陈康华. 低成本硫化物固态电解质Li6-xPS5-xClx的制备与性能研究[J]. 电化学(中英文), 2020, 26(6): 885-889. |
[4] | 晋通正, 杨雨萌, 范圣慧, 卫国英, 张昭. 溶解氧及波长对光助阳极沉积CeO2薄膜的影响[J]. 电化学(中英文), 2020, 26(6): 868-875. |
[5] | 娄景媛, 尤东江, 李雪菁. 全钒氧化还原液流电池用石墨毡电极的分步氧化活化[J]. 电化学(中英文), 2020, 26(6): 876-884. |
[6] | 吴凯. 锂硫电池正极材料的制备及工艺优化[J]. 电化学(中英文), 2020, 26(6): 825-833. |
[7] | 俞成荣, 朱建国, 蒋聪盈, 谷宇晨, 周晔欣, 李卓斌, 邬荣敏, 仲政, 官万兵. 基于电-化-热耦合理论对称双阴极固体氧化物燃料电池堆的电流与温度场数值模拟[J]. 电化学(中英文), 2020, 26(6): 789-796. |
[8] | 朱畅, 陈为, 宋艳芳, 董笑, 李桂花, 魏伟, 孙予罕. 反应条件对铜催化CO2电还原的影响[J]. 电化学(中英文), 2020, 26(6): 797-807. |
[9] | 王学良, 丛媛媛, 邱晨曦, 王盛杰, 秦嘉琪, 宋玉江. 核壳结构Ru@PtRu纳米花电催化剂的制备及碱性氢析出反应性能研究[J]. 电化学(中英文), 2020, 26(6): 815-824. |
[10] | 陈品松, 胡一涛, 张信义, 沈培康. 立体构造石墨烯材料对铅酸蓄电池负极性能影响的研究[J]. 电化学(中英文), 2020, 26(6): 834-843. |
[11] | 张泽阳, 孙岚, 林昌健. RGO-TiO2纳米管阵列的制备及其光电性能[J]. 电化学(中英文), 2020, 26(6): 844-849. |
[12] | 马武威, 常启刚, 史雄芳, 童延斌, 周立, 叶邦策, 鲁建江, 赵金虎. 基于纳米孔金与离子印迹聚合物结合的新型电化学传感器用于测定砷离子(III)[J]. 电化学(中英文), 2020, 26(6): 900-910. |
[13] | 王存, 张维江, 何腾飞, 雷博, 史尤杰, 郑耀东, 罗伟林, 蒋方明. NCA三元锂离子电池分荷电状态循环的热特性和容量衰退研究[J]. 电化学(中英文), 2020, 26(6): 777-788. |
[14] | 段明涛, 蒙延双, 张红帅. Ni3S2@碳纳米管复合材料的制备及其储钠性能[J]. 电化学(中英文), 2020, 26(6): 850-858. |
[15] | 王怡捷, 钮东方, 张新胜. 离子液体中18-冠醚-6添加剂对三价铬电沉积的影响[J]. 电化学(中英文), 2020, 26(6): 859-867. |
阅读次数 | ||||||
全文 |
|
|||||
摘要 |
|
|||||