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电化学（中英文） ›› 2012, Vol. 18 ›› Issue (5): 405-409.  doi: 10.61558/2993-074X.2611

• 表界面电化学 • 上一篇    下一篇

基于琼脂支撑的液/液界面上AgTCNQ的电化学合成

黄丽1,2; 汪宜娴3; Michael V. Mirkin3; 任斌1,2; 詹东平1,2*   

  1. 1. 厦门大学化学化工学院化学系, 福建厦门361005; 2. 厦门大学固体表面物理化学国家重点实验室, 福建厦门361005; 3. 纽约市立大学皇后学院化学与生物化学系袁美国纽约11367
  • 收稿日期:2012-07-01 修回日期:2012-10-08 发布日期:2012-10-28 出版日期:2012-10-28
  • 通讯作者: 詹东平 E-mail:dpzhan@xmu.edu.cn
  • 基金资助:

    This work was supported by National Science Foundation of China (No. 20973142, No. 21061120456, and No. 21021002), National Basic Research Program of China (2011CB933700) and the National Science Foundation (CHE-1026582; MVM).

Electrochemical Synthesis of Silver-Tetracyanoquinodimethane Nanorods at Agar Supported Water/1,2-Dichloroethane Interface

Li Huang1,2, Yixian Wang3, Michael V. Mirkin3, Bin Ren1,2, Dongping Zhan1,2*   

  1. 1. Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China; 2. State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen 361005, Fujian, China; 3. Department of Chemistry and Biochemistry, Queens College-CUNY, Flushing, New York 11367, USA
  • Received:2012-07-01 Revised:2012-10-08 Online:2012-10-28 Published:2012-10-28
  • Contact: Dongping Zhan E-mail:dpzhan@xmu.edu.cn
  • Supported by:

    This work was supported by National Science Foundation of China (No. 20973142, No. 21061120456, and No. 21021002), National Basic Research Program of China (2011CB933700) and the National Science Foundation (CHE-1026582; MVM).

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摘要： 具有高导电性和独特电学性质的金属有机络合物AgTCNQ是一种重要的电荷转移盐.本文采用琼脂作为胶凝剂构成水|1,2-二氯乙烷液液界面；施加电压时银离子由水相穿过水凝胶进入有机相，与TCNQ-反应生成AgTCNQ纳米棒.结果表明液/液界面电化学方法为合成有机金属功能材料的有效途径.

关键词: 液/液界面, 银-四氰基对苯二醌二甲烷, 电化学合成, 纳米棒

Abstract: Silver-tetracyanoquinodimethane (AgTCNQ) is an important charge transfer salt due to its high conductivity and other electronic properties. In this communication, we report the synthesis of AgTCNQ at the liquid/liquid interface. Agar was used as a gelling agent to support water/1,2-dichloroethane (DCE) interface. Silver ions were transferred from the hydrogel into DCE phase, where they combined with TCNQ- to form AgTCNQ nanorods. The developed method can provide a new route for synthesis of functional materials based on the electrochemistry at the liquid/liquid interface.

Key words: liquid/liquid interface, silver-tetracyanoquinodimethane, electrochemical synthesis, nanorods

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