钠离子电池硬碳基负极材料的研究进展

doi:10.13208/j.electrochem.2204301

摘要/Abstract

摘要：

本文系统地总结了近年来钠离子电池中硬碳负极材料的研究进展以及相应储钠机理的发展历程，并从结构设计和电解液调控两方面综述了硬碳材料性能的提升策略。简述了前驱体的选择、碳化温度、预处理、造孔剂、杂原子掺杂、材料复合、电解液调控以及预钠化等策略对硬碳负极材料储钠性能的影响。本文为高性能低成本硬碳材料的设计合成和电解液匹配提供了新的见解，并展望了未来硬碳负极材料进一步研发的方向。

关键词: 钠离子电池, 硬碳, 负极材料, 储钠性能

Abstract:

This paper systematically summarizes the research progress of hard carbon anode materials in sodium ion batteries (SIBs) and the development of the corresponding sodium storage mechanism in recent years, and reviews the performance improvement strategies of hard carbon materials from the aspects of structural design and electrolyte regulation. The effects of the selection of precursors, carbonization temperature, pretreatment, pore formers, heteroatom doping, material compounding, electrolyte regulation and pre-sodiumization on the sodium storage performance of hard carbon anode materials are briefly described. This paper provides new insights into the design, synthesis and electrolyte matching of high-performance and low-cost hard carbon materials, and looks forward to the direction of further research and development of SIBs hard carbon anode materials in the future.

Key words: Sodium-ion battery, Hard carbon, Anode material, Sodium storage performance

殷秀平, 赵玉峰, 张久俊. 钠离子电池硬碳基负极材料的研究进展[J]. 电化学（中英文）, 2023, 29(10): 2204301.

Xiu-Ping Yin, Yu-Feng Zhao, Jiu-Jun Zhang. Research Progress and Performance Improvement Strategies of Hard Carbon Anode Materials for Sodium-Ion Batteries[J]. Journal of Electrochemistry, 2023, 29(10): 2204301.

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链接本文: https://electrochem.xmu.edu.cn/CN/10.13208/j.electrochem.2204301

https://electrochem.xmu.edu.cn/CN/Y2023/V29/I10/2204301

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Precursor	Carbonization temperature (°C)	Capacity -ICE (mAh·g^-1)	Rate capability (mAh·g^-1)	Cycle number	Cyclability (mAh·g^-1)	Ref.
Renewable Cotton	1300	315%-83%	180/0.3 A·g^-1	100	305(97%)	[20]
Polyaniline	1150	270%-51.6%	40/3 A·g^-1	500	207(77%)	[27]
Walnut shell	1000	257%-71%	48/2 A·g^-1	300	170(70.8%)	[29]
Oak leaves	1000	360%-74.8%	270/0.04 A·g^-1	200	243(90%)	[30]
Cherry petals	1000	310.2%-67.3%	25/1 A·g^-1	500	131.5(89.8%)	[31]
Kelp	1300	334%-64.1%	96/1 A·g^-1	200	205(93%)	[32]
Lignin	1100	299%-68%	77/3 A·g^-1	300	298(98%)	[33]
Honeycomb	900	221.5%-59.8%	87.3/5 A·g^-1	200	203(91.6%)	[35]
Pomelo peels	700	314.5%-27%	71/5 A·g^-1	220	181(99.3%)	[37]
Lotus stems	1400	351%-70%	150/0.5 A·g^-1	450	330(94%)	[42]
Chitosan	800	245%-32.3%	55/5 A·g^-1	100	155(63.3%)	[43]
Artemia cyst shell	850	325%-32%	63/5 A·g^-1	200	174(53.3%)	[44]
Eggshell membranes	1300	310%-89%	142/0.5 A·g^-1	250	236(99%)	[45]
Tissue	1300	338.2%-91.2%	170/2 A·g^-1	1000	286.5(93%)	[47]
Pitch	1400	300.6%-88.6%	-	200	279.8(93.1%)	[49]
Cork-derived	1600	358%-81%	-	200	312(87%)	[50]
Phenol-Formaldehyde	1400	410%-84%	-	40	393.6(96%)	[51]
Mg(C₆H₁₁O₇)₂	1500	478%-88%	360/2.5 A·g^-1	35	450(94.1%)	[53]
polyvinylpyrrolidone	1000	393.4%-89%	79.9/2 A·g^-1	100	399.5(97.2%)	[58]
Graphene oxide	1000	417%-57.3%	83/5 A·g^-1	100	133(83%)	[62]
Filter paper-pitch	1000	282%-80%	75/1.2 A·g^-1	100	191(74%)	[66]
Xylose	1200	363.8%-84.93%	214/10 A·g^-1	400	337(92.6%)	[70]