电化学(中英文) ›› 2024, Vol. 30 ›› Issue (3): 2314003. doi: 10.61558/2993-074X.3443
• 综述 • 上一篇
马俊博a, 林生a, 林志群b, 孙岚a,*(), 林昌健a,*()
收稿日期:
2023-12-01
修回日期:
2024-01-02
接受日期:
2024-01-05
出版日期:
2024-03-28
发布日期:
2024-01-15
Ma Jun-Boa, Lin Shenga, Lin Zhiqunb, Sun Lana,*(), Lin Chang-Jiana,*()
Received:
2023-12-01
Revised:
2024-01-02
Accepted:
2024-01-05
Published:
2024-03-28
Online:
2024-01-15
Contact:
*Lan Sun, Tel: (86-592)2186862; E-mail: 摘要:
氨(NH3)是一种现代社会必需的化学物质。目前,工业上合成NH3仍然采用的是Haber-Bosch过程,即以H2和N2为反应物在铁基催化剂的作用下于高温(400-600 oC)高压(20-40 Mpa)下将N2转化为NH3。然而,其效率只有10%-15%,同时造成大量的能源消耗,而且CO2排放不可避免。开发构建可持续发展的清洁友好的新能源体系是解决能源危机和环境污染问题、实现碳达峰和碳中和的关键战略。半导体光(电)催化固氮可以利用绿色无污染的太阳能制取重要的基础化工原料氨,有望代替传统的化工制氨工艺,解决其能源消耗严重和环境污染的问题。本文概述了光(电)催化固氮反应及其影响因素、光催化、电催化和光电催化固氮反应实验装置与基本特征、光(电)催化固氮反应催化剂研究进展、光电催化固氮反应机理,着重论述了半导体光催化剂、光(电)催化固氮体系以及光催化固氮机理的最新进展,并对太阳能光催化固氮技术加以评述和展望。
马俊博, 林生, 林志群, 孙岚, 林昌健. 太阳能光(电)催化固氮研究进展[J]. 电化学(中英文), 2024, 30(3): 2314003.
Ma Jun-Bo, Lin Sheng, Lin Zhiqun, Sun Lan, Lin Chang-Jian. Recent Advances in Solar Photo(electro)catalytic Nitrogen Fixation[J]. Journal of Electrochemistry, 2024, 30(3): 2314003.
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