阳极氧化法制备光电化学防腐蚀二氧化钛薄膜

电化学（中英文） ›› 2004, Vol. 10 ›› Issue (3): 353-358.

阳极氧化法制备光电化学防腐蚀二氧化钛薄膜

武朋飞,李谋成,沈嘉年,肖美群,刘东

上海大学材料所,上海大学材料所,上海大学材料所,上海大学材料所,上海大学材料所上海200072 ,上海200072 ,上海200072 ,上海200072 ,上海200072

收稿日期:2004-08-28 修回日期:2004-08-28 出版日期:2004-08-28 发布日期:2004-08-28

Preparation of Photo-electrochemical Anticorrosion TiO_2 Films by Anodization Method

WU Peng-fei~* , LI Mou-cheng, SHEN Jia-nian, XIAO Mei-qun, LIU Dong

(Institute of Materials, Shanghai University, Shanghai 200072, China

Received:2004-08-28 Revised:2004-08-28 Published:2004-08-28 Online:2004-08-28

摘要/Abstract

摘要： 　应用阳极氧化法制备二氧化钛薄膜.研究了阳极氧化电压、电解质的性质、浓度对二氧化钛薄膜光电化学防腐蚀性能的影响,并测定该薄膜在模拟海水中的极化曲线以及与45#碳钢的耦合电流曲线.

关键词: 阳极氧化, 二氧化钛薄膜, 防腐蚀

Abstract: Titanium oxide films have photo-electrochemical anticorrosion effect. We investigated the TiO_(2) films prepared by anodization method to protect for 45~(#) carbon steel in man-made seawater(3%NaCl). Various parameters, including voltages, electrolytes nature and concentration of electrolyte were examined. The polarization curves and of TiO_(2) and coupling photo-current curve between TiO_(2) film and 45~(#) carbon steel were measured.

Key words: Anodization method, TiO_(2) film, Anticorrosion

中图分类号:

TG174

武朋飞,李谋成,沈嘉年,肖美群,刘东. 阳极氧化法制备光电化学防腐蚀二氧化钛薄膜[J]. 电化学（中英文）, 2004, 10(3): 353-358.

WU Peng-fei~* , LI Mou-cheng, SHEN Jia-nian, XIAO Mei-qun, LIU Dong . Preparation of Photo-electrochemical Anticorrosion TiO_2 Films by Anodization Method[J]. Journal of Electrochemistry, 2004, 10(3): 353-358.

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://electrochem.xmu.edu.cn/CN/

https://electrochem.xmu.edu.cn/CN/Y2004/V10/I3/353

参考文献

[1]　OhkoY,SaitohS,TatsumaT,etal.Photoelectrochemicalanticorrosionandself cleaningeffectsofaTiO2coatingfortype304stainlesssteel[J].J.Electrochem.Soc.,2001,148(1):B24. [2]　OhkoY,SaitohS,TatsumaT,etal.PhotoelectrochemicalanticorrosioneffectofSrTiO3forcarbonstee[J]J.ElectrochemicalandSolid StateLetters,2002,5(2):B9. [3]　YuanJ,FujisawaR,TsujikawaS.PhotopotentialsofcoppercoatedwithTiO2bySol Gelmethod[J].Zairyo toKankyo,1994,43:433. [4]　FujisawaR,TsujikawaS.Photo protectionof304stainlesssteelwithTiO2coating[J].MaterialsScienceForum.,1995,185188:1075. [5]　YuanJ,TsujikawaS.CharacterizationofSol Gel DerivedTiO2coatingandtheirphotoeffectsoncoppersubstrates[J].J.Electrochem.Soc.,1995,142(10):3444. [6]　YuanJ,TsujikawaS.Photo effectofSol GelderivedTiO2coatingoncarbonsteelinalkalinesolution[J].Zairyo toKankyo,1995,44:534. [7]　HuangJ,ShinoharaT,TsujikawaS.ProtectionofcarbonsteelfromatmosphericcorrosionbyTiO2coating[J].Zairyo to Kankyo,1999,48:575. [8]　HuangJ,ShinoharaT,TsujikawaS.EffectsofinterfacialironoxidesoncorrosionprotectionofcarbonsteelbyTiO2coatingunderillumination[J].Zairyo to Kankyo,1997,46:651. [9]　AladjemA.Reviewanodicoxidationoftitaniumanditsalloys[J].JournalofMaterialsScience,1973,8:688. [10]　Young TaegS,CarinaBJ,YongsooJ,etal.Theelectrochemicaloxidegrowthbehaviourontitaniuminacidandalkalineelectrolytes[J].MedicalEngineeringandPhysics,2001,23:329. [11]　DelplanckeJL,DegrezM,FontanaA,etal.Self colouranodizingoftitanium[J].Surf.Technol.,1982,16:153. [12]　JouveG,LeachJSL.Theincreaseintemperatureoftheanodicfilmformedontitaniumduringgrowthinacidmedia[J].ThinSolidFilms,1983,110:263. [13]　ArsovLjD,KormannC,PliethW.InSituRamanSpectraofanodicallyformedtitaniumdioxidelayersinsolutionsofH2SO4,KOH,andHNO3[J].J.Electrochem.Soc.,1991,138(10):2964. [14]　SatoN.Atheoryforbreakdownofanodicoxidefilmsonmetals[J].ElectrochimicaActa,1971,16:1683. [15]　DyerCK,LeachJSL.Breakdownandefficiencyofanodicoxidegrowthontitanium[J].J.Electrochem.Soc.:ElectrochemicalScienceandTechnology,1978,125(7):1032.