Schiff碱在金电极上的自组装膜

电化学（中英文） ›› 2002, Vol. 8 ›› Issue (2): 219-223.

Schiff碱在金电极上的自组装膜

丁克强,王庆飞,贾振斌,田娜,王宁,童汝亭,王心葵,邵会波

河北师范大学化学系,河北师范大学化学系,河北师范大学化学系,河北师范大学化学系,河北师范大学化学系,河北师范大学化学系,中国科学院山西煤炭化学研究所,首都师范大学化学系河北石家庄050016中国科学院山西煤炭化学研究所,山西太原030001 ,河北石家庄050016 ,河北石家庄05

收稿日期:2002-05-28 修回日期:2002-05-28 出版日期:2002-05-28 发布日期:2002-05-28

Self-assembled Monolayer of Schiff Bases on Au electrode

DING Ke_qiang 1,2 , WANG Qing_fei 1,JIA Zhen_bin 1,TIAN Na 1,WANG Ning 1,TONG Ru_ting 1,WANG Xin_kui 2,SHAO Hui_bo 3*

(1.Dept. of Chem. Hebei Teacher's Univ., Shijiazhuang 050016,China;2.Inst. of Coal Chem. Chinese Academy of Sci., Taiy

Received:2002-05-28 Revised:2002-05-28 Published:2002-05-28 Online:2002-05-28

摘要/Abstract

摘要： 本文利用自组装技术 ,首次将带有巯基的Schiff碱自组装到Au电极的表面 ;并利用扫描电子的显微电镜 (SEM )直接证实了Schiff碱的成膜 ,用循环伏安和交流阻抗技术对其膜的致密性等进行了分析 ,证实由Schiff碱形成的膜虽较疏松 ,但对异相电子转移起到了一定的抑制作用 ,本工作为利用自组装膜的方法研究Schiff碱提供了必要的实验理论参考

关键词: Schiff碱, 自组装膜, 电化学表征

Abstract: Schiff bases tailored with _SH group,was self_assembled on Au substrate for the first time.The packing degree of this monolayer was described with SEM technique.Spontaneously,the self_assembled monolayer (SAM) was briefly characterized with CV and EIS methods.Though Comparing with the SAM of alkanethiol,the membrane we fabricated was relatively loose,our work is the first step to study Schiff bases by means of self_assembled monolayer.

Key words: Schiff bases, Self_assembled monolayer, Electrochemical characterization

中图分类号:

O646

丁克强,王庆飞,贾振斌,田娜,王宁,童汝亭,王心葵,邵会波. Schiff碱在金电极上的自组装膜[J]. 电化学（中英文）, 2002, 8(2): 219-223.

DING Ke_qiang 1,2 , WANG Qing_fei 1,JIA Zhen_bin 1,TIAN Na 1,WANG Ning 1,TONG Ru_ting 1,WANG Xin_kui 2,SHAO Hui_bo 3* . Self-assembled Monolayer of Schiff Bases on Au electrode[J]. Journal of Electrochemistry, 2002, 8(2): 219-223.

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https://electrochem.xmu.edu.cn/CN/Y2002/V8/I2/219

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