欢迎访问《电化学(中英文)》期刊官方网站,今天是

电化学(中英文) ›› 1996, Vol. 2 ›› Issue (1): 84-88. 

• 研究论文 • 上一篇    下一篇

低磷化学镀镍层性能的研究

郭慧林,胡信国,苏贵品   

  1. 西北大学化学系,哈尔滨工业大学应用化学系
  • 收稿日期:1996-02-28 修回日期:1996-02-28 出版日期:1996-02-28 发布日期:1996-02-28

A Study on Performance of Electroless Nickel Coatings Containing Low Phsphorus

Guo Huilin   

  1. (Department of Chemistry, Northwest University, Xi'an 710069)Hu Xinguo; Su Guipin (Department of Applied Chemistry,Harbin Institute of Technology,Harbin 150001
  • Received:1996-02-28 Revised:1996-02-28 Published:1996-02-28 Online:1996-02-28

摘要: 低磷镀层(LP)在碱性和中性盐水条件下的耐蚀性较高磷镀层好。当LP镀层在350℃下热处理1h后,镀层的显微硬度从454Hv增加到890Hv。差热分析研究发现,在341.6℃和406.2℃有两个放热峰,分别对应于新相Ni5P2和Ni3P的形成。利用X射线衍射对镀层的结构进行分析,发现该镀层由非常细的微晶构成。

关键词: 化学镀镍, 低磷, X射线衍射

Abstract: The low phosphorus coatings(LP) had superior corrosion resistence to that of high phosphorus(HP) in alkaline and neutral NaCl sulutions. The microhardness of the coatings increaed from 454 Hv to 890 Hv when they were heated at 350℃ for one hour. Two exothermic peaks were observed at 341. 6℃and 406. 2℃, which respectively corresponded to form the new phases Ni_5P_2 and Ni_3P in the differential thermal analysis. The atomic structure of as-deposited coatings in the terms of X-ray diffraction had confirmed that the coatings coasisted of extremely fine crystallites.

Key words: Electroless nickel, Low phosphorus, X-ray diffraction, Differential thermal analysis.

中图分类号: