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电化学(中英文) ›› 1996, Vol. 2 ›› Issue (1): 89-95. 

• 研究论文 • 上一篇    下一篇

熔融碳酸盐燃料电池研究

李乃朝,衣宝廉,孔莲英,张恩俊,林化新,曲天锡,程英才   

  1. 中科院大连化学物理研究所,化学工程研究室
  • 收稿日期:1996-02-28 修回日期:1996-02-28 出版日期:1996-02-28 发布日期:1996-02-28

Research on Molten Carbnate Fuel Cell

Li Naichao; Yi Baolian; Kong Lianying; Zhang Enjun;Lin Huaxin; Qu Tianxi; Cheng Yingcai   

  1. (Dept. of Chemical Engineering, Dalian Institute of Chemical Physics, Chinese Academy, Dalian 116011
  • Received:1996-02-28 Revised:1996-02-28 Published:1996-02-28 Online:1996-02-28

摘要: 以烧结Ni作电极,以LiAlO2无机膜作电池隔膜,组装成了电极面积28cm2的小型熔融碳酸盐燃料电池,试验了各种工作条件对电池性能的影响,电池经多次启动性能无衰减。放电电流密度100mA/cm2,电池电压0.95V;放电电流密度125mA/cm2,电池输出功率114mW/cm2;燃料气利用率80%,电池能量效率61%。

关键词: 熔融碳酸盐燃料电池, 电池性能, 输出功率, 能量效率

Abstract: Cold-roll-milling has been evaluated as a technique for preparing porous LiAlO_2 matrices for use as a molten carbonate fuel cell electrolyte matrix. This technique produces reliable electrolyte structures with the following characteristics and advantages: ease of handling, uniform thickness, using nontoxic inorganic solvents, controlled pore size distribution, and ability to be impregnated with the alkali carbonate without fracrure.The Molren Carbnatod Fuel Cell(MCFC) was assembled from sintered Ni electrodes and LiAlO_2 electrolyte matrix, the electrode area is 28 cm ̄2, the effect of operating conditions on cell performance was tested, it was found that the cell performance changed little with many times of starting. At current density 100 mA/cm ̄2 , the cell volltage is 0. 95 V. At current density 125 mA/cm ̄2, the cell output power is 114 mW/cm ̄2. At fuel utilization 80%, the cell energy efficiency is 61%.

Key words: Molten Carbnate Fuel Cell, Cell performance, Output power, Energy efficiency

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