以MgO和V2O5为原料,应用固相合成法制备具有单斜结构的MgV2O6.在非质子性电解液(如Mg(AlBu2Cl2)2/THF溶液)中,Mg2+在这一正极材料中表现出较好的充/放电循环性能.
袁华堂
,
焦丽芳
,
曹建胜
,
刘秀生
,
赵明
,
王永梅
. 可再充镁离子电池正极材料MgV_2O_6的制备及其电化学性能研究[J]. 电化学, 2004
, 10(4)
: 460
-463
.
DOI: 10.61558/2993-074X.1602
MgV_2O_6was synthesized by conventional solid-state reaction from MgO and V_2O_(5)as starting materials. X-Ray diffraction analysis showed that the prepared sample belongs to the monoclinic structure. Electrochemical magnesium insertion from aprotic electrolytes such as organomagnesium halides into this host was found possible and exhibited charge/discharge circulation.
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