Fe(Ⅲ)-草酸-葡萄糖酸钙媒质体系间接电化学还原及棉织物染色的研究

doi:10.61558/2993-074X.2869

电化学（中英文） ›› 2011, Vol. 17 ›› Issue (4): 444-447. doi: 10.61558/2993-074X.2869

Fe(Ⅲ)-草酸-葡萄糖酸钙媒质体系间接电化学还原及棉织物染色的研究

王清芝*, 王炜

东华大学，生态纺织科学技术教育部重点实验室，上海 201620

收稿日期:2011-07-12 修回日期:2011-08-17 出版日期:2011-11-28 发布日期:2011-09-29
通讯作者: 王清芝 E-mail:wangqingzhi@mail.dhu.edu.cn

Indirect Electrochemical Reduction and Cotton Dyeing Process in Fe(Ⅲ)-Oxalate-Calcium Gluconate System

WANG Qing-Zhi*, WANG Wei

Donghua Unversity, Key Laboratory of Science & Technology of Eco-Textile, Ministry of Education, Shanghai 201620, China

Received:2011-07-12 Revised:2011-08-17 Published:2011-11-28 Online:2011-09-29
Contact: WANG Qing-Zhi E-mail:wangqingzhi@mail.dhu.edu.cn

摘要/Abstract

摘要： 应用循环伏安法研究了Fe(Ⅲ)-草酸-葡萄糖酸钙媒质体系的电化学行为及其可能的反应机理，实验表明Fe(Ⅱ)-葡萄糖酸盐起着最终的还原作用。电解还原时间、工作电压和阴极面积这三个因素影响着电流效率，在Fe(Ⅲ)-草酸-葡萄糖酸钙媒质体系中，还原大红R的电流效率最高可达89%，其电解还原时间10min，工作电压4V，阴极面积40cm2。

关键词: 循环伏安, 电流效率, 工作电压, 阴极面积, 棉织物染色；Fe(Ⅲ)-草酸-葡萄糖酸钙媒质体系

Abstract: The electrochemical behavior and possible reaction mechanism in Fe(Ⅲ)-oxalate-calcium gluconate system were studied by cyclic voltammetry. The results showed that Fe(Ⅱ)-gluconate was the final reductant. The reduction time, the working voltage and the cathode area influenced the current efficiency. The high current efficiency of 89% for the indirect electrochemical reduction of Vat Scarlet R could be achieved with reduction time of 10 min, working voltage of 4 V and cathode area of 40 cm2 in Fe(Ⅲ)-oxalate-calcium gluconate system.

Key words: cyclic voltammetry (CV), current efficiency;working voltage, cathode area, Fe(Ⅲ)-oxalate-calcium gluconate system;cotton dyeing

中图分类号:

O646

王清芝, 王炜. Fe(Ⅲ)-草酸-葡萄糖酸钙媒质体系间接电化学还原及棉织物染色的研究[J]. 电化学（中英文）, 2011, 17(4): 444-447.

WANG Qing-Zhi, WANG Wei. Indirect Electrochemical Reduction and Cotton Dyeing Process in Fe(Ⅲ)-Oxalate-Calcium Gluconate System[J]. Journal of Electrochemistry, 2011, 17(4): 444-447.

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https://electrochem.xmu.edu.cn/CN/Y2011/V17/I4/444

参考文献

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Fe(Ⅲ)-草酸-葡萄糖酸钙媒质体系间接电化学还原及棉织物染色的研究

Indirect Electrochemical Reduction and Cotton Dyeing Process in Fe(Ⅲ)-Oxalate-Calcium Gluconate System

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