聚间甲氧基苯胺的结构及其氧化还原活性研究

电化学（中英文） ›› 2004, Vol. 10 ›› Issue (2): 205-209.

聚间甲氧基苯胺的结构及其氧化还原活性研究

何云游,许一婷,戴李宗,Gal Jean-Yves,吴辉煌

厦门大学化学化工学院固体表面物理化学国家重点实验室,厦门大学化学化工学院固体表面物理化学国家重点实验室,厦门大学化学化工学院固体表面物理化学国家重点实验室,法国国家科研中心水科学研究所蒙彼利埃大学,厦门大学化学化工学院固体表面物理化学国家重点实验室福建厦门361005 ,福建厦门361005 ,福建厦门361005 ,蒙彼利埃34095 ,福建厦门361005

收稿日期:2004-05-28 修回日期:2004-05-28 出版日期:2004-05-28 发布日期:2004-05-28

Structures and Redox Activities of Poly(m-methoxyaniline)

HE Yun-you~

(1),XU Yi-ting~(1),DAI Li-zong~(*1),Gal Jean-yves~(2),Wu Hui-huang~(1) Physical Chemistry of Solid Surfaces,Xiamen University,Xiamen 361005, China, 2.UMR Laboratory Hydrosciences. Maison des Sciences de l'Eau de Montpellier. Université Montpellier II. Cedex 05 Montpellier 34095,France

Received:2004-05-28 Revised:2004-05-28 Published:2004-05-28 Online:2004-05-28

摘要/Abstract

摘要： 　应用循环伏安法研究经HCl、TSA和HClO4等不同酸掺杂的聚间甲氧基苯胺(PmMAn)的电化学活性.结果表明,HClO4是合成PmMAn的最佳酸介质,在此介质中得到的聚合产物具有良好的氧化还原活性.FT IR,SEM和XRD测试分别说明,酸根离子作为抗衡阴离子嵌入PmMAn分子链,并对聚合物的氧化还原活性有较大影响;PmMAn表现出典型的高分子晶体性质,符合单斜晶系的特征.

关键词: 聚间甲氧基苯胺, 氧化还原活性

Abstract: Poly(m-methoxyaniline), PmMAn, was prepared in the presence of HCl, p-toluene-sulfonic acid and perchloric acid. By using cyclic voltammetry, the effect of different acid dopant on electrochemical activities of PmMAn was studied. The results showed that perchloric acid is the best acid to prepare PmMAn with good electrochemical activities The FTIR spectra indicate that the acid radical anions have embedded into PmMAn molecularchain as counter-ion during synthetic process, and this great influences the redox activities of PmMAn. SEM and XRD measurements illustrate that PmMAn is characterized by its typical molecular crystalline being monoclinic.

Key words: Poly(m-methoxyaniline), Electrochemical properties, Polymer structures

中图分类号:

O631

何云游,许一婷,戴李宗,Gal Jean-Yves,吴辉煌. 聚间甲氧基苯胺的结构及其氧化还原活性研究[J]. 电化学（中英文）, 2004, 10(2): 205-209.

HE Yun-you~. Structures and Redox Activities of Poly(m-methoxyaniline)[J]. Journal of Electrochemistry, 2004, 10(2): 205-209.

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链接本文: https://electrochem.xmu.edu.cn/CN/

https://electrochem.xmu.edu.cn/CN/Y2004/V10/I2/205

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