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电化学(中英文) ›› 2007, Vol. 13 ›› Issue (4): 415-419. 

• 研究论文 • 上一篇    下一篇

芦丁的电化学伏安行为及其应用

钱宗耀;李炳奇;刘红;夏新福;王银美;牛雅萍;   

  1. 石河子大学化学化工学院,石河子大学化学化工学院,石河子大学化学化工学院,石河子大学化学化工学院,石河子大学化学化工学院,石河子大学化学化工学院 石河子大学生命科学学院,新疆石河子832003
  • 收稿日期:2007-11-28 修回日期:2007-11-28 出版日期:2007-11-28 发布日期:2007-11-28

Voltammetric Behavior of Rutin and Its Application

QIAN Zong-yao1,2,LI Bing-qi1,LIU Hong1,XIA Xin-fu1,WANG Yin-mei1,NIU Ya-ping1   

  1. (1.College of Chemistry and Chemical Engineering,Shihezi University,Shihezi 832003,Xinjiang,China,2.College of Life Science Shihezi University,Shihezi 832003,Xinjiang,China
  • Received:2007-11-28 Revised:2007-11-28 Published:2007-11-28 Online:2007-11-28

摘要: 芦丁在0.1mol/L Tris-HCl缓冲溶液(pH=8.3)中产生灵敏的线性扫描极谱峰,峰电位EP=-1.10V(vs.Ag/AgCl).峰电流与芦丁浓度在7×10-7~9.8×10-6mol/L范围内呈良好的线性关系.可用于乌拉尔甘草内黄酮含量的测定.线性扫描和循环伏安法测试表明,该体系属具有吸附性的准可逆过程体系.

关键词: 芦丁, 伏安行为, 线性扫描

Abstract: In solution of 0.1mol/L Tris-HCl(pH=8.3),a sensitive reduction peak of rutin was obtained by liner sweep polarography.The peak potential was-1.10V(vs.Ag/AgCl).The peak current was proportional to the concentration of rutin over the range of 7×10-7~9.8×10-6mol/L.This method has been applied to the determination of the flavonoid in G.Uralensis.The results showed that the reduction process was irreversible with adsorption that studied by linear sweep and cyclic voltammetry.

Key words: rutin, voltammetric behavior, linear sweep polarography

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