欢迎访问《电化学(中英文)》期刊官方网站,今天是

电化学(中英文) ›› 2017, Vol. 23 ›› Issue (3): 297-306.  doi: 10.13208/j.electrochem.161047

• 有机电化学及电化学工业近期研究专辑(华东理工大学张新胜教授、北京化工大学曾程初教授主编) • 上一篇    下一篇

高烯丙醇和高烯丙胺的电化学合成研究进展

钟伟强,梁向晖,黄精美*   

  1. 广东省功能分子工程重点实验室,化学与化工学院,华南理工大学 广州 510641
  • 收稿日期:2016-10-31 修回日期:2017-01-16 出版日期:2017-06-29 发布日期:2017-01-19
  • 通讯作者: 黄精美 E-mail:chehjm@scut.edu.cn
  • 基金资助:

    国家自然科学基金(21471059)、华南理工大学探索性项目(Y1140410,Y9160040)资助

Electrochemical Synthesis of Homoallylic Alcohols and Homoallylic Amines

ZHONG Wei-qiang, LIANG Xiang-hui, HUANG Jing-mei*   

  1. Key Laboratory of Functional Molecular Engineering of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, Guangdong 510641, China
  • Received:2016-10-31 Revised:2017-01-16 Published:2017-06-29 Online:2017-01-19
  • Contact: HUANG Jing-mei E-mail:chehjm@scut.edu.cn

摘要:

电化学技术已经在有机合成得到广泛重视,本文简要概述了利用羰基和亚胺的电化学烯丙基化反应合成高烯丙醇和高烯丙胺的方法. 该方法已经得到了比较瞩目的进展,特别是在水相中的电化学烯丙基化反应,充分体现了绿色化学的特点。在提高电流效率和区域选择性,利用手性催化剂进行手性合成等方面还期待更多的关注和发展.

关键词: 电化学合成, 烯丙醇, 烯丙胺, 烯丙基化反应

Abstract:

Electrochemical technique has been widely applied in the organic synthesis. This review focuses on the electrochemical synthesis of homoallylic alcohols and homoallylic amines from the allylation of carbonyl compounds and imines. This method has been developed impressively, especially in the field of electrochemical allylation in a green solvent of aqueous media. Improvement of the efficiency of the electricity, regio-selectivity and chiral synthesis are expected.

Key words: Eletrochemical synthesis, Homoallylic alcohols, Homoallylic amines, Allylation

中图分类号: