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电化学(中英文) ›› 2003, Vol. 9 ›› Issue (1): 93-97. 

• 研究论文 • 上一篇    下一篇

从废铁屑电解制备纯铁及其腐蚀特性

曹为民,印仁和,严惠根,叶志强   

  1. 上海大学理学院化学系,上海大学理学院化学系,上海大学理学院化学系,上海大学理学院化学系 上海200436 ,上海200436 ,上海200436 ,上海200436
  • 收稿日期:2003-02-28 修回日期:2003-02-28 出版日期:2003-02-28 发布日期:2003-02-28

Pure Iron Electrolyzed from Scrap Iron Chips and its Corrosion Characteristics

Cao Wei_min*, Yin Ren_he, Yan Hui_Ceng, Ye Zhi_qiang   

  1. (Dept.Chem.Shanghai University,Shanghai 200436,China)
  • Received:2003-02-28 Revised:2003-02-28 Published:2003-02-28 Online:2003-02-28

摘要:  以工业废铁屑作原料制备高纯度电解铁,并优化了在氯化物溶液中的电解工艺条件,所得样品纯度最高可达到99.983%.通过SEM断面形貌观察,该电解铁样品非常致密.交流阻抗及腐蚀速率测定表明,电解铁的纯度越高,其耐腐蚀性能越好.

关键词: 纯铁, 电解制备, 腐蚀特性, SEM

Abstract: The high purity electrolytic iron was made from scrap iron chips. Electrolytic conditions of pure iron were determined in chloride baths and the highest purity was 99.983% by chemical analysis. Pure iron had very compact texture and high mechanical strength by SEM figures of cross section. In deaerated 0.5 kmol·m-3H2SO4 and 0.5 kmol·m-3NaCl solutions, the corrosion rate of iron decreased with increasing purity.

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