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电化学(中英文) ›› 2000, Vol. 6 ›› Issue (4): 421-427. 

• 研究论文 • 上一篇    下一篇

电化学原位拉曼光谱技术对金电极表面生物分子吸附行为研究

吴霞琴,曹晓卫,王浙苏,孟晓云,章宗穰   

  1. 上海师范大学化学系!上海200234,上海师范大学化学系!上海200234,上海师范大学化学系!上海200234,上海师范大学化学系!上海200234,上海师范大学化学系!上海200234
  • 收稿日期:2000-11-28 修回日期:2000-11-28 出版日期:2000-11-28 发布日期:2000-11-28

A study of the Adsorption Behaviors on the Surface of Gold electrode by In-situ Electrochemical Raman Spectroscopy

WU Xia qin, CAO Xiao wei, WANG Zhe su, MENG Xiao yun, ZHANG Zong rang *   

  1. (Dept. of Chem., Shanghai Teachers Univ., Shanghai 200234 China
  • Received:2000-11-28 Revised:2000-11-28 Published:2000-11-28 Online:2000-11-28

摘要: 报道腺嘌呤在裸金电极及其修饰的金电极上的电化学原位拉曼光谱图 ,着重分析了不同电位下腺嘌呤和超氧化物歧化酶在金电极上的吸附及其相互作用 ,初步讨论了腺嘌呤对促进超氧化物歧化酶电子传递过程的作用机制 .

关键词: 电化学原位拉曼光谱技术, 超氧化物歧化酶, 腺嘌吟

Abstract: The results of in situ measurements with Raman spectroelectrochemical thchnique on bare gold electrode and adenine modified gold electrode were reported. The adsorption behaviors of adenine and superoxide dismutase(SOD) and their interactions with gold electrode were analyed. The mechanism of promoted electron transfer process of SOD in the presence of adenine at gold electrode surface is discussed.

Key words: In situ Raman spectroelectrochemistry, Superoxide dismutase, Adenine