关键词: 自组装膜, 膜电容, 膜的几何厚度, 电化学表观有效厚度

Abstract: The geometrical thickness, which was obtained from the capacitance of membrane, can be used to characterize the existence of membrane. The apparent effective thickness, which is analyzed from the electron transfer constant of transmembrane, can be used to determine the degree of “collapsed" of molecules. Though the two thicknesses were different in value, there was no contradiction. The influence on the geometrical thickness is little, but the effect to the apparent effective thickness is great from the small “collapsed" area in the membrane from the given calculation.

Key words: Self assembled monolayers, The capacitance of membrane, The geometrical thickness of membrane, The apparent effective thickness