欢迎访问《电化学(中英文)》期刊官方网站,今天是

电化学(中英文) ›› 2000, Vol. 6 ›› Issue (4): 412-416. 

• 研究论文 • 上一篇    下一篇

金属腐蚀监测的光波导传感方法研究

黎学明,陈伟民,黄尚廉,张娜,黄宗卿   

  1. 光电技术及系统教育部重点实验室,重庆大学!四川重庆400044,光电技术及系统教育部重点实验室,重庆大学!四川重庆400044,光电技术及系统教育部重点实验室,重庆大学!四川重庆400044,重庆大学化学化工学院!四川重庆400044,重庆大学化学化工学院!四川重庆400044
  • 收稿日期:2000-11-28 修回日期:2000-11-28 出版日期:2000-11-28 发布日期:2000-11-28

A Study of Monitoring Corrosion of Metal Via an Optic Waveguide Sensing Method

LI Xue ming *1 ,CHEN Wei ming 1, HUANG Shang lian 1, ZHANG Na 2, HUANG Zong qing 2   

  1. (1.The Key Labor. for Optoelectronic Tech. & System, The Mini. Edu. Commission of China, Chongqing Univ., Chongqing 400044, China) 2.Dept. of Applied Chem.
  • Received:2000-11-28 Revised:2000-11-28 Published:2000-11-28 Online:2000-11-28

摘要: 本文提出一种用于金属腐蚀监测的光波导传感方案 ,用金属膜层局部取代光波导的介质包层 ,构成腐蚀敏感膜 ,从而获取金属腐蚀信息 .依据波导理论选用 72 1比色皿上的石英玻璃作为光波导材料 ,利用电化学方法在波导材料内表面上形成Fe C合金腐蚀敏感膜 ,并用XRD、EDX等对膜层结构进行分析 .在电化学腐蚀膜的同时 ,用光学方法记录光波导输出光功率的变化 ,实验结果表明电化学方法与光学方法获取的腐蚀信息同步 ,证实了所提传感方案可行

关键词: 光波导, 腐蚀监测, Fe-C合金

Abstract: An optical wave guide sensing method was proposed for monitoring corrosion of metal in outdoors steel structures. Replacing the cladding of wave guide with metal film in a particular location, the method takes the metal film as the corrosion sensitive film. The experiment of waveguide sensor was carried out on a 721 colorimetric vessel, with which the soution is held in itself and the light is propagated in its sidewall. A Fe C alloy film was electroplated onto the inner sied of vessel to form the corrosion sensitive film. The structure of the Fe C alloy film was studied by XRD、EDX and burning gas capacity method.The comparison test of optics and electrochemistry was used to eveluate the sensing ability of the film; it's shown that the light propagating in the opitical waveguide is affected by the polarization current. The result demonstrated the feasibility of using optical fiber corrosion sensors for monitoring corrosion of outdoor steel structures.

Key words: Optic wave guide, Corrosion monitoring, Fe C alloy