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电化学(中英文) ›› 2000, Vol. 6 ›› Issue (2): 227-232. 

• 研究论文 • 上一篇    下一篇

腐蚀介质中混凝土/钢筋界面电极电位分布的立体分析

胡荣宗,林昌健,周香,谭建光,赵雄超   

  1. 厦门大学化学系!固体表面物理化学国家重点实验室,物理化学研究所,福建厦门361005,厦门大学化学系!固体表面物理化学国家重点实验室,物理化学研究所,福建厦门361005,厦门大学化学系!固体表面物理化学国家重点实验室,物理化学研究所,福建厦门361005,厦门大学化学系!固体表面物理
  • 收稿日期:2000-05-28 修回日期:2000-05-28 出版日期:2000-05-28 发布日期:2000-05-28

An Investigation on the Corrosion Potential Imaging at the Interface of Concrete/Reinforcing Bar in Corrosion Media

HU Rong_zong, LIN Chang_jian, ZHOU Xiang, TAN Jian_guang, ZHAO Xiong_chao   

  1. (Dept. of Chem. State Key Lab. of Physical Chemistry for Solid Surface, Inst. of Phys. Chem., Xiamen Univ., Xiamen 361005, China
  • Received:2000-05-28 Revised:2000-05-28 Published:2000-05-28 Online:2000-05-28

摘要: 由于混凝土的隔离和高绝缘性 ,常规的电化学技术、微探针扫描技术均难于获得在腐蚀介质的浸泡下混凝土 /钢筋界面 ,特别是不同深处的混凝土 /钢筋界面的电位分布 .本文提出用阵列电极法并结合电子技术和微机控制技术 ,获得同一水平面上混凝土 /钢筋界面以及不同深处的混凝土 /钢筋界面的电位分布立体信息图 .结果表明 :在NaCl介质中经过一段时间的浸泡 ,混凝土中的钢筋腐蚀可发生并发展 ;而在Na2 SO4 介质中经过一段时间的浸泡 ,虽钢筋腐蚀一般不发生 ,但混凝土可能破坏 .不同深处混凝土 /钢筋界面腐蚀优先发生在混凝土覆盖较浅的部位 .

关键词: 混凝土, 钢筋, 阵列电极

Abstract: The iron array electrode covered with concrete as a new electrochemical technique is applied to map the potential imaging and to investigate on the iron electrode corrosion process under concrete: In Cl - solution the corrosion of the iron array electrode covered with concrete had been prevented for a short term since the concrete protection, but the corrosion still occurreed and developed after immersed for a long time. In SO 4 2- solution although the sample had being immersed for a long time and the concrete was possibly broken, the corrosion did not develop. In Cl - solution the corrosion of the iron array electrode covered with concrete in deferent deeps occurred first where the concrete covered was thin.

Key words: Array electrode, Concrete, Reinforcing bar, Iron eletrode

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