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电化学(中英文) ›› 1998, Vol. 4 ›› Issue (1): 101-105. 

• 研究论文 • 上一篇    下一篇

钐离子在油/水界面迁移的电化学行为

狄俊伟,徐肖邢,吴莹,范瑞溪   

  1. 苏州大学化学化工学院
  • 收稿日期:1998-02-28 修回日期:1998-02-28 出版日期:1998-02-28 发布日期:1998-02-28

The Migration of Samarium(Ⅲ)across Oil/water Interface

Di Junwei* Xu Xiaoxing Wu Ying Fan Ruixi   

  1. (School of Chem. and Chemical Eng., Suzhou Univ., Suzhou 215006)
  • Received:1998-02-28 Revised:1998-02-28 Published:1998-02-28 Online:1998-02-28

摘要: 钐离子在油/水界面迁移的电化学行为①狄俊伟*徐肖邢**吴莹范瑞溪(苏州大学化学化工学院苏州215006)近年来,人们对中性载体推动金属离子在油/水界面转移的报道较多[1~4].通常的实验研究大多采用水相中的金属离子MZ+大大过量,而于油相中溶解少量的...

Abstract: The migration of Samarium(Ⅲ)across water/nitrobenzene (w/nb) interface facilitated by diantipyrylmethane (DAM) and the electrochemical behaviour affected by emulsifier OP in the nb phase have been studied by normal and convolute cyclic voltammetry. It is concluded that the formation of the complex occurs at w/nb interface and the mechanism of the samarium(Ⅲ)transfer across w/nb interface facilitated by DAM is E mechanism.

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