非水溶剂中八丁氧基2，3－萘酞菁氯锰（Ⅲ）的电化学研究

电化学（中英文） ›› 1996, Vol. 2 ›› Issue (4): 448-451.

非水溶剂中八丁氧基2，3－萘酞菁氯锰（Ⅲ）的电化学研究

杨素苓,刘尔生,陈耐生,黄金陵,王晓玉,卜平段,武彪,吴谊群,左霞

福州大学化学系,黑龙江大学化学系

收稿日期:1996-11-28 修回日期:1996-11-28 出版日期:1996-11-28 发布日期:1996-11-28

Study of Electrochemistry of Octa Butyl 2, 3 Naphthalocyanine Manganese(Ⅲ) in Nonaqeous Solvents

Yang Suling Liu Ersheng Chen Naisheng Huang Jinling

(Dept. of Chem., Fuzhou Univ., Fuzhou 350002) Wang Xiaoyu Pu Ping Duan Wubiao Wu Yiqun Zuo Xia (Dept. of Chem., Heilongjiang Univ., Harbin 150080

Received:1996-11-28 Revised:1996-11-28 Published:1996-11-28 Online:1996-11-28

摘要/Abstract

摘要： 非水溶剂中八丁氧基２，３萘酞菁氯锰（Ⅲ）的电化学研究①杨素苓刘尔生陈耐生黄金陵（福州大学化学系，福州３５０００２）王晓玉卜平段武彪吴谊群左霞（黑龙江大学化学系，哈尔滨１５００８０）金属萘酞菁配合物由于含有比相应的酞菁配合物更大的π共轭体系，因而具...

Abstract: The electrochemical behavior of 5,9,14,18,23,27,32,36 Octa Butyl 2,3 Naphalocyanine Manganese (Ⅲ) [(BuO) 8NPcMn(Ⅲ)Cl] in four nonaqueous solvents was studied by means of cyclic voltammetry, and the corresponding half wave potentials (E 1/2 ) of redox reactions were obtained. Four (or five) pairs of redox peaks were assigned. The solvent effect on the electrochemical characteristics of this coordination compound was also discussed preliminarily, and the electrochemical behavior of the complex was compared with that of nonsubstitued naphthalocyanine.

Key words: Octa buty1 2, 3 naphthalocyanine manganese (Ⅲ), Electrochemistry, Nonaqeous solvents

中图分类号:

O628.5

杨素苓,刘尔生,陈耐生,黄金陵,王晓玉,卜平段,武彪,吴谊群,左霞. 非水溶剂中八丁氧基2，3－萘酞菁氯锰（Ⅲ）的电化学研究[J]. 电化学（中英文）, 1996, 2(4): 448-451.

Yang Suling Liu Ersheng Chen Naisheng Huang Jinling . Study of Electrochemistry of Octa Butyl 2, 3 Naphthalocyanine Manganese(Ⅲ) in Nonaqeous Solvents[J]. Journal of Electrochemistry, 1996, 2(4): 448-451.

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