亚硝酸根在钴（Ⅱ）－邻菲口罗啉络合物存在下的电催化还原

电化学（中英文） ›› 1996, Vol. 2 ›› Issue (2): 186-191.

亚硝酸根在钴（Ⅱ）－邻菲口罗啉络合物存在下的电催化还原

同健,党晓军,力虎林

兰州大学化学系

收稿日期:1996-05-28 修回日期:1996-05-28 出版日期:1996-05-28 发布日期:1996-05-28

Electrocatalytic Reduction of Nitrite in The Presence of Complex of Cobalt(Ⅱ) and 1,10 Phenanthroline

Tong Jian Dang Xiaojun Li Hulin

(Department of chemistry, Lanzhou University, Lanzhou 730000

Received:1996-05-28 Revised:1996-05-28 Published:1996-05-28 Online:1996-05-28

摘要/Abstract

摘要： 研究钴（Ⅱ）－邻菲口罗啉络合物Ｃｏ（Ｐｈｅｎ）２＋２在玻碳电极上的伏安行为和对亚硝酸根电化学还原的催化作用以及影响催化作用的因素

关键词: 亚硝酸根, 邻菲口罗啉, 电化学催化

Abstract: The electrochemistry of cobalt(Ⅱ) 1,10 phenanthroline Co(Phen) 2+ 2 complex and its ability to electrocatalyze the reduction of nitrite were studied , we found that this complex could act as a catalyst in alkaline or neutral solution for nitrite reduction. We have investigated the effect of the complex composition on electrocatalytic ability. The effects of pH value, complex concentration, regeneration and activation of electrocatalyst on the catalytic current have been studied and discussed.

Key words: Nitrite, Phenanthroline, Electrocatalytic

中图分类号:

O641.4

同健,党晓军,力虎林. 亚硝酸根在钴（Ⅱ）－邻菲口罗啉络合物存在下的电催化还原[J]. 电化学（中英文）, 1996, 2(2): 186-191.

Tong Jian Dang Xiaojun Li Hulin . Electrocatalytic Reduction of Nitrite in The Presence of Complex of Cobalt(Ⅱ) and 1,10 Phenanthroline[J]. Journal of Electrochemistry, 1996, 2(2): 186-191.

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https://electrochem.xmu.edu.cn/CN/Y1996/V2/I2/186

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