PMMA基凝胶聚合物电解质双电层电容器的研究

doi:10.61558/2993-074X.1789

电化学（中英文） ›› 2007, Vol. 13 ›› Issue (1): 101-105. doi: 10.61558/2993-074X.1789

PMMA基凝胶聚合物电解质双电层电容器的研究

孟祥利;殷金玲;任娟;张宝宏;

哈尔滨工程大学化工学院,哈尔滨工程大学化工学院,哈尔滨工程大学化工学院,哈尔滨工程大学化工学院黑龙江哈尔滨150001,黑龙江哈尔滨150001,黑龙江哈尔滨150001,黑龙江哈尔滨150001

收稿日期:2007-02-28 修回日期:2007-02-28 发布日期:2007-02-28 出版日期:2007-02-28

Investigations on EDLCs using PMMA-based Gel Polymer Electrolytes

MENG Xiang-li,YIN Jin-ling,REN Juan,ZHANG Bao-hong*

(School of Chemical Enginering,Harbin Engineering University,Harbin 150001,Heilongjiang,China

Received:2007-02-28 Revised:2007-02-28 Online:2007-02-28 Published:2007-02-28

摘要/Abstract

摘要： 以碳酸丙烯酯(PC)和碳酸乙烯酯(EC)作增塑剂,LiClO4作支持电解质,高比表面积活性炭为电极,内聚合法制作PMMA-PC+EC-LiClO4体系凝胶聚合物电解质(GPE)双电层电容器.应用交流阻抗、循环伏安、恒流充放电等方法研究了该电容器的性能.结果表明,PMMA-GPE的离子电导率在室温下达3.7 mS.cm-1,电容器的工作电压达3 V,比容量达41.6 F.g-1(I=1 mA.cm-2),等效串联电阻仅为几欧姆.

关键词: 双电层电容器, 凝胶聚合物电解质, 聚甲基丙烯酸甲酯, 增塑剂, 活性炭

Abstract: Polymethyl methacrylate(PMMA) based gel polymer electrolytes electrochemical double layer capacitors(GPE-EDLCs) were fabricated by an in situ polymerisatonal method with actived carbon electrodes,using propylene carbonate(PC) and ethylene carbonate(EC) as plasticizer,lithion perchlorate as surporting electrolytes.The ion conductivity values of GPEs were evaluated by AC impedance.The properties of PMMA-based GPEs capacitors were researched by impedance spectrum,cyclic voltammetry,galvanostatic charge-discharge.It showed that the ion conductivities of the PMMA-based gel polymer electrolytes reached to 3.7 mS·cm-1 at ambient tempreture.The working voltage of the capacitors reached to 3.0 V.The specific capacitance of the capacitor was obtained as high as 41.6 F·g-1(I=1 mA·cm-2).The equivalent serial resistance of the capacitors were just several Ohm.

Key words: EDLCs, gel polymer electrolytes, PMMA, plasticizer, activated carbon

中图分类号:

TM535

孟祥利, 殷金玲, 任娟, 张宝宏, . PMMA基凝胶聚合物电解质双电层电容器的研究[J]. 电化学（中英文）, 2007, 13(1): 101-105.

MENG Xiang-li, YIN Jin-ling, REN Juan, ZHANG Bao-hong. Investigations on EDLCs using PMMA-based Gel Polymer Electrolytes[J]. Journal of Electrochemistry, 2007, 13(1): 101-105.

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链接本文: https://electrochem.xmu.edu.cn/CN/10.61558/2993-074X.1789

https://electrochem.xmu.edu.cn/CN/Y2007/V13/I1/101

参考文献

[1]Hashmi S A,Kumar A,Tripathi.Investgations on elec-trochemical surpercapacitors using polypyrrole redoxeletrodes and PMMA based gel electrodes and PMMAbased gel electrolytes[J].European Polymer Journal,2005,41:1373-1379. [2]LIU X J,Osaka T.Properties of electric double-layercapacitors with various polymer gel electrolytes[J].JElectrochem Soc,1997,144(9):3066-3071. [3]Hashmi S A,Suematsu S,Naoi K.All solid-state redoxsupercapacitors based on supramolecular 1,5-diamino-anthraquinone oligomeric electrode and polymeric elec-trolytes[J].J Power Sources,2004,137:145-151. [4]Lewang A,Krzyzanowski M.A new polymer electrolyteploy(arylonitrile)-dimethylsulpnoxide-salt for electro-chemical capacitors[J].J Electrochimica Acta,2003,48:1325-1329. [5]Fabio A D,Giorgi A G,Mastragostino N,et al.Carbon-polymer(3-methylthiopnene)hybrid supercapacitors[J].J Electrochem Soc,2001,148(8):A845-A850. [6]Levie R D.On porus electrodes in electrolytes solution[J].J Electrochimica Acta,1973,8:751-780. [7]Lewandowski A,Krzyzanowski M.Anewpolymer electro-lyte poly(arylonitrile)-dimethylsulphoxide-salt for elec-trochemical capacitors[J].J Electrochimica Acta,2003,48:1325-1329. [8]Malcolm D,Amanda J,Pappin,et al.Devolopment ofelectrochemical capacitors incorporating processable pol-ymer gel electrolytes[J].J Electrochimica acta,1998:10(43):1601-1605. [9]LIU X J,Osaka T.All-solid-state electric double-layercapacitors with isotropic high-density grahiteelectrodeand polyethylene oxide/LiClO4polymer electrolyte[J].JElectrochem Soc,1996,143(12):3982-3986. [10]Ishikawa M,Ihara M,Morita M,et al.Electric doublelayer capacitors with newgel electrolytes[J].J Electro-chimica Acta,1995,40(13):2217-2222. [11]Conway B E.Electrochemical supercapacitors scientificfundamentals and technological applications[M].NewYork:Kluwer Acdamic/Plenum Publisher,1999.

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PMMA基凝胶聚合物电解质双电层电容器的研究

Investigations on EDLCs using PMMA-based Gel Polymer Electrolytes

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