泡沫镍载 NiCO2O4电极的制备及其催化 H2O2电氧化的性能

doi:10.13208/j.electrochem.180921

电化学（中英文） ›› 2020, Vol. 26 ›› Issue (1): 96-102. doi: 10.13208/j.electrochem.180921

泡沫镍载 NiCO₂O₄电极的制备及其催化 H₂O₂电氧化的性能

陈维伟, 张飞凡, 杜佳亮, 王毅, 赵春林, 朱凯, 曹殿学, 王贵领^*()

哈尔滨工程大学材料科学与化学工程学院,黑龙江哈尔滨 150001

收稿日期:2018-09-21 修回日期:2019-02-19 出版日期:2020-02-28 发布日期:2019-02-19
通讯作者: 王贵领 E-mail:wangguiling@hrbeu.edu.cn
基金资助:
国家大学生创新训练项目;国家自然科学基金项目(51572052)

Preparation and Electrocatalytic Performance of NiCo₂O₄/Ni Foam for Hydrogen Peroxide Electrooxidation

CHEN Wei-wei, ZHANG Fei-fan, DU Jia-liang, WANG Yi, ZHAO Chun-lin, ZHU Kai, CAO Dian-xue, WANG Gui-ling^*()

College of Material Science and Chemical Engineering, Harbin Engineering University,Harbin 150001, Heilongjiang, China

Received:2018-09-21 Revised:2019-02-19 Published:2020-02-28 Online:2019-02-19
Contact: WANG Gui-ling E-mail:wangguiling@hrbeu.edu.cn

摘要/Abstract

摘要：

本文以水热法结合热处理法原位制备了泡沫镍载 NiCo₂O₄纳米线电极,使用XRD、SEM和TEM对合成的 NiCo₂O₄纳米线进行了表征,NiCo₂O₄纳米线直径约80 nm,长度约 3 ~ 5 μm. 使用循环伏安和计时电流法测试了泡沫镍载NiCo₂O₄纳米线催化H₂O₂的电氧化性能,结果表明泡沫镍载NiCo₂O₄纳米线对H₂O₂电氧化有着优良的催化活性、稳定性和传质性能,在0.3 V电位下0.4 mol·L ^-1 H₂O₂和2 mol·L ^-1 NaOH溶液中氧化电流可达380 mA·cm ^-2.

关键词: H₂O₂电氧化, 水热法, 泡沫镍, NiCo₂O₄纳米线

Abstract:

The electrodes of Ni foam supported NiCo₂O₄ nanowires were prepared by hydrothermal method, followed by a thermal treatment in air, and were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). It was found that the NiCo₂O₄ nanowires had a diameter of about 50 nm with a length up to 3 ~ 5 μm. The catalytic performances of the Ni foam supported NiCo₂O₄ nanowires for H₂O₂ electrooxidation were studied by cyclic voltammetry and chronoamperometry. The results show that the Ni foam supported NiCo₂O₄ nanowires electrode exhibited superior activity, stability, and mass transport property for H₂O₂ electrooxidation. A current density of 380 mA·cm ^-2 was achieved at 0.3 V in 0.4 mol·L ^-1 H₂O₂ and 2 mol·L ^-1 NaOH at room temperature.

Key words: hydrogen peroxide electrooxidation, hydrothermal method, Ni foam, NiCo₂O₄ nanowires

中图分类号:

O646

陈维伟, 张飞凡, 杜佳亮, 王毅, 赵春林, 朱凯, 曹殿学, 王贵领. 泡沫镍载 NiCO₂O₄电极的制备及其催化 H₂O₂电氧化的性能[J]. 电化学（中英文）, 2020, 26(1): 96-102.

CHEN Wei-wei, ZHANG Fei-fan, DU Jia-liang, WANG Yi, ZHAO Chun-lin, ZHU Kai, CAO Dian-xue, WANG Gui-ling. Preparation and Electrocatalytic Performance of NiCo₂O₄/Ni Foam for Hydrogen Peroxide Electrooxidation[J]. Journal of Electrochemistry, 2020, 26(1): 96-102.

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链接本文: https://electrochem.xmu.edu.cn/CN/10.13208/j.electrochem.180921

https://electrochem.xmu.edu.cn/CN/Y2020/V26/I1/96

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泡沫镍载 NiCO₂O₄电极的制备及其催化 H₂O₂电氧化的性能

Preparation and Electrocatalytic Performance of NiCo₂O₄/Ni Foam for Hydrogen Peroxide Electrooxidation

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