全钒液流电池铂氢微型参比电极体系的构筑与性能

doi:10.13208/j.electrochem.141209

电化学（中英文） ›› 2015, Vol. 21 ›› Issue (2): 162-166. doi: 10.13208/j.electrochem.141209

全钒液流电池铂氢微型参比电极体系的构筑与性能

林志彬¹，董燕青²，郑明森²，董全峰^1,2*

1. 厦门大学能源学院，福建厦门 361005；2. 厦门大学化学化工学院，福建厦门 361005

收稿日期:2014-12-09 修回日期:2015-01-19 出版日期:2015-04-28 发布日期:2015-04-23
通讯作者: 董全峰 E-mail:qfdong@xmu.edu.cn

A Platinum-Hydrogen Reference Micro-Electrode for All Vanadium Redox Flow Battery

LIN Zhi-bin¹, DONG Yan-qing², ZHENG Ming-sen², DONG Quan-feng^1,2*

1. College of Energy, Xiamen University, Xiamen 361005, Fujian, China; 2. College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China

Received:2014-12-09 Revised:2015-01-19 Published:2015-04-28 Online:2015-04-23
Contact: DONG Quan-feng E-mail:qfdong@xmu.edu.cn

摘要/Abstract

摘要： 铂丝电极表面上电沉积一层金属钯，用阴离子交换隔膜材料封装，制得铂氢微型参比电极，工艺简单、稳定性高. 将该微型参比电极应用于全钒储能电池性能研究，可内置于电池多孔电极内部，监测电池正负极充放电性能. 结果显示，电池容量衰减主要归因于电解液中的活性物质V(IV)的逐渐减少及V(V)的积累导致正负极活性物质不平衡.

关键词: 参比电极, 全钒液流电池, PVP-PES隔膜

Abstract: A platinum-hydrogen reference micro-electrode was made with electroplating Pd on the surface of Pt wire and then coating anion membrane material. This reference electrode was built-in the porous electrode of the all vanadium redox flow batteries (VRFB), and monitored the charging /discharging and self-discharging of the VRFB. The results indicated that the capacity fading of VRFB occurred due to the graduate reduction of V(IV) active species in the electrolyte and the accumulation of V(V) in the positive electrode, leading to nonequilibrium of active species between the positive and negative electrodes.

Key words: reference electrode, all vanadium redox flow batteries, application

中图分类号:

TM911
O646

林志彬，董燕青，郑明森，董全峰*. 全钒液流电池铂氢微型参比电极体系的构筑与性能[J]. 电化学（中英文）, 2015, 21(2): 162-166.

LIN Zhi-bin, DONG Yan-qing, ZHENG Ming-sen, DONG Quan-feng*. A Platinum-Hydrogen Reference Micro-Electrode for All Vanadium Redox Flow Battery[J]. Journal of Electrochemistry, 2015, 21(2): 162-166.

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://electrochem.xmu.edu.cn/CN/10.13208/j.electrochem.141209

https://electrochem.xmu.edu.cn/CN/Y2015/V21/I2/162

参考文献

[1] Zhang Y(张燕), Song Y S(宋玉苏), Wang Y S(王源升). Performance of silver-silver chloride reference probe[J]. Journal of Chinese Society for Corrosion and Protection(中国腐蚀与防护学报), 2007, 27(3): 176-180.
[2] Tian B(田斌), Hu M(胡明), Li C F(李春福), et al. State of The art and future trends of Ag/AgCl reference electrodes for high temperature and high pressure aqueous systems[J]. Journal of Chinese Society for Corrosion and Protection(中国腐蚀与防护学报), 2003, 23(6): 370-374.
[3] Wang J L(王金龙), Wang J(王佳), Jia H G(贾红刚), et al. The state of the art and advance of the research and application of solid silver-silver chloride reference electrodes[J]. Journal of Chinese Society for Corrosion and Protection(中国腐蚀与防护学报), 2013, 33(2): 81-89.
[4] Xie S L(谢声洛). Analysis technology of ion selective electrode[M]. Beijing: Chemical Industry Press(化学工业出版社), 1985: 117-120.
[5] Suzuki H, Ozawa H, Sasaki S, et al. Micromachined liquid-junction Ag/AgCl reference electrode[J]. Sensors and Actuators B-Chemical, 1998, 46(2): 146-154.
[6] Kim H R, Kima Y D, Kima K I, et al. Enhancement of physical and chemical properties of thin film Ag/AgCl reference electrode using a Ni buffer layer[J]. Sensors and Actuators B-Chemical, 2004, 97(2/3): 348-354.
[7] Ruetschi P. Silver-silver sulfate reference electrodes for use in lead-acid batteries[J]. Journal of Power Sources, 2003, 116(1/2): 53-60.
[8] Shono K, Kobayashi T, Tabuchi M, et al. Proposal of simple and novel method of capacity fading analysis using pseudo-reference electrode in lithium ion cells: Application to solvent-free lithium ion polymer batteries[J]. Journal of Power Sources, 2014, 247: 1026-1032.
[9] Ventosa E, Skoumal M, Vázquez F J, et al. Operando studies of all-vanadium flow batteries: Easy-to-make reference electrode based on silvere-silver sulfate[J]. Journal of Power Sources, 2014, 271: 556-560.
[10] Zhang Q, Dong Q F, Zheng M S, et al. The preparation of a novel anion-exchange membrane and its application in all-vanadium redox batteries[J]. Journal of Membrane Science, 2012, 421: 232-237.
[11] Kausar N, Howe R, Skyllas-Kazacos M. Raman spectroscopy studies of concentrated vanadium redox battery positive electrolytes[J]. Journal of Applied Electrochemistry, 2001, 31(12): 1327-1332.
[12] Chen J Q(陈金庆), Zhu S Q(朱顺泉), Wang B G(王保国), et al. Model of open-circuit voltage for all-vanadium redox flow battery[J]. Journal of Chemical Industry and Engineering(化工学报), 2009, 60(1): 211-215.
[13] Vijayakumar M, Li L Y, Graff G, et al. Towards understanding the poor thermal stability of V5+ electrolyte solution in vanadium redox flow batteries[J]. Journal of Power Sources, 2011, 196(7): 3669-3672.

全钒液流电池铂氢微型参比电极体系的构筑与性能

A Platinum-Hydrogen Reference Micro-Electrode for All Vanadium Redox Flow Battery

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 10

Metrics

[1]	谭青龙，王海宁，卢善富，梁大为，武春晓，相艳. 表面修饰模式对Nafion离子选择性影响及在VRFB中的应用[J]. 电化学（中英文）, 2017, 23(4): 409-419.
[2]	杨莉，徐兵，王海，董泽华. 适用于钢筋混凝土腐蚀监测的长效MnO₂参比电极的研制[J]. 电化学（中英文）, 2017, 23(1): 36-44.
[3]	青格勒图, 郭伟男, 刘平, 王保国. 全钒液流电池的隔膜研究与应用[J]. 电化学（中英文）, 2015, 21(5): 449-454.
[4]	王晓丽, 张宇, 张华民. 全钒液流电池储能技术开发与应用进展[J]. 电化学（中英文）, 2015, 21(5): 433-440.
[5]	杨大伟, 董燕青, 范镜敏, 郑明森, 董全峰. 全钒液流电池磺化石墨烯/Nafion复合膜的研究[J]. 电化学（中英文）, 2015, 21(5): 407-410.
[6]	杨旺火, 胡融刚, 叶陈清, 杭纬, 李宁, 林昌健. 阵列参比电极法研究316不锈钢焊缝腐蚀行为[J]. 电化学（中英文）, 2011, 17(4): 373-379.
[7]	柳东东, 林茂才, 管涛, 余晴春, . 全钒氧化还原液流电池Nafion/SiO_2复合膜的研究[J]. 电化学（中英文）, 2010, 16(4): 455-459.
[8]	赵平, 张华民, 文越华, 衣宝廉, . 全钒液流单电池充放电行为及特性研究(英文)[J]. 电化学（中英文）, 2007, 13(1): 12-18.
[9]	汪的华,陈政. 熔盐电化学创新研究——武汉大学电化学研究中心熔盐电化学研究工作简介[J]. 电化学（中英文）, 2005, 11(2): 119-124.
[10]	高佩,金先波,汪的华,胡晓宏,陈政. 新型高温、长寿命氯化物熔盐参比电极的制备与研究[J]. 电化学（中英文）, 2005, 11(1): 8-11.