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研究论文

添加剂氟代乙烯碳酸酯对锂离子电池低温性能影响的机制研究

  • 卞锋菊 ,
  • 张忠如 ,
  • 杨勇
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  • 1. 厦门大学电化学技术教育部工程研究中心,福建 厦门 361100;2. 厦门大学化学化工学院,福建 厦门 361005;3. 厦门大学能源研究院,福建 厦门 361100

收稿日期: 2012-07-13

  修回日期: 2012-09-12

  网络出版日期: 2012-09-30

基金资助

福建省重大科技专项(No. 2009HZ0004)资助

Effects of Fluoroethylene Carbonate Additive on Low Temperature Performance of Li-ion Batteries

  • BIAN Feng-Ju ,
  • ZHANG Zhong-Ru ,
  • YANG Yong
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  • 1. Engineering Research Center of Electrochemical Technology of MOE, Xiamen, 361100; 2. College of Chemistry and Chemical Engineering, Xiamen, 361005; 3. School of Energy Research, Xiamen University, Xiamen, 361100

Received date: 2012-07-13

  Revised date: 2012-09-12

  Online published: 2012-09-30

摘要

本文通过磷酸铁锂/碳电池研究了电解液添加剂氟代乙烯碳酸酯(FEC)对电池低温性能的影响. 电池充放电实验证明,FEC添加剂能够在负极表面形成良好的固体电解质界面层(SEI). 电解液中添加5% FEC后,电池-40 oC低温放电容量保持率可以从31.7%提高至43.7%,还提高了电池放电电压平台. 交流阻抗测试表明,FEC的加入能够有效降低电池的界面传荷阻抗(Rct). 参比电极测试表明,其主要是降低了碳负极的低温极化.

本文引用格式

卞锋菊 , 张忠如 , 杨勇 . 添加剂氟代乙烯碳酸酯对锂离子电池低温性能影响的机制研究[J]. 电化学, 2013 , 19(4) : 355 -360 . DOI: 10.61558/2993-074X.2121

Abstract

The effects of fluoroethylene carbonate (FEC) on the low temperature performance of lithium ion phosphate full battery are evaluated by different techniques. By addition of 5 wt% FEC into a commercial electrolyte, effective solid electrolyte interface (SEI) film can be formed on the graphite electrodes, the discharge capacity retention at -40 oC was increased from 31.7% to 43.7%, and the discharge voltage plateau of the cell is raised. This is attributed to a reduced charge transfer resistance and a lowered polarization on the graphite electrode by electrochemical impedance spectroscopy (EIS) and reference electrode test.
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