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研究论文

钙钛矿La1-xSrxCoO3的电化学电容性能

  • 徐暘 ,
  • 包彦彦 ,
  • 杜龙飞 ,
  • 曹殿学 ,
  • 王贵领
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  • 1. 哈尔滨工程大学材料科学与化学工程学院,黑龙江 哈尔滨 150001; 2. 黑龙江中医药大学药学院,黑龙江 哈尔滨 150040

收稿日期: 2012-02-27

  修回日期: 2012-04-10

  网络出版日期: 2012-04-20

基金资助

国家自然科学基金项目(No. 20973048)资助

The Electrochemical Capacitance Performance of La1-xSrxCoO3 Perovskites

  • XU Yang ,
  • BAO Yan-Yan ,
  • DU Long-Fei ,
  • CAO Dian-Xue ,
  • WANG Gui-Ling
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  • 1. College of Material Science and Chemical Engineering, Harbin Engineering University, Harbin 150001,China;2. College of Pharmacy, Heilongjiang University of Traditional Chinese Medicine, Harbin 150040, China

Received date: 2012-02-27

  Revised date: 2012-04-10

  Online published: 2012-04-20

摘要

以溶胶-凝胶法制备La1-xSrxCoO3(x = 0.2, 0.4, 0.6, 0.8)电极材料,XRD表征证明所得产物属钙钛矿相. 由循环伏安和充放电曲线测试了La1-xSrxCoO3在碱性介质中的电化学电容性能. 结果表明,La0.6Sr0.4CoO3电极10 mA.cm-2电流密度的放电比电容为325 F.g-1,500周期循环后其比电容仍保持于315 F.g-1,比电容保持率97.0%.

本文引用格式

徐暘 , 包彦彦 , 杜龙飞 , 曹殿学 , 王贵领 . 钙钛矿La1-xSrxCoO3的电化学电容性能[J]. 电化学, 2013 , 19(2) : 174 -177 . DOI: 10.61558/2993-074X.2110

Abstract

In this paper, the La1-xSrxCoO3 (x = 0.2, 0.4, 0.6, 0.8) perovskites powders were synthesized by a sol-gel method. The perovskite phases were characterized by X-ray diffraction (XRD), while the electrochemical capacitance performance of La1-xSrxCoO3 electrodes in alkaline electrolyte was studied by cyclic voltammetry and galvanostatic charge/discharge test. It was found that the La0.6Sr0.4CoO3 electrode exhibited a specific capacitance of 325 F.g-1 in 6.0 mol.L-1 KOH electrolyte at a current density of 10 mA.cm-2, and the specific capacitance of 315 F.g-1 could be maintained after 500 charge/discharge cycles which corresponds to the retention rate of 97%.
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