基于琼脂支撑的液/液界面上AgTCNQ的电化学合成

黄丽; 汪宜娴; Michael V. Mirkin; 任斌; 詹东平

doi:10.61558/2993-074X.2611

电化学 >

2012 , Vol. 18 >Issue 5: 405 - 409

DOI: https://doi.org/10.61558/2993-074X.2611

表界面电化学

基于琼脂支撑的液/液界面上AgTCNQ的电化学合成

黄丽 ,
汪宜娴 ,
Michael V. Mirkin ,
任斌 ,
詹东平

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1. 厦门大学化学化工学院化学系, 福建厦门361005; 2. 厦门大学固体表面物理化学国家重点实验室, 福建厦门361005; 3. 纽约市立大学皇后学院化学与生物化学系袁美国纽约11367

收稿日期: 2012-07-01

修回日期: 2012-10-08

网络出版日期: 2012-10-28

基金资助

This work was supported by National Science Foundation of China (No. 20973142, No. 21061120456, and No. 21021002), National Basic Research Program of China (2011CB933700) and the National Science Foundation (CHE-1026582; MVM).

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Electrochemical Synthesis of Silver-Tetracyanoquinodimethane Nanorods at Agar Supported Water/1,2-Dichloroethane Interface

Li Huang ,
Yixian Wang ,
Michael V. Mirkin ,
Bin Ren ,
Dongping Zhan

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1. Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China; 2. State Key Laboratory of Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen 361005, Fujian, China; 3. Department of Chemistry and Biochemistry, Queens College-CUNY, Flushing, New York 11367, USA

Received date: 2012-07-01

Revised date: 2012-10-08

Online published: 2012-10-28

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摘要

具有高导电性和独特电学性质的金属有机络合物AgTCNQ是一种重要的电荷转移盐.本文采用琼脂作为胶凝剂构成水|1,2-二氯乙烷液液界面；施加电压时银离子由水相穿过水凝胶进入有机相，与TCNQ^-反应生成AgTCNQ纳米棒.结果表明液/液界面电化学方法为合成有机金属功能材料的有效途径.

关键词： 液/液界面; 银-四氰基对苯二醌二甲烷; 电化学合成; 纳米棒

本文引用格式

黄丽 , 汪宜娴 , Michael V. Mirkin , 任斌 , 詹东平 . 基于琼脂支撑的液/液界面上AgTCNQ的电化学合成[J]. 电化学, 2012 , 18(5) : 405 -409 . DOI: 10.61558/2993-074X.2611

Abstract

Silver-tetracyanoquinodimethane (AgTCNQ) is an important charge transfer salt due to its high conductivity and other electronic properties. In this communication, we report the synthesis of AgTCNQ at the liquid/liquid interface. Agar was used as a gelling agent to support water/1,2-dichloroethane (DCE) interface. Silver ions were transferred from the hydrogel into DCE phase, where they combined with TCNQ^- to form AgTCNQ nanorods. The developed method can provide a new route for synthesis of functional materials based on the electrochemistry at the liquid/liquid interface.

Key words： liquid/liquid interface; silver-tetracyanoquinodimethane; electrochemical synthesis; nanorods

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