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研究论文

纳米金膜电极上CN~-吸附的电化学和原位红外反射光谱研究

  • 甄春花 ,
  • 范纯洁 ,
  • 孙世刚
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  • 厦门大学化学化工学院化学系固体表面物理化学国家重点实验室,厦门大学化学化工学院化学系固体表面物理化学国家重点实验室,厦门大学化学化工学院化学系固体表面物理化学国家重点实验室 福建厦门361005,福建厦门361005,福建厦门361005

收稿日期: 2008-05-28

  修回日期: 2008-05-28

  网络出版日期: 2008-05-28

Cyclic Voltammetry and in situ FTIR Studies of Cyanide Adsorption on Nanostructured Au Film Electrode in Alkaline Solutions

  • ZHEN Chun-Hua ,
  • FAN Chun-Jie ,
  • SUN Shi-Gang
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  • (Department of chemistry,College of Chemistry and Chemical Engineering,State Key Laboratory of PhysicalChemistry of Solid Surfaces,Xiamen University,Xiamen 361005,Fujian,China

Received date: 2008-05-28

  Revised date: 2008-05-28

  Online published: 2008-05-28

摘要

应用循环伏安(CV)和原位红外反射光谱(in situFTIRS)研究碱性介质中氰(CN-)在纳米金膜电极(nm-Au/GC)上的吸附行为.结果显示,当研究电极电位低于0.0 V时,CN-可稳定吸附在nm-Au/GC电极表面,高于0.0 V,则发生氧化脱附.发现nm-Au/GC表面具有异常红外效应(AIREs),即吸附态CN-谱峰呈现出与本体Au电极不同的方向倒反、红外吸收增强(39.2倍)以及半峰宽增加的异常光谱特征.本研究将纳米薄膜材料的这一AIREs从过渡金属拓展到币族金属,进一步证明AIREs是迄今研究的金属及合金纳米材料的普遍特性.

本文引用格式

甄春花 , 范纯洁 , 孙世刚 . 纳米金膜电极上CN~-吸附的电化学和原位红外反射光谱研究[J]. 电化学, 2008 , 14(2) : 218 -222 . DOI: 10.61558/2993-074X.1895

Abstract

The adsorption of cyanide(CN-) on electrodes of nanometer scale thin film of gold supported on glassy carbon(nm-Au/GC) in alkaline solutions were investigated using cyclic voltammetry and in situ FTIR spectroscopy.It has revealed that the electrodeposited nanostructured Au thin film exhibited AIREs(abnormal infrared effects) for CN-adsorption,which manifested 3 nonlinear IR spectral features: inversion of the direction of CN-band,enhancement of IR absorption of adsorbed CN-species(about 39.2 folds) and increase in the FWHM(full width at half maximum) of CN-band.
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