电催化活性亚甲基化合物的环丙烷化反应
收稿日期: 2023-03-22
修回日期: 2023-05-11
录用日期: 2023-06-29
网络出版日期: 2023-07-11
Electrocatalytic Cyclopropanation of Active Methylene Compounds
Received date: 2023-03-22
Revised date: 2023-05-11
Accepted date: 2023-06-29
Online published: 2023-07-11
揭亮华 , 徐海超 . 电催化活性亚甲基化合物的环丙烷化反应[J]. 电化学, 2024 , 30(4) : 2313001 . DOI: 10.13208/j.electrochem.2313001
The development of novel strategies to access cyclopropanes has become increasingly important due to the vital role of these three-membered ring structures in synthetic intermediates, natural products, and pharmaceuticals. Herein, we present an electrocatalytic method for the synthesis of cyclopropanes through intermolecular dehydrogenative annulation of active methylene compounds and arylalkenes. This electrochemical process requires no chemical oxidants, allowing for a speedy access to various functionalized cyclopropanes from inexpensive and readily available materials.
Key words: Electrochemistry; Cyclopropane; Catalyst; Alkene; Organic electrosynthesis
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